PL10123B1 - Moist fuel dehydration method. - Google Patents

Moist fuel dehydration method. Download PDF

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Publication number
PL10123B1
PL10123B1 PL10123A PL1012327A PL10123B1 PL 10123 B1 PL10123 B1 PL 10123B1 PL 10123 A PL10123 A PL 10123A PL 1012327 A PL1012327 A PL 1012327A PL 10123 B1 PL10123 B1 PL 10123B1
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PL
Poland
Prior art keywords
fuel
water
pressure
liquid
tar
Prior art date
Application number
PL10123A
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Polish (pl)
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Publication date
Application filed filed Critical
Publication of PL10123B1 publication Critical patent/PL10123B1/en

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Description

Usuwanie wody z róznych gatunków wegla, szczególnie z wegla brunatnego, smól, olejów mineralnych, torfu, drzewa i podobnego paliwa wilgotnego, posiada w praktyce doniosle znaczenie, szczególnie gdy materjaly te maja podlegac dalszej obróbce wodorem lub gazami wydzielaj a- cemi tenze pod cisnieniem w temperaturze podwyzszonej, w celu uzyskiwania cennych a zwlaszcza niskowrzacych cieczy. Odwad¬ nianie usilowano osiagnac najrozmaitszemi sposobami, np. zapomoca wirowania, stla- czania, ekstrakcji i t. d,; w wiekszosci jed¬ nak przypadków odwadnianie to bylo nie¬ dostateczne lub uciazliwe, Okazalo sie obecnie, ze wode mozna u- sunac w sposób bardzo prosty, przez ogrza¬ nie wilgotnego paliwa z innem paliwem, pozostajacem w warunkach pracy w stanie plynnym, albo przez ogrzewanie wilgotne¬ go paliwa plynnego do temperatury powy¬ zej 200"C, stosujac cisnienia przekraczaja¬ ce kazdorazowe cisnienie pary wodnej, aby woda wydzielala sie praktycznie zupelnie w stanie plynnym. Przewazajaca czesc wo¬ dy wydziela sie wówczas nader szybko i mozna ja spuscic w stanie plynnym.W celu osiagniecia zupelnego wysusze¬ nia paliwa mozna proces powtórzyc, ewen¬ tualnie, kilkakrotnie.Szczególne znaczenie techniczne posia¬ da sposób niniejszy przy uszlachetnianiu róznych gatunków wegla, smól, olejów mi¬ neralnych i cial podobnych zapomoca wo-doru lub wydzielajacych go gazów, albo¬ wiem materjaly wyjsciowe dla procesu te¬ go ulegaja *w mysl wynalazku niniejszego podsuszaniu i w stanie suchym, albo z okre¬ slona zawartoscia wody, moga byc dopro¬ wadzane w stanie podgrzanym prawie do temperatury reakcji.Równiez i cieplo wody wydzielonej mozna wyzyskac, np. do podgrzewania swiezych ilosci materjalu bioracego udzial w reakcji.Suszenie i wydzielanie wody mozna po¬ nadto przyspieszyc, stosujac inne srodki pomocnicze, jako to mieszanie, wirowanie, kolejno ruch i odstawanie, dzialanie pola elektrycznego, domieszki przyspieszajace i srodki podobne. Naj wlasciwiej jest prowa¬ dzic ogrzewanie podlegajacego suszeniu materjalu w sposób ciagly w wezownicy, z której produkt przechodzi do rozdziela¬ cza, gdzie nastepuje podzial. Szczególna zalete sposobu stanowi okolicznosc, ze ob¬ rabiane materjaly nie ulegaja zmianom, jak to ma miejsce np. przy suszeniu gorace- mi gazami.Sposób niniejszy mozna z korzyscia stosowac równiez i wówczas, gdy woda po¬ wstaje dopiero w reakcji, jak to ma miej¬ sce np. przy obróbce zawierajacego tlen wegla para wodna pod cisnieniem i w tem¬ peraturze podniesionej.Przyklad. Surowy wegiel brunatny, za¬ wierajacy 50% wody, zadaje sie równa mu {na wage) iloscia smoly i ogrzewa pod ci¬ snieniem mechanicznem okolo 200 atm do 320°. Po usunieciu szybko wydzielajacej sie wody, produkt podgrzany poddaje sie dalszej obróbce wodorem pod cisnieniem, np. wedlug patentu Nr 8345, w celu wy¬ tworzenia cennych weglowodorów.Najwlasciwiej i najoszczedniej pokryc zapotrzebowanie ciepla niezbednego do od¬ wodniania czesciowo lub calkowicie cieplem wyzwalanem prey skraplaniu weglowodo¬ rów, powstajacych wskutek wzmiankowa¬ nej obróbki wodorem.W sposób podobny mozna wysuszyc smole surowa z wegla brunatnego o 50% wilgotnosci. Zawartosc wilgoci w smole mozna obnizyc w pierwszem stadjum pra¬ cy do 10—15%, w drugiem zas — wilgoc calkowicie usunac, PLRemoval of water from various types of coal, especially lignite, tar, mineral oils, peat, wood and similar moist fuel, is of great importance in practice, especially when these materials are to be further treated with hydrogen or gases that emit acemi tenze under pressure at elevated temperature in order to obtain valuable, especially low-boiling liquids. Attempts have been made to achieve dehydration by a variety of methods, for example by centrifugation, decay, extraction, etc. in most cases, however, this drainage was insufficient or inconvenient. It has now turned out that water can be disposed of very simply, by heating a wet fuel with another fuel, while operating in a liquid state, or by heating the wet liquid fuel to a temperature above 200 ° C, using pressures exceeding the pressure of the steam in each case, so that the water is released practically completely liquid. Most of the water then emits very quickly and can be drained into In order to achieve a complete drying of the fuel, the process may be repeated, possibly several times. The present method is of particular technical importance in the refining of various types of coal, tar, mineral oils and similar bodies that emit hydrogen or give off water. gases, or the starting materials for this process are subject to drying in the dry state in the sense of the present invention, or with a specific the water content, in a heated state, can be brought almost to the reaction temperature. The heat of the separated water can also be exploited, e.g. for heating fresh amounts of the material involved in the reaction. Drying and water separation can also be accelerated by using other auxiliaries. such as mixing, spinning, sequentially moving and standing, electric field action, accelerating admixtures and the like. It is most appropriate to heat the material to be dried continuously in the coil from which the product passes to the separator where it splits. A particular advantage of the process is the fact that the treated materials do not change, as is the case, for example, with hot gas drying. The present method can also be used advantageously when the water is only reacted as required. This occurs, for example, when treating oxygen-containing carbon with steam under pressure and at elevated temperature. The raw brown coal, containing 50% of water, is taken up to an equal (by weight) amount of tar and heated under a mechanical pressure of about 200 atm to 320 °. After the rapidly evolving water is removed, the heated product is further treated with hydrogen under pressure, e.g. according to patent No. 8345, in order to produce valuable hydrocarbons. It is most efficient and cost-effective to meet the heat requirement for dehydration partially or completely with heat released by condensation pre-treatment. the hydrocarbons formed by the aforementioned hydrotreatment. In a similar manner it is possible to dry tar raw lignite with 50% humidity. The moisture content of the tar can be reduced in the first stage of work to 10-15%, and in the second stage - the moisture content may be completely removed, PL

Claims (1)

1. Zastrzezenie patentowe. Sposób odwadniania paliwa wilgotne¬ go, jako to rozmaitych gatunków wegla, smól, olejów mineralnych, torfu, drzewa i materjalów podobnych, znamienny tern, ze paliwo stale ogrzewa sie wraz z paliwem plynnem albo samo paliwo plynne dopro¬ wadza sie do temperatury powyzej 200°, stosujac cisnienie naj wlasciwiej przekra¬ czajace kazdorazowe cisnienie pary wod¬ nej, przyczem woda wydziela sie praktycz¬ nie w zupelnosci w stanie plynnym, odda¬ jac swe cieplo np. materjalowi wyjsciowe¬ mu, dzieki czemu otrzymuje sie w warun¬ kach najkorzystniejszych przetwór., nada¬ jacy sie do uwodorniania pod cisnieniem. L G, Farbenindustrie Akt i en gesellschaft. Zastepca: M. Skrzypkowski, rzecznik patentowy. Druk L. Boguslawskiego, Warszawa. PL1. Patent claim. A method of dewatering wet fuel, such as various types of coal, tar, mineral oils, peat, wood and similar materials, characterized by the fact that the fuel is constantly heated with the liquid fuel or the liquid fuel itself is brought to a temperature above 200 ° C by applying a pressure most in excess of the steam pressure in each case, the water is practically completely completely liquid, giving off its heat to, for example, the starting material, thanks to which it is obtained under the most favorable processing conditions ., capable of being hydrogenated under pressure. L G, Farbenindustrie Akt and en gesellschaft. Deputy: M. Skrzypkowski, patent attorney. Print by L. Boguslawski, Warsaw. PL
PL10123A 1927-07-18 Moist fuel dehydration method. PL10123B1 (en)

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PL10123B1 true PL10123B1 (en) 1929-04-30

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