OA12082A - Method for the preparation of hydrogenated hydrocarbons. - Google Patents

Method for the preparation of hydrogenated hydrocarbons. Download PDF

Info

Publication number: OA12082A
Authority: OA; OAPI
Prior art keywords: hydrogenated; préparation; drocarbons; treatment; gas
Prior art date: 2000-02-03

Application number

OA1200200131A

Other languages

English (en)

Inventor

Giuseppe Bellussi

Alberto Delbianco

Luigina Maria Flora Sabatino

Roberto Zennaro

Mario Molinari

Original Assignee

Enitecnologie Spa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2000-02-03

Filing date

2001-01-25

Publication date

2006-05-04

2001-01-25 Application filed by Enitecnologie Spa filed Critical Enitecnologie Spa

2006-05-04 Publication of OA12082A publication Critical patent/OA12082A/en

Links

238000000034 method Methods 0.000 title claims abstract description 42
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 28
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 27
238000002360 preparation method Methods 0.000 title abstract description 3
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 79
239000000203 mixture Substances 0.000 claims abstract description 39
239000003054 catalyst Substances 0.000 claims abstract description 20
239000003345 natural gas Substances 0.000 claims abstract description 12
150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 7
239000007789 gas Substances 0.000 claims description 35
230000003197 catalytic effect Effects 0.000 claims description 8
238000007669 thermal treatment Methods 0.000 claims description 8
230000000737 periodic effect Effects 0.000 claims description 3
SGPGESCZOCHFCL-UHFFFAOYSA-N Tilisolol hydrochloride Chemical compound [Cl-].C1=CC=C2C(=O)N(C)C=C(OCC(O)C[NH2+]C(C)(C)C)C2=C1 SGPGESCZOCHFCL-UHFFFAOYSA-N 0.000 claims 1
239000012530 fluid Substances 0.000 claims 1
125000004122 cyclic group Chemical group 0.000 abstract 1
238000005984 hydrogenation reaction Methods 0.000 abstract 1
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 33
238000006243 chemical reaction Methods 0.000 description 33
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 21
239000000047 product Substances 0.000 description 19
230000008569 process Effects 0.000 description 14
238000004519 manufacturing process Methods 0.000 description 11
239000010457 zeolite Substances 0.000 description 11
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 9
229940075566 naphthalene Drugs 0.000 description 9
239000003921 oil Substances 0.000 description 9
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
238000005899 aromatization reaction Methods 0.000 description 7
239000001257 hydrogen Substances 0.000 description 7
229910052739 hydrogen Inorganic materials 0.000 description 7
239000007788 liquid Substances 0.000 description 7
229910052751 metal Inorganic materials 0.000 description 7
239000002184 metal Substances 0.000 description 7
150000002739 metals Chemical class 0.000 description 7
239000012071 phase Substances 0.000 description 7
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
239000005977 Ethylene Substances 0.000 description 6
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
229910021536 Zeolite Inorganic materials 0.000 description 6
229910052799 carbon Inorganic materials 0.000 description 6
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 6
239000000306 component Substances 0.000 description 5
230000009466 transformation Effects 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
150000001491 aromatic compounds Chemical class 0.000 description 3
239000001273 butane Substances 0.000 description 3
239000000446 fuel Substances 0.000 description 3
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
230000006835 compression Effects 0.000 description 2
238000007906 compression Methods 0.000 description 2
239000010779 crude oil Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000005755 formation reaction Methods 0.000 description 2
229910052733 gallium Inorganic materials 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
239000012263 liquid product Substances 0.000 description 2
229910052750 molybdenum Inorganic materials 0.000 description 2
-1 naphthene com-pounds Chemical class 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
229910052763 palladium Inorganic materials 0.000 description 2
229910052697 platinum Inorganic materials 0.000 description 2
238000002203 pretreatment Methods 0.000 description 2
239000001294 propane Substances 0.000 description 2
238000011084 recovery Methods 0.000 description 2
229910052707 ruthenium Inorganic materials 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
229910052720 vanadium Inorganic materials 0.000 description 2
QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical class C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000004913 activation Effects 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000003795 desorption Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
MEKDPHXPVMKCON-UHFFFAOYSA-N ethane;methane Chemical compound C.CC MEKDPHXPVMKCON-UHFFFAOYSA-N 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000003446 ligand Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
230000003340 mental effect Effects 0.000 description 1
239000003863 metallic catalyst Substances 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
229910000510 noble metal Inorganic materials 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
238000005691 oxidative coupling reaction Methods 0.000 description 1
238000007353 oxidative pyrolysis Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
230000036647 reaction Effects 0.000 description 1
239000011819 refractory material Substances 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
238000000844 transformation Methods 0.000 description 1
230000001131 transforming effect Effects 0.000 description 1
230000007704 transition Effects 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000001993 wax Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/929—Special chemical considerations
- Y10S585/943—Synthesis from methane or inorganic carbon source, e.g. coal

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Medicinal Preparation (AREA)
Catalysts (AREA)

OA1200200131A 2000-02-03 2001-01-25 Method for the preparation of hydrogenated hydrocarbons. OA12082A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT2000MI000166A IT1317757B1 (it)	2000-02-03	2000-02-03	Metodo per la preparazione di idrocarburi idrogenati.

Publications (1)

Publication Number	Publication Date
OA12082A true OA12082A (en)	2006-05-04

Family

ID=11443876

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
OA1200200131A OA12082A (en)	2000-02-03	2001-01-25	Method for the preparation of hydrogenated hydrocarbons.

Country Status (7)

Country	Link
US (1)	US7176342B2 (no)
AU (1)	AU2001240546A1 (no)
GB (1)	GB2371557B (no)
IT (1)	IT1317757B1 (no)
NO (1)	NO330242B1 (no)
OA (1)	OA12082A (no)
WO (1)	WO2001056957A1 (no)

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2000
- 2000-02-03 IT IT2000MI000166A patent/IT1317757B1/it active
2001
- 2001-01-25 AU AU2001240546A patent/AU2001240546A1/en not_active Abandoned
- 2001-01-25 US US10/110,782 patent/US7176342B2/en not_active Expired - Lifetime
- 2001-01-25 WO PCT/EP2001/000826 patent/WO2001056957A1/en not_active Ceased
- 2001-01-25 OA OA1200200131A patent/OA12082A/en unknown
- 2001-01-25 GB GB0209609A patent/GB2371557B/en not_active Expired - Lifetime
2002
- 2002-04-26 NO NO20022010A patent/NO330242B1/no not_active IP Right Cessation

Also Published As

Publication number	Publication date
US7176342B2 (en)	2007-02-13
IT1317757B1 (it)	2003-07-15
GB0209609D0 (en)	2002-06-05
NO330242B1 (no)	2011-03-14
WO2001056957A1 (en)	2001-08-09
GB2371557B (en)	2004-02-18
NO20022010L (no)	2002-06-13
AU2001240546A1 (en)	2001-08-14
ITMI20000166A1 (it)	2001-08-03
GB2371557A (en)	2002-07-31
ITMI20000166A0 (it)	2000-02-03
US20040015025A1 (en)	2004-01-22
NO20022010D0 (no)	2002-04-26

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