OA10126A - Improved method and apparatus for achieving high reaction rates - Google Patents

Improved method and apparatus for achieving high reaction rates Download PDF

Info

Publication number: OA10126A
Authority: OA; OAPI
Prior art keywords: reaction; métal; path length; sait; reactor
Prior art date: 1992-08-14

Application number

OA60608A

Other languages

English (en)

Inventor

Uwe Rockenfeller

Original Assignee

Rocky Research

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-08-14

Filing date

1995-02-10

Publication date

1996-12-18

1992-08-14 Priority claimed from US07/931,036 external-priority patent/US5328671A/en

1995-02-10 Application filed by Rocky Research filed Critical Rocky Research

1996-12-18 Publication of OA10126A publication Critical patent/OA10126A/en

Links

238000006243 chemical reaction Methods 0.000 title claims abstract description 242
238000000034 method Methods 0.000 title claims description 60
150000001875 compounds Chemical class 0.000 claims abstract description 114
238000009792 diffusion process Methods 0.000 claims abstract description 83
239000007795 chemical reaction product Substances 0.000 claims abstract description 27
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 163
239000007789 gas Substances 0.000 claims description 135
238000001179 sorption measurement Methods 0.000 claims description 68
229910000069 nitrogen hydride Inorganic materials 0.000 claims description 60
230000008569 process Effects 0.000 claims description 43
239000003463 adsorbent Substances 0.000 claims description 33
238000012546 transfer Methods 0.000 claims description 29
150000003839 salts Chemical class 0.000 claims description 28
239000000203 mixture Substances 0.000 claims description 26
229910021529 ammonia Inorganic materials 0.000 claims description 21
238000003795 desorption Methods 0.000 claims description 18
230000001965 increasing effect Effects 0.000 claims description 18
238000009826 distribution Methods 0.000 claims description 14
229910052718 tin Inorganic materials 0.000 claims description 14
229910052725 zinc Inorganic materials 0.000 claims description 14
239000011701 zinc Substances 0.000 claims description 14
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 13
229910052782 aluminium Inorganic materials 0.000 claims description 13
239000001110 calcium chloride Substances 0.000 claims description 13
229910001628 calcium chloride Inorganic materials 0.000 claims description 13
235000011148 calcium chloride Nutrition 0.000 claims description 13
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 12
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 11
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 11
229910001622 calcium bromide Inorganic materials 0.000 claims description 11
WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 claims description 11
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 10
229910021580 Cobalt(II) chloride Inorganic materials 0.000 claims description 10
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
229910052793 cadmium Inorganic materials 0.000 claims description 10
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 10
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 10
229910052708 sodium Inorganic materials 0.000 claims description 10
150000004820 halides Chemical class 0.000 claims description 9
239000011592 zinc chloride Substances 0.000 claims description 9
235000005074 zinc chloride Nutrition 0.000 claims description 9
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 9
229910021575 Iron(II) bromide Inorganic materials 0.000 claims description 8
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
GYCHYNMREWYSKH-UHFFFAOYSA-L iron(ii) bromide Chemical compound [Fe+2].[Br-].[Br-] GYCHYNMREWYSKH-UHFFFAOYSA-L 0.000 claims description 8
229910001625 strontium bromide Inorganic materials 0.000 claims description 8
YJPVTCSBVRMESK-UHFFFAOYSA-L strontium bromide Chemical compound [Br-].[Br-].[Sr+2] YJPVTCSBVRMESK-UHFFFAOYSA-L 0.000 claims description 8
229910021554 Chromium(II) chloride Inorganic materials 0.000 claims description 7
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
XBWRJSSJWDOUSJ-UHFFFAOYSA-L chromium(ii) chloride Chemical compound Cl[Cr]Cl XBWRJSSJWDOUSJ-UHFFFAOYSA-L 0.000 claims description 7
239000000741 silica gel Substances 0.000 claims description 7
229910002027 silica gel Inorganic materials 0.000 claims description 7
239000010457 zeolite Substances 0.000 claims description 7
101100096319 Drosophila melanogaster Spc25 gene Proteins 0.000 claims description 6
229910021380 Manganese Chloride Inorganic materials 0.000 claims description 6
GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 claims description 6
-1 MgClz Chemical compound 0.000 claims description 6
229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 6
229910021536 Zeolite Inorganic materials 0.000 claims description 6
229910001626 barium chloride Inorganic materials 0.000 claims description 6
WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 claims description 6
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 6
239000011565 manganese chloride Substances 0.000 claims description 6
235000002867 manganese chloride Nutrition 0.000 claims description 6
238000002156 mixing Methods 0.000 claims description 6
QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 6
229910001631 strontium chloride Inorganic materials 0.000 claims description 6
AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 claims description 6
ZSUXOVNWDZTCFN-UHFFFAOYSA-L tin(ii) bromide Chemical compound Br[Sn]Br ZSUXOVNWDZTCFN-UHFFFAOYSA-L 0.000 claims description 6
229910019131 CoBr2 Inorganic materials 0.000 claims description 5
239000001257 hydrogen Substances 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
229910001629 magnesium chloride Inorganic materials 0.000 claims description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
229910021626 Tin(II) chloride Inorganic materials 0.000 claims description 4
229910001623 magnesium bromide Inorganic materials 0.000 claims description 4
OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 claims description 4
235000011150 stannous chloride Nutrition 0.000 claims description 4
AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 claims description 4
229910021577 Iron(II) chloride Inorganic materials 0.000 claims description 3
229910001620 barium bromide Inorganic materials 0.000 claims description 3
NKQIMNKPSDEDMO-UHFFFAOYSA-L barium bromide Chemical compound [Br-].[Br-].[Ba+2] NKQIMNKPSDEDMO-UHFFFAOYSA-L 0.000 claims description 3
238000004891 communication Methods 0.000 claims description 3
150000004678 hydrides Chemical class 0.000 claims description 3
150000002431 hydrogen Chemical class 0.000 claims description 3
NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
229910052786 argon Inorganic materials 0.000 claims description 2
238000010926 purge Methods 0.000 claims description 2
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims 14
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 9
229910002651 NO3 Inorganic materials 0.000 claims 9
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 9
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims 9
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 9
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 9
239000003513 alkali Substances 0.000 claims 9
239000011734 sodium Substances 0.000 claims 9
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims 8
230000007704 transition Effects 0.000 claims 8
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
239000002250 absorbent Substances 0.000 claims 1
230000002745 absorbent Effects 0.000 claims 1
UBAZGMLMVVQSCD-UHFFFAOYSA-N carbon dioxide;molecular oxygen Chemical compound O=O.O=C=O UBAZGMLMVVQSCD-UHFFFAOYSA-N 0.000 claims 1
229910002091 carbon monoxide Inorganic materials 0.000 claims 1
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims 1
239000000463 material Substances 0.000 description 23
239000000376 reactant Substances 0.000 description 19
238000013461 design Methods 0.000 description 17
229910052751 metal Inorganic materials 0.000 description 14
239000002184 metal Substances 0.000 description 14
239000000047 product Substances 0.000 description 14
239000007787 solid Substances 0.000 description 13
239000012530 fluid Substances 0.000 description 12
150000002739 metals Chemical class 0.000 description 12
238000001816 cooling Methods 0.000 description 11
239000002245 particle Substances 0.000 description 10
239000000919 ceramic Substances 0.000 description 9
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
230000008901 benefit Effects 0.000 description 8
238000010438 heat treatment Methods 0.000 description 7
230000006872 improvement Effects 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
229910001868 water Inorganic materials 0.000 description 6
239000000654 additive Substances 0.000 description 5
238000004378 air conditioning Methods 0.000 description 5
239000011449 brick Substances 0.000 description 5
229910052804 chromium Inorganic materials 0.000 description 5
239000011651 chromium Substances 0.000 description 5
229910052802 copper Inorganic materials 0.000 description 5
239000010949 copper Substances 0.000 description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
229910052759 nickel Inorganic materials 0.000 description 5
238000005457 optimization Methods 0.000 description 5
239000011148 porous material Substances 0.000 description 5
239000011135 tin Substances 0.000 description 5
229910021560 Chromium(III) bromide Inorganic materials 0.000 description 4
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
238000010521 absorption reaction Methods 0.000 description 4
238000013459 approach Methods 0.000 description 4
UZDWIWGMKWZEPE-UHFFFAOYSA-K chromium(iii) bromide Chemical compound [Cr+3].[Br-].[Br-].[Br-] UZDWIWGMKWZEPE-UHFFFAOYSA-K 0.000 description 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
150000001649 bromium compounds Chemical class 0.000 description 3
238000004146 energy storage Methods 0.000 description 3
150000004694 iodide salts Chemical class 0.000 description 3
229910052742 iron Inorganic materials 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
238000013508 migration Methods 0.000 description 3
230000005012 migration Effects 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
229910052700 potassium Inorganic materials 0.000 description 3
230000035484 reaction time Effects 0.000 description 3
239000002594 sorbent Substances 0.000 description 3
238000002336 sorption--desorption measurement Methods 0.000 description 3
238000012360 testing method Methods 0.000 description 3
VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
229910021568 Manganese(II) bromide Inorganic materials 0.000 description 2
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
101100496858 Mus musculus Colec12 gene Proteins 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
229910045601 alloy Inorganic materials 0.000 description 2
239000000956 alloy Substances 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
230000008859 change Effects 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
238000010276 construction Methods 0.000 description 2
RJYMRRJVDRJMJW-UHFFFAOYSA-L dibromomanganese Chemical compound Br[Mn]Br RJYMRRJVDRJMJW-UHFFFAOYSA-L 0.000 description 2
230000002708 enhancing effect Effects 0.000 description 2
230000007613 environmental effect Effects 0.000 description 2
239000006260 foam Substances 0.000 description 2
239000013529 heat transfer fluid Substances 0.000 description 2
239000003446 ligand Substances 0.000 description 2
229910052744 lithium Inorganic materials 0.000 description 2
AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
238000005259 measurement Methods 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
150000002823 nitrates Chemical class 0.000 description 2
150000003891 oxalate salts Chemical class 0.000 description 2
229910000073 phosphorus hydride Inorganic materials 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
229910001495 sodium tetrafluoroborate Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
238000003860 storage Methods 0.000 description 2
229910052712 strontium Inorganic materials 0.000 description 2
150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
230000002459 sustained effect Effects 0.000 description 2
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
239000011475 Accrington brick Substances 0.000 description 1
101100328886 Caenorhabditis elegans col-2 gene Proteins 0.000 description 1
229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
229910021592 Copper(II) chloride Inorganic materials 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
229910019445 Mg(ClO4) Inorganic materials 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
229910000792 Monel Inorganic materials 0.000 description 1
229910021585 Nickel(II) bromide Inorganic materials 0.000 description 1
206010036086 Polymenorrhoea Diseases 0.000 description 1
241000206608 Pyropia tenera Species 0.000 description 1
101100237460 Rattus norvegicus Mgll gene Proteins 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
241001122767 Theaceae Species 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000003973 alkyl amines Chemical class 0.000 description 1
239000001273 butane Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
238000005056 compaction Methods 0.000 description 1
239000002131 composite material Substances 0.000 description 1
239000012809 cooling fluid Substances 0.000 description 1
OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
230000001351 cycling effect Effects 0.000 description 1
150000004985 diamines Chemical class 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000007710 freezing Methods 0.000 description 1
230000008014 freezing Effects 0.000 description 1
239000008187 granular material Substances 0.000 description 1
CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 1
235000015243 ice cream Nutrition 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
150000001247 metal acetylides Chemical class 0.000 description 1
229910001510 metal chloride Inorganic materials 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
IPLJNQFXJUCRNH-UHFFFAOYSA-L nickel(2+);dibromide Chemical compound [Ni+2].[Br-].[Br-] IPLJNQFXJUCRNH-UHFFFAOYSA-L 0.000 description 1
150000002826 nitrites Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000011236 particulate material Substances 0.000 description 1
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
230000035699 permeability Effects 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000002984 plastic foam Substances 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
230000000135 prohibitive effect Effects 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
239000001294 propane Substances 0.000 description 1
239000008262 pumice Substances 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000005057 refrigeration Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
238000005245 sintering Methods 0.000 description 1
239000008247 solid mixture Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 description 1
238000005496 tempering Methods 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
210000002268 wool Anatomy 0.000 description 1
RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/003—Storage or handling of ammonia
- C01C1/006—Storage or handling of ammonia making use of solid ammonia storage materials, e.g. complex ammine salts
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/047—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for absorption-type refrigeration systems
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B35/00—Boiler-absorbers, i.e. boilers usable for absorption or adsorption
- F25B35/04—Boiler-absorbers, i.e. boilers usable for absorption or adsorption using a solid as sorbent
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
- F28D20/003—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using thermochemical reactions
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage

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Engineering & Computer Science (AREA)
Chemical & Material Sciences (AREA)
Thermal Sciences (AREA)
Organic Chemistry (AREA)
Physics & Mathematics (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Mechanical Engineering (AREA)
General Engineering & Computer Science (AREA)
Biomedical Technology (AREA)
Materials Engineering (AREA)
Oil, Petroleum & Natural Gas (AREA)
Environmental & Geological Engineering (AREA)
Inorganic Chemistry (AREA)
Health & Medical Sciences (AREA)
Combustion & Propulsion (AREA)
Analytical Chemistry (AREA)
Sorption Type Refrigeration Machines (AREA)
Physical Or Chemical Processes And Apparatus (AREA)
Steering Control In Accordance With Driving Conditions (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Catalysts (AREA)
Superconductors And Manufacturing Methods Therefor (AREA)

OA60608A 1992-08-14 1995-02-10 Improved method and apparatus for achieving high reaction rates OA10126A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US07/931,036 US5328671A (en)	1989-03-08	1992-08-14	Heat and mass transfer
US08/104,427 US5441716A (en)	1989-03-08	1993-08-09	Method and apparatus for achieving high reaction rates

Publications (1)

Publication Number	Publication Date
OA10126A true OA10126A (en)	1996-12-18

Family

ID=26801531

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
OA60608A OA10126A (en)	1992-08-14	1995-02-10	Improved method and apparatus for achieving high reaction rates

Country Status (20)

Country	Link
US (1)	US5441716A (de)
EP (1)	EP0682768B1 (de)
JP (1)	JP3194746B2 (de)
CN (1)	CN1079276C (de)
AT (1)	ATE189053T1 (de)
AU (1)	AU681092B2 (de)
BR (1)	BR9306892A (de)
CA (1)	CA2141037C (de)
CZ (1)	CZ290058B6 (de)
DE (1)	DE69327664T2 (de)
DK (1)	DK0682768T3 (de)
ES (1)	ES2144011T3 (de)
HU (1)	HU220368B1 (de)
MX (1)	MX9304936A (de)
NZ (1)	NZ255736A (de)
OA (1)	OA10126A (de)
PL (1)	PL307478A1 (de)
SG (1)	SG129986A1 (de)
SK (1)	SK283642B6 (de)
WO (1)	WO1994011685A1 (de)

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- 1993-08-09 US US08/104,427 patent/US5441716A/en not_active Expired - Lifetime
- 1993-08-13 DK DK93920001T patent/DK0682768T3/da active
- 1993-08-13 EP EP93920001A patent/EP0682768B1/de not_active Expired - Lifetime
- 1993-08-13 BR BR9306892A patent/BR9306892A/pt not_active IP Right Cessation
- 1993-08-13 PL PL93307478A patent/PL307478A1/xx unknown
- 1993-08-13 SG SG9602239-7A patent/SG129986A1/en unknown
- 1993-08-13 ES ES93920001T patent/ES2144011T3/es not_active Expired - Lifetime
- 1993-08-13 HU HU9500429A patent/HU220368B1/hu not_active IP Right Cessation
- 1993-08-13 SK SK196-95A patent/SK283642B6/sk not_active IP Right Cessation
- 1993-08-13 DE DE69327664T patent/DE69327664T2/de not_active Expired - Lifetime
- 1993-08-13 MX MX9304936A patent/MX9304936A/es active IP Right Grant
- 1993-08-13 AT AT93920001T patent/ATE189053T1/de not_active IP Right Cessation
- 1993-08-13 CZ CZ1995382A patent/CZ290058B6/cs not_active IP Right Cessation
- 1993-08-13 CA CA002141037A patent/CA2141037C/en not_active Expired - Fee Related
- 1993-08-13 NZ NZ255736A patent/NZ255736A/en not_active IP Right Cessation
- 1993-08-13 WO PCT/US1993/007588 patent/WO1994011685A1/en not_active Ceased
- 1993-08-13 JP JP50849594A patent/JP3194746B2/ja not_active Expired - Fee Related
- 1993-08-13 AU AU50076/93A patent/AU681092B2/en not_active Ceased
- 1993-08-14 CN CN93117765A patent/CN1079276C/zh not_active Expired - Fee Related
1995
- 1995-02-10 OA OA60608A patent/OA10126A/en unknown

Also Published As

Publication number	Publication date
US5441716A (en)	1995-08-15
HUT75501A (en)	1997-05-28
WO1994011685A1 (en)	1994-05-26
SK19695A3 (en)	1995-08-09
EP0682768B1 (de)	2000-01-19
SG129986A1 (en)	2007-03-20
CZ290058B6 (cs)	2002-05-15
ES2144011T3 (es)	2000-06-01
CA2141037A1 (en)	1994-05-26
SK283642B6 (sk)	2003-11-04
AU5007693A (en)	1994-06-08
CN1093794A (zh)	1994-10-19
MX9304936A (es)	1994-08-31
ATE189053T1 (de)	2000-02-15
PL307478A1 (en)	1995-05-29
DE69327664T2 (de)	2000-08-31
CZ38295A3 (en)	1995-09-13
CN1079276C (zh)	2002-02-20
CA2141037C (en)	2004-03-30
HU220368B1 (hu)	2002-01-28
JP3194746B2 (ja)	2001-08-06
HU9500429D0 (en)	1995-04-28
AU681092B2 (en)	1997-08-21
DK0682768T3 (da)	2000-07-10
JPH08504929A (ja)	1996-05-28
DE69327664D1 (de)	2000-02-24
NZ255736A (en)	1997-01-29
BR9306892A (pt)	1998-12-08
EP0682768A1 (de)	1995-11-22

Publication	Publication Date	Title
OA10126A (en)	1996-12-18	Improved method and apparatus for achieving high reaction rates
US5328671A (en)	1994-07-12	Heat and mass transfer
US5628205A (en)	1997-05-13	Refrigerators/freezers incorporating solid-vapor sorption reactors capable of high reaction rates
CA2198711C (en)	2006-11-28	Improved rapid sorption cooling or freezing appliance
CA2215212C (en)	2007-06-12	Improved heating and air conditioning systems incorporating solid-vapor sorption reactors capable of high reaction rates
Critoph et al.	2005	Review of trends in solid sorption refrigeration and heat pumping technology
EP0613611B1 (de)	1997-12-17	Kühleinrichtung für elektronische und komputer bestandteile
KR100306706B1 (ko)	2001-11-30	높은반응속도를얻기위한개선된방법및그장치
CN1161742A (zh)	1997-10-08	改进的快速吸附冷却或冷冻设备
MXPA97007182A (en)	1998-07-03	Improved air heating and air conditioning systems that incorporate solid-steam absorption reactors with reacc altitude capacity
Rockenfeller et al.	1987	Rotesco-50/50: A Thermal Energy Storage Concept for the Temperature Range− 50° F to+ 50° F
HK1009483B (en)	2005-10-28	Improved refrigerators/freezers incorporating solid-vapor sorption reactors capable of high reaction rates
JPS60245974A (ja)	1985-12-05	多重効用ヒ−トポンプ装置