OA11315A - Method for the separation of acid from sugars. - Google Patents

Method for the separation of acid from sugars. Download PDF

Info

Publication number: OA11315A
Authority: OA; OAPI
Prior art keywords: acid; sugar; heavy metals; solution; chromatographie
Prior art date: 1997-08-04

Application number

OA1200000023A

Other languages

English (en)

Inventor

Russo Lawrence J Jr

Original Assignee

Controlled Environment Syst

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-08-04

Filing date

2000-02-01

Publication date

2003-10-27

2000-02-01 Application filed by Controlled Environment Syst filed Critical Controlled Environment Syst

2003-10-27 Publication of OA11315A publication Critical patent/OA11315A/en

Links

239000002253 acid Substances 0.000 title claims abstract description 105
235000000346 sugar Nutrition 0.000 title claims abstract description 104
238000000034 method Methods 0.000 title claims abstract description 83
150000008163 sugars Chemical class 0.000 title claims abstract description 20
238000000926 separation method Methods 0.000 title abstract 2
239000000463 material Substances 0.000 claims abstract description 65
230000007717 exclusion Effects 0.000 claims abstract description 22
229920002678 cellulose Polymers 0.000 claims abstract description 21
239000001913 cellulose Substances 0.000 claims abstract description 21
125000000129 anionic group Chemical group 0.000 claims abstract description 17
239000007788 liquid Substances 0.000 claims abstract description 17
229920002488 Hemicellulose Polymers 0.000 claims abstract description 13
238000005903 acid hydrolysis reaction Methods 0.000 claims abstract description 9
238000004519 manufacturing process Methods 0.000 claims abstract description 7
229910001385 heavy metal Inorganic materials 0.000 claims description 53
229920005989 resin Polymers 0.000 claims description 23
239000011347 resin Substances 0.000 claims description 23
239000010801 sewage sludge Substances 0.000 claims description 17
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 16
235000008733 Citrus aurantifolia Nutrition 0.000 claims description 15
235000011941 Tilia x europaea Nutrition 0.000 claims description 15
239000004571 lime Substances 0.000 claims description 15
229910052751 metal Inorganic materials 0.000 claims description 13
239000002184 metal Substances 0.000 claims description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
239000002699 waste material Substances 0.000 claims description 11
240000004808 Saccharomyces cerevisiae Species 0.000 claims description 10
239000002244 precipitate Substances 0.000 claims description 9
150000002739 metals Chemical class 0.000 claims description 8
239000000203 mixture Substances 0.000 claims description 8
239000002351 wastewater Substances 0.000 claims description 7
238000010438 heat treatment Methods 0.000 claims description 6
150000002500 ions Chemical class 0.000 claims description 6
239000010440 gypsum Substances 0.000 claims description 5
229910052602 gypsum Inorganic materials 0.000 claims description 5
230000003301 hydrolyzing effect Effects 0.000 claims description 5
239000002440 industrial waste Substances 0.000 claims description 5
239000010865 sewage Substances 0.000 claims description 5
238000001035 drying Methods 0.000 claims description 4
239000010802 sludge Substances 0.000 claims description 4
238000007865 diluting Methods 0.000 claims description 3
238000005406 washing Methods 0.000 claims description 3
238000011437 continuous method Methods 0.000 claims description 2
238000004821 distillation Methods 0.000 claims description 2
235000013405 beer Nutrition 0.000 claims 3
125000001477 organic nitrogen group Chemical group 0.000 claims 2
SGPGESCZOCHFCL-UHFFFAOYSA-N Tilisolol hydrochloride Chemical compound [Cl-].C1=CC=C2C(=O)N(C)C=C(OCC(O)C[NH2+]C(C)(C)C)C2=C1 SGPGESCZOCHFCL-UHFFFAOYSA-N 0.000 claims 1
238000002270 exclusion chromatography Methods 0.000 claims 1
230000003472 neutralizing effect Effects 0.000 claims 1
239000010813 municipal solid waste Substances 0.000 abstract description 7
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 5
239000000243 solution Substances 0.000 description 36
229920001429 chelating resin Polymers 0.000 description 12
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
238000000855 fermentation Methods 0.000 description 10
230000004151 fermentation Effects 0.000 description 10
235000014680 Saccharomyces cerevisiae Nutrition 0.000 description 9
229920005610 lignin Polymers 0.000 description 9
229920003023 plastic Polymers 0.000 description 8
239000004033 plastic Substances 0.000 description 8
125000002091 cationic group Chemical group 0.000 description 7
229920001467 poly(styrenesulfonates) Polymers 0.000 description 7
239000000047 product Substances 0.000 description 7
-1 septage Substances 0.000 description 7
239000000061 acid fraction Substances 0.000 description 5
238000005516 engineering process Methods 0.000 description 5
238000012545 processing Methods 0.000 description 5
238000011084 recovery Methods 0.000 description 5
239000005060 rubber Substances 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
229920005654 Sephadex Polymers 0.000 description 4
239000012507 Sephadex™ Substances 0.000 description 4
238000004587 chromatography analysis Methods 0.000 description 4
125000000524 functional group Chemical group 0.000 description 4
239000011521 glass Substances 0.000 description 4
238000004064 recycling Methods 0.000 description 4
238000001223 reverse osmosis Methods 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
239000002028 Biomass Substances 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
238000011109 contamination Methods 0.000 description 3
239000000413 hydrolysate Substances 0.000 description 3
239000011148 porous material Substances 0.000 description 3
238000011144 upstream manufacturing Methods 0.000 description 3
239000010920 waste tyre Substances 0.000 description 3
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 2
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
239000012141 concentrate Substances 0.000 description 2
238000010924 continuous production Methods 0.000 description 2
238000010790 dilution Methods 0.000 description 2
239000012895 dilution Substances 0.000 description 2
238000000605 extraction Methods 0.000 description 2
239000000446 fuel Substances 0.000 description 2
230000014509 gene expression Effects 0.000 description 2
239000008103 glucose Substances 0.000 description 2
238000004128 high performance liquid chromatography Methods 0.000 description 2
230000007062 hydrolysis Effects 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
238000001032 ion-exclusion chromatography Methods 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
239000012528 membrane Substances 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
244000005700 microbiome Species 0.000 description 2
239000010815 organic waste Substances 0.000 description 2
239000000123 paper Substances 0.000 description 2
108090000623 proteins and genes Proteins 0.000 description 2
238000012216 screening Methods 0.000 description 2
239000002910 solid waste Substances 0.000 description 2
238000004611 spectroscopical analysis Methods 0.000 description 2
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
239000000725 suspension Substances 0.000 description 2
BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
APCLRHPWFCQIMG-UHFFFAOYSA-N 4-(5,6-dimethoxy-1-benzothiophen-2-yl)-4-oxobutanoic acid Chemical compound C1=C(OC)C(OC)=CC2=C1SC(C(=O)CCC(O)=O)=C2 APCLRHPWFCQIMG-UHFFFAOYSA-N 0.000 description 1
PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
229920000936 Agarose Polymers 0.000 description 1
241000894006 Bacteria Species 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
229920002271 DEAE-Sepharose Polymers 0.000 description 1
GUBGYTABKSRVRQ-WFVLMXAXSA-N DEAE-cellulose Chemical compound OC1C(O)C(O)C(CO)O[C@H]1O[C@@H]1C(CO)OC(O)C(O)C1O GUBGYTABKSRVRQ-WFVLMXAXSA-N 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
241000588724 Escherichia coli Species 0.000 description 1
241000490229 Eucephalus Species 0.000 description 1
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
101100476713 Gallus gallus SAX1 gene Proteins 0.000 description 1
229940125791 MSA-2 Drugs 0.000 description 1
108010057081 Merozoite Surface Protein 1 Proteins 0.000 description 1
101710162106 Merozoite surface antigen 2 Proteins 0.000 description 1
101100460492 Mus musculus Nkx1-2 gene Proteins 0.000 description 1
OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 description 1
241001520808 Panicum virgatum Species 0.000 description 1
241000219000 Populus Species 0.000 description 1
229920001131 Pulp (paper) Polymers 0.000 description 1
229920002125 Sokalan® Polymers 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
241000592342 Tracheophyta Species 0.000 description 1
240000008042 Zea mays Species 0.000 description 1
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
235000002017 Zea mays subsp mays Nutrition 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000003463 adsorbent Substances 0.000 description 1
239000002154 agricultural waste Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
150000001413 amino acids Chemical class 0.000 description 1
238000005349 anion exchange Methods 0.000 description 1
239000003957 anion exchange resin Substances 0.000 description 1
239000003242 anti bacterial agent Substances 0.000 description 1
229940088710 antibiotic agent Drugs 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
238000010364 biochemical engineering Methods 0.000 description 1
229920001222 biopolymer Polymers 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000011111 cardboard Substances 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000004035 construction material Substances 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
239000005289 controlled pore glass Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
235000005822 corn Nutrition 0.000 description 1
238000004185 countercurrent chromatography Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000000428 dust Substances 0.000 description 1
230000005611 electricity Effects 0.000 description 1
238000000909 electrodialysis Methods 0.000 description 1
239000002360 explosive Substances 0.000 description 1
239000000835 fiber Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000002920 hazardous waste Substances 0.000 description 1
150000002402 hexoses Chemical class 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000002198 insoluble material Substances 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
239000004310 lactic acid Substances 0.000 description 1
235000014655 lactic acid Nutrition 0.000 description 1
238000004811 liquid chromatography Methods 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
239000001630 malic acid Substances 0.000 description 1
235000011090 malic acid Nutrition 0.000 description 1
230000000813 microbial effect Effects 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000012544 monitoring process Methods 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
235000015097 nutrients Nutrition 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
239000011368 organic material Substances 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
230000020477 pH reduction Effects 0.000 description 1
239000010893 paper waste Substances 0.000 description 1
239000011087 paperboard Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
150000002972 pentoses Chemical class 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229920003053 polystyrene-divinylbenzene Polymers 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000012163 sequencing technique Methods 0.000 description 1
238000001542 size-exclusion chromatography Methods 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000010959 steel Substances 0.000 description 1
239000010907 stover Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000001384 succinic acid Substances 0.000 description 1
235000011044 succinic acid Nutrition 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000002023 wood Substances 0.000 description 1
239000010925 yard waste Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
- B01D15/10—Selective adsorption, e.g. chromatography characterised by constructional or operational features
- B01D15/18—Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns
- B01D15/1814—Recycling of the fraction to be distributed
- B01D15/1821—Simulated moving beds
- B01D15/185—Simulated moving beds characterised by the components to be separated
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
- C13K1/04—Purifying
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
- B01D15/10—Selective adsorption, e.g. chromatography characterised by constructional or operational features
- B01D15/18—Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns
- B01D15/1814—Recycling of the fraction to be distributed
- B01D15/1821—Simulated moving beds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
- B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
- B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction, e.g. ion-exchange, ion-pair, ion-suppression or ion-exclusion
- B01D15/361—Ion-exchange
- B01D15/363—Anion-exchange
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
- B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
- B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction, e.g. ion-exchange, ion-pair, ion-suppression or ion-exclusion
- B01D15/365—Ion-exclusion

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Emergency Medicine (AREA)
Analytical Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Sustainable Development (AREA)
General Health & Medical Sciences (AREA)
Biochemistry (AREA)
Organic Chemistry (AREA)
Treatment Of Liquids With Adsorbents In General (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Preparation Of Compounds By Using Micro-Organisms (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)

OA1200000023A 1997-08-04 2000-02-01 Method for the separation of acid from sugars. OA11315A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US5467697P	1997-08-04	1997-08-04
US09/042,587 US5968362A (en)	1997-08-04	1998-03-17	Method for the separation of acid from sugars

Publications (1)

Publication Number	Publication Date
OA11315A true OA11315A (en)	2003-10-27

Family

ID=26719423

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
OA1200000023A OA11315A (en)	1997-08-04	2000-02-01	Method for the separation of acid from sugars.

Country Status (16)

Country	Link
US (3)	US5968362A (de)
EP (1)	EP1027122A4 (de)
JP (1)	JP2001511418A (de)
CN (1)	CN1145514C (de)
AP (1)	AP1129A (de)
AU (1)	AU747398B2 (de)
BR (1)	BR9811487A (de)
CA (1)	CA2299257A1 (de)
EA (1)	EA002483B1 (de)
HU (1)	HUP0004550A3 (de)
IL (1)	IL134098A (de)
NO (1)	NO20000368L (de)
NZ (1)	NZ502461A (de)
OA (1)	OA11315A (de)
PL (1)	PL338389A1 (de)
WO (1)	WO1999006133A1 (de)

Families Citing this family (77)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19858892A1 (de) *	1998-12-19	2000-06-21	Merck Patent Gmbh	Kontinuierliches Verfahren zur Trennung von Stoffen nach Molekülgröße
US7537826B2 (en)	1999-06-22	2009-05-26	Xyleco, Inc.	Cellulosic and lignocellulosic materials and compositions and composites made therefrom
FI20002148L (fi) *	2000-09-29	2002-03-30	Xyrofin Oy	Menetelmä tuotteiden talteenottamiseksi
WO2005009578A2 (en) *	2003-07-16	2005-02-03	Amalgamated Research, Inc.	Method for the recovery of acids from hydrometallurgy process solutions
JP4309196B2 (ja) *	2003-07-25	2009-08-05	日揮株式会社	擬似移動層クロマト分離方法
US20060011547A1 (en) *	2004-07-13	2006-01-19	Bell Stephen A	Methods of separating components in treatment fluids
US8003352B2 (en) *	2004-07-16	2011-08-23	Iogen Energy Corporation	Method of obtaining a product sugar stream from cellulosic biomass
WO2006095349A1 (en) *	2005-03-10	2006-09-14	Refael Aharon	Method of recycling fibers from sewage sludge and means thereof
US7708214B2 (en)	2005-08-24	2010-05-04	Xyleco, Inc.	Fibrous materials and composites
US20150328347A1 (en)	2005-03-24	2015-11-19	Xyleco, Inc.	Fibrous materials and composites
UA114465C2 (uk)	2005-07-19	2017-06-26	Інбікон А/С	Спосіб перетворення целюлозного матеріалу в етанол
FR2900654B1 (fr) *	2006-05-05	2008-08-01	Applexion	Procede de purification d'un acide organique par chromatographie
WO2007144476A1 (fr)	2006-06-16	2007-12-21	Groupe Novasep	Procede de separation sequence multicolonnes
US7497392B2 (en) *	2006-07-17	2009-03-03	Alliance Technology Group, Inc.	Process and apparatus for transforming waste materials into fuel
JP4336994B2 (ja) *	2006-07-31	2009-09-30	三菱自動車工業株式会社	フィルム付き合成板
PL2051824T3 (pl) *	2006-08-01	2020-11-16	Vwp Waste Processing Limited	Recykling odpadów z gospodarstw domowych
CA2661531C (en) *	2006-08-18	2014-06-17	Iogen Energy Corporation	Method of obtaining an organic salt or acid from an aqueous sugar stream
FR2907687B1 (fr) *	2006-10-30	2008-12-26	Applexion	Procede de purification de sialyllactose par chromatographie
US8247200B2 (en) *	2007-01-25	2012-08-21	Iogen Energy Corporation	Method of obtaining inorganic salt and acetate salt from cellulosic biomass
JP5263859B2 (ja) *	2007-04-23	2013-08-14	独立行政法人農業・食品産業技術総合研究機構	バイオマスの糖化・回収方法
FI123960B (fi) *	2007-11-14	2014-01-15	Aalto Korkeakoulusaeaetioe	Menetelmä lipidin tuottamiseksi
GB0801787D0 (en) *	2008-01-31	2008-03-05	Reclaim Resources Ltd	Apparatus and method for treating waste
US20090221079A1 (en) *	2008-02-28	2009-09-03	Dionex Corporation	Sample pretreatment and extraction
DE102008022242A1 (de) *	2008-05-06	2009-11-12	Green Sugar Gmbh	Apparatur zur Entfernung von Halogenwasserstoffsäuren aus Biomassehydrolysaten
FI20085477A0 (fi)	2008-05-20	2008-05-20	St1 Biofuels Oy	Menetelmä ja laite biojätteen käsittelemiseksi
CA2739451A1 (en) *	2008-10-17	2010-04-22	Mascoma Corporation	Production of pure lignin from lignocellulosic biomass
BRPI0917617B8 (pt)	2008-12-09	2018-09-25	Toray Industries	método para produzir açúcar líquido e método para produzir um produto químico
JP5526154B2 (ja)	2009-02-25	2014-06-18	カウンシル・オヴ・サイエンティフィック・アンド・インダストリアル・リサーチ	脱酸用ポリベンゾイミダゾール系膜
US8115047B2 (en) *	2009-04-01	2012-02-14	Earth Renewal Group, Llc	Aqueous phase oxidation process
US8481800B2 (en) *	2009-04-01	2013-07-09	Earth Renewal Group, Llc	Aqueous phase oxidation process
US7915474B2 (en) *	2009-04-01	2011-03-29	Earth Renewal Group, Llc	Aqueous phase oxidation process
US7951988B2 (en) *	2009-04-01	2011-05-31	Earth Renewal Group, Llc	Aqueous phase oxidation process
US9272936B2 (en)	2009-04-01	2016-03-01	Earth Renewal Group, Llc	Waste treatment process
US8168847B2 (en) *	2009-04-01	2012-05-01	Earth Renewal Group, Llc	Aqueous phase oxidation process
CN102596800B (zh)	2009-08-11	2015-03-04	Fp创新研究中心	来自纳米晶体纤维素制备过程的废液流的分离
US20110183389A1 (en) *	2009-10-26	2011-07-28	Van Walsum G Peter	Production of lactic acid from hemicellulose extracts
CN102725042A (zh)	2009-12-07	2012-10-10	加拿大阿普塔利斯制药公司	包含离子杂质的单糖混合物的纯化方法
JP5581069B2 (ja) *	2010-01-29	2014-08-27	株式会社藤井基礎設計事務所	酸回収方法、糖液の製造方法、及び発酵方法
US20130004994A1 (en)	2010-03-10	2013-01-03	Masayuki Hanakawa	Method for producing pure sugar solution, and method for producing chemical product
CA2795503C (en)	2010-03-19	2020-02-18	Poet Research, Inc.	System for treatment of biomass to facilitate the production of ethanol
EP3594354A1 (de)	2010-03-19	2020-01-15	Poet Research Incorporated	Methode zur produktion eines fermentationsprodukts aus biomasse
BR112012032999B1 (pt)	2010-06-26	2022-11-29	Virdia, Llc	Hidrolisado lignocelulósico e métodos de hidrólise ácida e desacidificação para gerar misturas de açúcar a partir de lignocelulose
IL206678A0 (en)	2010-06-28	2010-12-30	Hcl Cleantech Ltd	A method for the production of fermentable sugars
US20130266706A1 (en) *	2010-07-13	2013-10-10	Nederlandse Organisatie Voor Toegepast- Natuurwetenschappelijk Onderzoek Tno	Methods and compositions for deacidifying fruit juice
IL207329A0 (en)	2010-08-01	2010-12-30	Robert Jansen	A method for refining a recycle extractant and for processing a lignocellulosic material and for the production of a carbohydrate composition
IL207945A0 (en)	2010-09-02	2010-12-30	Robert Jansen	Method for the production of carbohydrates
PT106039A (pt)	2010-12-09	2012-10-26	Hcl Cleantech Ltd	Processos e sistemas para o processamento de materiais lenhocelulósicos e composições relacionadas
MX2013008370A (es)	2011-01-18	2014-01-20	Poet Res Inc	Sistemas y metodos para la hidrolisis de biomasa.
PH12013502015A1 (en)	2011-03-29	2013-12-16	Toray Industries	Method for manufacturing sugar solution
GB2524906B8 (en)	2011-04-07	2016-12-07	Virdia Ltd	Lignocellulose conversion processes and products
EP2729585A4 (de)	2011-07-07	2015-03-18	Poet Res Inc	Systeme und verfahren für säurerecycling
US9617608B2 (en)	2011-10-10	2017-04-11	Virdia, Inc.	Sugar compositions
NL1039316C2 (en) *	2012-01-23	2013-07-25	Univ Delft Tech	Process for the production of substantially pure monomers from biopolymers.
CN104093485B (zh)	2012-01-31	2017-03-29	赛罗尔比利时公司	从木质纤维素基质中提取戊糖的方法
US9459184B2 (en)	2012-03-08	2016-10-04	Dionex Corporation	Sorption of water from a sample using a polymeric drying agent
US9187790B2 (en)	2012-03-25	2015-11-17	Wisconsin Alumni Research Foundation	Saccharification of lignocellulosic biomass
US9493851B2 (en)	2012-05-03	2016-11-15	Virdia, Inc.	Methods for treating lignocellulosic materials
EP2862890A1 (de)	2012-05-03	2015-04-22	Virdia Ltd.	Verfahren zur Extraktion von Lignin aus Biomasse
EP2847342B1 (de) *	2012-05-07	2020-08-12	Archer Daniels Midland Co.	Reinigung von bernsteinsäure
JP5671594B2 (ja) *	2012-11-28	2015-02-18	日本食品化工株式会社	糖縮合物の製造法
NZ743055A (en)	2013-03-08	2020-03-27	Xyleco Inc	Equipment protecting enclosures
TWI476203B (zh)	2013-03-18	2015-03-11	Ind Tech Res Inst	醣類的分離方法
US9150938B2 (en)	2013-06-12	2015-10-06	Orochem Technologies, Inc.	Tagatose production from deproteinized whey and purification by continuous chromatography
AU2014288309B9 (en)	2013-07-09	2018-04-26	Toray Industries, Inc.	Method for producing saccharide solution
US11458414B2 (en)	2013-10-13	2022-10-04	Synergy Burcell Technologies, Llc	Methods and apparatus utilizing vacuum for breaking organic cell walls
US11078548B2 (en)	2015-01-07	2021-08-03	Virdia, Llc	Method for producing xylitol by fermentation
US9739692B2 (en)	2015-03-27	2017-08-22	Dionex Corporation	Pump-less method and apparatus for solvent extraction from a sample
JP6646065B2 (ja) *	2015-04-21	2020-02-14	エフピーイノベイションズ	酸／糖溶液から酸を回収するための方法
CN107849620B (zh)	2015-05-27	2022-01-11	威尔迪亚有限责任公司	用于处理木质纤维素材料的综合方法
CN108367212A (zh) *	2015-12-01	2018-08-03	陶氏环球技术有限责任公司	使用聚合物大孔吸附剂色谱分离有机酸
CN105601679B (zh) *	2016-01-13	2019-10-15	复旦大学	一种从生物质水热液化水解液中分离回收单糖、有机酸和酚类化合物组分的方法
MY186792A (en)	2016-02-04	2021-08-20	Ind Tech Res Inst	Method for separating hydrolysis product of biomass
CN109689852B (zh)	2016-07-06	2022-06-07	威尔迪亚有限责任公司	精制木质纤维素水解产物的方法
CN108220486A (zh) *	2017-12-28	2018-06-29	天津大学	一种利用酸阻滞树脂分离糖酸的方法
FR3082756B1 (fr) *	2018-06-26	2021-01-29	Seprosys	Procede de separation de molecules ionisees dans une solution en contenant
IT201900024991A1 (it)	2019-12-20	2021-06-20	Versalis Spa	Procedimento per il recupero ed il riciclo di acido alchil-solfonico nella produzione di lipidi da biomassa derivante da piante di guayule.
CN114307252B (zh) *	2021-12-30	2022-09-20	南京工业大学	一种利用准二维色谱法分离糖和酸的工艺

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3227510A (en) *	1958-03-04	1966-01-04	Tee Pak Inc	Dyeing substrates ionically binding in localized areas catalysts for the predyeing olefin polymerization thereon
US4452640A (en) *	1982-05-11	1984-06-05	Purdue Research Foundation	Quantitative hydrolysis of cellulose to glucose using zinc chloride
US4764276A (en) *	1984-07-30	1988-08-16	Advanced Separation Technologies Incorporated	Device for continuous contacting of fluids and solids
US4522726A (en) *	1984-07-30	1985-06-11	Progress Equities Incorporated	Advanced separation device and method
US4642903A (en) *	1985-03-26	1987-02-17	R. P. Scherer Corporation	Freeze-dried foam dosage form
US5084104A (en) *	1989-12-05	1992-01-28	Cultor, Ltd.	Method for recovering xylose
EP0481603A1 (de) *	1990-10-15	1992-04-22	The Dow Chemical Company	Trennung von organischen schwachen Säuren von Flüssigkeitsmischungen
US5562777A (en) *	1993-03-26	1996-10-08	Arkenol, Inc.	Method of producing sugars using strong acid hydrolysis of cellulosic and hemicellulosic materials
US5597714A (en) *	1993-03-26	1997-01-28	Arkenol, Inc.	Strong acid hydrolysis of cellulosic and hemicellulosic materials
US5407580A (en) *	1993-09-29	1995-04-18	Tennessee Valley Authority	Process for separating acid-sugar mixtures using ion exclusion chromatography
US5407817A (en) *	1993-12-23	1995-04-18	Controlled Environmental Systems Corporation	Municipal solid waste processing facility and commercial ethanol production process
US5571703A (en)	1993-12-23	1996-11-05	Controlled Environmental Systems Corporation	Municipal solid waste processing facility and commercial ethanol production process
US5482631A (en) *	1994-10-06	1996-01-09	Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College	Separation of inositols from sugars and sugar alcohols
UA43879C2 (uk) *	1994-12-07	2002-01-15	Кентроулд Інвайєронментал Сістемз Корпорейшн	Спосіб одержання молочної кислоти з міських твердих відходів (варіанти) та спосіб одержання молочної кислоти з целюлозного компонента міських твердих відходів
US5560827A (en) *	1995-02-02	1996-10-01	Tennessee Valley Authority	Exclusion chromatographic separation of ionic from nonionic solutes
US5651895A (en) *	1995-02-21	1997-07-29	Envirocorp Services & Technology	Heavy metals removal

1998
- 1998-03-17 US US09/042,587 patent/US5968362A/en not_active Expired - Lifetime
- 1998-08-03 PL PL98338389A patent/PL338389A1/xx unknown
- 1998-08-03 AU AU86802/98A patent/AU747398B2/en not_active Ceased
- 1998-08-03 CN CNB988078643A patent/CN1145514C/zh not_active Expired - Fee Related
- 1998-08-03 HU HU0004550A patent/HUP0004550A3/hu unknown
- 1998-08-03 IL IL13409898A patent/IL134098A/en not_active IP Right Cessation
- 1998-08-03 JP JP2000504938A patent/JP2001511418A/ja not_active Withdrawn
- 1998-08-03 EP EP98938229A patent/EP1027122A4/de not_active Withdrawn
- 1998-08-03 WO PCT/US1998/015991 patent/WO1999006133A1/en not_active Ceased
- 1998-08-03 BR BR9811487-5A patent/BR9811487A/pt not_active Application Discontinuation
- 1998-08-03 NZ NZ502461A patent/NZ502461A/en unknown
- 1998-08-03 AP APAP/P/2000/001741A patent/AP1129A/en active
- 1998-08-03 EA EA200000201A patent/EA002483B1/ru not_active IP Right Cessation
- 1998-08-03 CA CA002299257A patent/CA2299257A1/en not_active Abandoned
1999
- 1999-07-16 US US09/354,666 patent/US6391204B1/en not_active Expired - Fee Related
2000
- 2000-01-25 NO NO20000368A patent/NO20000368L/no not_active Application Discontinuation
- 2000-02-01 OA OA1200000023A patent/OA11315A/en unknown
- 2000-10-23 US US09/694,017 patent/US6419828B1/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
US6391204B1 (en)	2002-05-21
CA2299257A1 (en)	1999-02-11
HUP0004550A3 (en)	2003-02-28
EA200000201A1 (ru)	2000-08-28
NO20000368D0 (no)	2000-01-25
EP1027122A1 (de)	2000-08-16
CN1145514C (zh)	2004-04-14
AP2000001741A0 (en)	2000-03-31
AP1129A (en)	2002-12-07
AU8680298A (en)	1999-02-22
EP1027122A4 (de)	2002-02-13
HUP0004550A2 (hu)	2001-06-28
US6419828B1 (en)	2002-07-16
CN1270538A (zh)	2000-10-18
IL134098A0 (en)	2001-04-30
NZ502461A (en)	2002-03-01
EA002483B1 (ru)	2002-06-27
JP2001511418A (ja)	2001-08-14
BR9811487A (pt)	2000-09-19
NO20000368L (no)	2000-01-25
PL338389A1 (en)	2000-10-23
US5968362A (en)	1999-10-19
IL134098A (en)	2004-06-01
WO1999006133A1 (en)	1999-02-11
AU747398B2 (en)	2002-05-16

Publication	Publication Date	Title
AU747398B2 (en)	2002-05-16	Method for the separation of acid from sugars
CN109705175B (zh)	2022-07-05	使用模拟移动床色谱纯化中性人乳寡糖的方法
EP1737550B1 (de)	2016-03-09	Gewinnung von anorganischem salz bei der verarbeitung von lignocellulosehaltigen einsatzstoffen
US9233906B2 (en)	2016-01-12	Purification of succinic acid from the fermentation broth containing ammonium succinate
US20090023187A1 (en)	2009-01-22	Method of obtaining a product sugar stream from cellulosic biomass
EP2847342B1 (de)	2020-08-12	Reinigung von bernsteinsäure
AU2020375503B2 (en)	2024-05-02	Improved method for manufacturing allulose
CN105238841A (zh)	2016-01-13	头孢菌素c吸附废液中dcpc的回收与转化方法
US7364880B2 (en)	2008-04-29	Integration of at least two processes to re-use acid
IL152887A (en)	2004-06-20	Method for the separation of acids from sugars
MXPA00001030A (en)	2001-05-07	Method for the separation of acid from sugars
HK1032212A (en)	2001-07-13	Method for the separation of acid from sugars
CZ2000261A3 (cs)	2000-09-13	Způsob separace kyseliny z cukrů
AU2006233711A1 (en)	2006-10-19	Method for recovering a basic amino acid from a fermentation liquor
KR19990064154A (ko)	1999-07-26	산 생성물을 회수하기 위한 열-처리 분리 및탈수 방법
HK40008041B (en)	2023-04-06	Process for purification of a neutral human milk oligosaccharide using simulated moving bed chromatography
HK40008041A (en)	2020-06-12	Process for purification of a neutral human milk oligosaccharide using simulated moving bed chromatography