PL101630B1 - AN INSECTICIDE SPECIALLY AGAINST COLORADO POTATO BEETLE - Google Patents
AN INSECTICIDE SPECIALLY AGAINST COLORADO POTATO BEETLE Download PDFInfo
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- PL101630B1 PL101630B1 PL19085376A PL19085376A PL101630B1 PL 101630 B1 PL101630 B1 PL 101630B1 PL 19085376 A PL19085376 A PL 19085376A PL 19085376 A PL19085376 A PL 19085376A PL 101630 B1 PL101630 B1 PL 101630B1
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- phosphate
- insecticide
- dimethyl
- dichlorophenyl
- colorado potato
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- 239000002917 insecticide Substances 0.000 title claims description 12
- 241000258916 Leptinotarsa decemlineata Species 0.000 title claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- 239000004480 active ingredient Substances 0.000 claims description 5
- IIMQBSMLPGKJKO-UHFFFAOYSA-N (2,4-dichlorophenyl) dihydrogen phosphate Chemical compound OP(O)(=O)OC1=CC=C(Cl)C=C1Cl IIMQBSMLPGKJKO-UHFFFAOYSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 description 16
- 239000010452 phosphate Substances 0.000 description 16
- 239000000203 mixture Substances 0.000 description 13
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- MSHXTAQSSIEBQS-UHFFFAOYSA-N s-[3-carbamoylsulfanyl-2-(dimethylamino)propyl] carbamothioate;hydron;chloride Chemical compound [Cl-].NC(=O)SCC([NH+](C)C)CSC(N)=O MSHXTAQSSIEBQS-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- -1 (2,4-dichlorophenyl) -2-bromovinyl Chemical group 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- HCOUCSPSOOLMCL-UHFFFAOYSA-N C1=CC(=C(C=C1Cl)Cl)C(=COP(=O)(O)O)Br Chemical compound C1=CC(=C(C=C1Cl)Cl)C(=COP(=O)(O)O)Br HCOUCSPSOOLMCL-UHFFFAOYSA-N 0.000 description 6
- 241000238631 Hexapoda Species 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 241000257303 Hymenoptera Species 0.000 description 5
- 241001465754 Metazoa Species 0.000 description 4
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 description 4
- 230000000749 insecticidal effect Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 125000004201 2,4-dichlorophenyl group Chemical group [H]C1=C([H])C(*)=C(Cl)C([H])=C1Cl 0.000 description 3
- 244000061456 Solanum tuberosum Species 0.000 description 3
- GXJQMKFJQFGQKV-KHPPLWFESA-N 2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS(O)(=O)=O GXJQMKFJQFGQKV-KHPPLWFESA-N 0.000 description 2
- ORDKAVSHIKNMAN-XYOKQWHBSA-N [(e)-2-bromo-1-(2,4-dichlorophenyl)ethenyl] diethyl phosphate Chemical compound CCOP(=O)(OCC)O\C(=C\Br)C1=CC=C(Cl)C=C1Cl ORDKAVSHIKNMAN-XYOKQWHBSA-N 0.000 description 2
- FSAVDKDHPDSCTO-WQLSENKSSA-N [(z)-2-chloro-1-(2,4-dichlorophenyl)ethenyl] diethyl phosphate Chemical compound CCOP(=O)(OCC)O\C(=C/Cl)C1=CC=C(Cl)C=C1Cl FSAVDKDHPDSCTO-WQLSENKSSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- XXPRRHYTDCWGRP-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-(4-nonylphenoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 XXPRRHYTDCWGRP-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
- JBGFYJXVXHRGJW-UHFFFAOYSA-N OP(O)(OC=C(C(C(Cl)=C1)=CC=C1Cl)Cl)=O Chemical compound OP(O)(OC=C(C(C(Cl)=C1)=CC=C1Cl)Cl)=O JBGFYJXVXHRGJW-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 150000001875 compounds Chemical group 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- MQJUTXAYGNUBKO-UHFFFAOYSA-M sodium;3,7-ditert-butylnaphthalene-2-sulfonate Chemical compound [Na+].C1=C(C(C)(C)C)C(S([O-])(=O)=O)=CC2=CC(C(C)(C)C)=CC=C21 MQJUTXAYGNUBKO-UHFFFAOYSA-M 0.000 description 1
- 239000002426 superphosphate Substances 0.000 description 1
- 238000001356 surgical procedure Methods 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004552 water soluble powder Substances 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Przedmiotem wynalazku jest srodek owadobójczy którego substancje czynna stanowi mieszanina znanych substancji owadobójczych.The subject of the invention is an insecticide whose active ingredients are a mixture of known ones insecticides.
Fosforan 0,0-dwumetylo-0-l(2,4-dwuchlorofenylo)-2-bromowinylowy wykazuje znacznie slabsza aktyw¬ nosc owadobójcza w stosunku do stonki ziemniaczanej niz typowe insektycydy z grupy zwiazków fosforoorga¬ nicznych: fosforan 0,0-dwuetylo-0-l (2,4-dwuchlorofenylo)-2-chlorowinylowy (chlorfenwinfos) oraz fosforan 0,0-dwuetylo-0-l (2,4-dwuchlorofenylo)-2-bromowinylowy (bromfenwinfos). Zaleta fosforanu 0,0-dwumetylo-0- 1 (2,4-dwuchlorofenylo)-2-bromowinylowego jest jego stosunkowo niska toksycznosc dla czlowieka i zwierzat wyzszych, w przeciwienstwie do toksycznosci chlorfenwinfosu i bromfenwinfosu. W warunkach polowych nie stwierdzono ujemnego wplywu na pszczoly fosforanu 0,0-dwumetylo-0-l (2,4-dwuchlorofenylo)-2-bromowiny- lowego, przy zastosowaniu tej substancji w dawce 0,5 kg/ha. Jednakze w dawkach wyzszych substancja ta moze wykazywac ujemny wplyw na pszczoly, gdyz wedlug przyjetej klasyfikacji, na podstawie badan laboratoryjnych nalezy zaliczyc ja do insektycydów trujacych dla pszczól.O, O-dimethyl-O-l (2,4-dichlorophenyl) -2-bromovinyl phosphate shows much lower activity insecticidal activity against the Colorado potato beetle than typical insecticides from the group of organophosphorus compounds of the following: 0.0-diethyl-O-l (2,4-dichlorophenyl) -2-chlorovinyl phosphate (chlorphenvinphos) and phosphate 0.0-diethyl-O-l (2,4-dichlorophenyl) -2-bromovinyl (bromfenvinphos). Advantage of 0.0-Dimethyl-O- Phosphate 1 (2,4-dichlorophenyl) -2-bromovinyl is relatively low toxic to humans and animals higher, in contrast to the toxicity of chlorfenvinphos and bromfenvinphos. In the field, no 0.0-dimethyl-0-l (2,4-dichlorophenyl) -2-bromovine phosphate was found to have a negative effect on bees at the rate of 0.5 kg / ha of this substance. However, at higher doses, this substance can show a negative effect on bees, because according to the adopted classification, on the basis of laboratory tests it is one of the insecticides poisonous to bees.
Znane jest stosowanie w ochronie roslin chlorowodorku l,3-dwu(karbamylotio)-2-N-dwumetyloaminopro- panu (kartap). Jest to zwiazek chemiczny o stosunkowo niskiej toksycznosci dla ludzi oraz zwierzat stalociepl¬ nych i pszczól. Kartap wykazuje silne dzialanie owadobójcze szczególnie w stosunku do stonki ziemniaczanej, jednakze w dawkach wyzszych (0,5-0,75 kg/ha). Preparaty zawierajace kartap stosowane sa w postaci granulowanej oraz proszku do opylania i proszku rozpuszczalnego w wodzie (nazwa handlowa: Padan).It is known to use the hydrochloride of 1,3-di (carbamylthio) -2-N-dimethylaminoprop in plant protection. to you (kartap). It is a chemical compound of relatively low toxicity to humans and animals in heat-heat and bees. Kartap has a strong insecticidal effect, especially against the Colorado potato beetle, however, at higher doses (0.5-0.75 kg / ha). Preparations containing the carton are used in the form of granulated, dusting powder and water-soluble powder (trade name: Padan).
Stwierdzono nieoczekiwanie, ze mieszanina fosforanu 0,0-dwumetylo-0-l (2,4-dwuchlorofenylo)-2-bromo- winylowego z chlorowodorkiem l,3-dwu(karbamylotio)-2-N-dwumetyloaminopropanu wykazuje dzialanie syner- giczne.It has surprisingly been found that a mixture of 0,0-dimethyl-O-l (2,4-dichlorophenyl) -2-bromo phosphate of vinyl with 1,3-di (carbamylthio) -2-N-dimethylaminopropane hydrochloride shows a synergistic gical.
Istota wynalazku polega na zastosowaniu w srodku owadobójczym jako substancji czynnej mieszaniny fosforanu 0,0-dwumetylo-0-l (2,4-dwuchlorofenylo)-2-bromowinylowego z chlorowodorkiem l ,3-dwu(karbamy- lotio) -2-N-dwumetyloaminopropanu w proporcji na kazdklDO czesci fosforanu 0,0-dwumetylo-0-l)2,4-dwuchle~ rofenylo)-2-bromowinylowego 10-1000 czesci chlorowodorku i 1,3- dwu(karbamylotio)-2-N^wumetyloamino- propanu.2 101 630 Srodek owadobójczy bedacy przedmiotem niniejszego wynalazku stosowany nawet w malych ilosciach dziala bardzo skutecznie zarówno na populacje owadów wrazliwych jak i odpornych na DDT. Srodek charakteryzuje sie niska toksycznoscia dla ludzi i zwierzat wyzszych, nie kumuluje sie w srodowisku i w tkankach zwierzecych. Na skutek stosowania w niskich dawkach fosforan 0,0-dwumctylo-0-l(2,4-dwuchlorofenylo)-2-bro- mowinylowy, bedacy skladnikiem mieszaniny, jest bezpieczny dla pszczól; jednoczesnie srodowisko ulega mniejszemu schemizowaniu. Z uwagi na swoje wlasciwosci srodek ten moze znalezc szerokie zastosowanie szczególnie w zwalczaniu stonki ziemniaczanej na ziemniakach.The essence of the invention consists in the use of a mixture in an insecticide as an active ingredient 0,0-dimethyl-O-l (2,4-dichlorophenyl) -2-bromovinyl phosphate with 1,3-di (carbam- lotio) -2-N-dimethylaminopropane in proportion to each part of the phosphate 0,0-dimethyl-0-l) 2,4-dibi ~ rophenyl) -2-bromovinyl 10-1000 parts of hydrochloride and 1,3- di (carbamylthio) -2-N- vumethylamino- propane. 2 101 630 The insecticide object of the present invention is used even in small amounts has a very effective effect on populations of both sensitive and DDT resistant insects. Center is characterized by low toxicity to humans and higher animals, does not accumulate in the environment and in tissues animals. As a result of the use of low doses, 0.0-dimethyl-O-l (2,4-dichlorophenyl) -2-bromo phosphate mvinyl, which is a component of the mixture, is safe for bees; at the same time the environment succumbs less schematic. Due to its properties, this measure can be used widely especially in the control of the Colorado potato beetle on potatoes.
Wyniki badan biologicznych przedstawiono., w tablicach I, II i III.The results of biological tests are presented in Tables I, II and III.
Tablica I, Dzialanie owadobójcze mieszaniny fosforanu 0,0-dwumetylo-CM (2,4-dwuchlorofenylo)-2- bromowinylowego i chlorowodorku 1,3-dwu(karbamylotio)-2-N-dwumetylo- aminopropanu na stonke ziemniaczana Sklad imieszaniny w procentach kartap 0 27 50 70 83 100 fosforan j.w. 100 73 50 17 0 Dawka (mcg/szt).Table I, Insecticidal activity of the phosphate mixture 0,0-dimethyl-CM (2,4-dichlorophenyl) -2- bromovinyl and hydrochloride 1,3-two (carbamylthio) -2-N-dimethyl- aminopropane on the Colorado potato beetle Composition and mixture in percents cartap 0 27 50 70 83 100 phosphate as above 100 73 50 17 0 Dose (mcg / pc).
LD50 0,93 0,94 1,12 1,16 1,18 2,70 LD,0 2,55 2,68 2,95 2,92 3,61 6,70 Badania przeprowadzono metoda topical application stosujac roztwory preparatów w ilosci mci/chrzaszcza stonki ziemniaczanej. Dawki LD50 i LD90 powodujace odpowiednio 50% i 90% smiertelnosci owadów testowych okreslano z 5 zastosowanych stezen metoda logarytmiczno-probitowa.LD50 0.93 0.94 1.12 1.16 1.18 2.70 LD, 0 2.55 2.68 2.95 2.92 3.61 6.70 The research was carried out using the topical application method using the amount of the preparation solutions mci / Colorado potato beetle. LD50 and LD90 doses causing 50% and 90% mortality respectively The test insects were determined by the logarithmic-probit method from 5 applied concentrations.
Sposród badanych wariantów mieszaniny najwyzszy synergizm wykazal preparat zawierajacy 83% kartapu i 17% fosforanu, rózniac sie nieistotnie w LD90 od dzialania stonkobójczego wariantu mieszaniny zawierajacej 70% kartapu i 30% fosforanu 0,0-dwumetylo-0-l(2,4-dwuchlorofenylo)-2-bromowinylowego.Among the tested variants of the mixture, the highest synergism was shown by the preparation containing 83% of cartap and 17% phosphate, not significantly different in LD90 from the stonicidal effect of the variant of the mixture containing 70% cartap and 30% 0.0-dimethyl-O-l (2,4-dichlorophenyl) -2-bromovinyl phosphate.
Tablica II Badanie szybkosci dzialania owadobójczego na stonke ziemniaczana mieszaniny fosforanu 0,0-dwumetylo-0-l(2,4-dwuchlorofenylo)-2-bromowinylowego i chlorowodorku l,3-dwu(karbamyiotio)-2-N-dwumetyloaminopropanu w proporcji 30% + 70%, Substancja badana Kartap Fosforan 0,0-dwumetylo- 0-1(2,4-dwuchlorofeny- lo)-2-bromowinylowy Kartap 70% + fosforan j.w. 30% Ilosc godzin jaka uplynela LT50 — poczatek dzialania ,3 6,7 3,9 LT50 -50% skutecznosci 14,4 12,0 7,9 od zabiegu LT95 -95% skutecznosci 40,0 ,0 16,0 Ilosc godzin w ciagu których zginelo 90% owadów (LT9S-LT$) 34,7 18,3 12,1101 630 3 Badania przeprowadzono metoda testu kontaktowo-pokarmowego dozujac roztwory preparatów przy pomocy wiezy POTTER'A jednoczesnie na rosliny ziemniaka i chrzaszcze stonki ziemniaczanej w ilosci 2 ml/100 cm2. Zastosowano stezenie 0,5% substancji czynnej. Obserwacje smiertelnosci owadów wykonywano w odstepach 30-minutowych az do wystapienia smiertelnosci powyzej 85% a nastepnie w wiekszych odstepach czasu. Srednie czasy wymierania 5%, 50% i 95% populacji okreslono metoda logarytmiczno-probitowa.Table II Test of the rate of insecticidal action on the Colorado potato beetle of the phosphate mixture 0.0-dimethyl-O-l (2,4-dichlorophenyl) -2-bromovinyl and 1,3-di (carbamyiotio) -2-N-dimethylaminopropane hydrochloride in the proportion of 30% + 70%, Test substance Kartap 0,0-dimethyl-phosphate 0-1 (2,4-dichlorophenes- lo) -2-bromovinyl Cartap 70% + phosphate as above thirty% The number of hours that have passed LT50 - the beginning actions , 3 6.7 3.9 LT50 -50% effectiveness 14.4 12.0 7.9 from surgery LT95 -95% effectiveness 40.0 , 0 16.0 Number of hours within which 90% died insects (LT9S-LT $) 34.7 18.3 12.1101 630 3 The research was carried out using the food contact test method, dispensing the solutions of the preparations at help POTTER's tower simultaneously on the potato plants and the Colorado potato beetles in the amount of 2 ml / 100 cm2. A concentration of 0.5% active ingredient was used. Observations of the insect mortality were made in intervals of 30 minutes until the occurrence of a mortality above 85% and then at greater intervals time. The mean times of extinction of 5%, 50% and 95% of the population were determined by the log-probit method.
Sposród badanych preparatów najwyzsza szybkosc dzialania wykazala mieszanina kartapu i fosforanu 0,0- dwumetylo-0-l(2,4-dwuchlorofenylo)-2-bromowinylowego.Among the tested preparations, the highest speed of action was shown by a mixture of kartap and phosphate 0.0- dimethyl-O-l (2,4-dichlorophenyl) -2-bromovinyl.
Tablica III.Table III.
Badanie dzialania pokarmowo-kontaktowego mieszaniny fosforanu 0,0-dwumetylo-0-l(2,4-dwuchlorofenylo)-2- -bromowinylowego i chlorowodorku l,3-dwu(karbamylotio)-2-N-dwumetyloamino- propanu na stonke ziemniaczana Substancja badana Kartap Fosforan i.w.Study of food-contact effects phosphate mixtures 0,0-dimethyl-0-l (2,4-dichlorophenyl) -2- -bromovinyl and hydrochloride 1,3-two (carbamylthio) -2-N-dimethylamino- propane on the Colorado potato beetle Test substance Kartap Phosphate i.w.
Kartap + fosforan j.w. w proporcji 7 :3 Srednie stezenie (%) LC50 LC90 0,30 0,69 0,18 0,46 0,19 0,40 Badania przeprowadzono metoda testu kontaktowo-pokarmowego dozujac roztwory preparatów przy pomocy wiezy POTTERA jednoczesnie na rosliny ziemniaka i chrzaszcze stonki ziemniaczanej w ilosci 2 ml/100 cm2. Zastosowano po 4 stezenia roztworów. Obserwacje smiertelnosci owadów testowych wykonano w odstepach 15-minutowych. Srednie stezenia LC50 iLC90 wywolujace odpowiednio 50% i 90% smiertelnosci owadów okreslono metoda logarytmiczno-probitowa.Kartap + phosphate as above in the proportion of 7: 3 Average concentration (%) LC50 LC90 0.30 0.69 0.18 0.46 0.19 0.40 The research was carried out using the food contact test method, dispensing the solutions of the preparations at help POTTER's tower simultaneously on the potato plants and the Colorado potato beetles in the amount 2 ml / 100 cm2. 4 solution concentrations were used. Observations of the mortality of test insects were made in 15-minute intervals. Mean concentrations of LC50 and LC90 resulting in 50% and 90% mortality, respectively insects were determined by the log-probit method.
Mieszanina zawierajaca 30% fosforanu 0,0-dwumetylo-0-l(2,4-dwuchlorofenylo)-2-bromowinylowego i 70% chlorowodorku l,3-dwu(karbamylotio)-2-N-dwumetyloaminopropanu charakteryzuje sie dzialaniem synergicz- nym.Mixture of 30% 0.0-dimethyl-O-l (2,4-dichlorophenyl) -2-bromovinyl phosphate and 70% 1,3-di (carbamylthio) -2-N-dimethylaminopropane hydrochloride has a synergistic effect nym.
Srodek owadobójczy wedlug wynalazku gotowy do stosowania otrzymuje sie w zwykly sposób przez wymieszanie srodków owadobójczych, którymi sa chlorowodorek 1,3-dwu(karbamylotio)-2-N-dwumetyloamino- propanu (kartap) i fosforan 0,0-dwumetylo-0-l(2,4-dwuchlorofenylo)-2-bromowinylowy, z substancjami pomoc¬ niczymi przy pomocy typowych mieszalników i mikronizatorów jak mlyny sztyftowe lub strumieniowe. Jako substancje pomocnicze stosuje sie nosniki mineralne pochodzenia organicznego takie jak diatomit lub nieorgani¬ czne takie jak krzemionki naturalne badz syntetyczne takie jak krzemionka wytracona Arsil lub krzemionka wytracona przy produkcji superfosfatu.The insecticide according to the invention ready for use is obtained in the usual way by mixing insecticides, which are 1,3-di (carbamylthio) -2-N-dimethylamino hydrochloride propane (kartap) and 0,0-dimethyl-O-l (2,4-dichlorophenyl) -2-bromovinyl phosphate, with auxiliary substances with the use of typical mixers and micronizers, such as stick or jet mills. As auxiliary substances are mineral carriers of organic origin, such as diatomite or inorganic materials active silicas such as natural silicas or synthetic silicas such as precipitated silica Arsil or silica lost in the production of superphosphate.
Jako srodki powierzchniowo-czynne stosuje sie substancje anionoczynne takie jak sole kwasów ligninosul- fonowych (klutan), naftalenosulfonowych (Nekalina S) lub metylotauryny (Sapogen T), niejonowe substancje powierzchniowoczynne na przyklad alkilofenole zawierajace grupy oksyetylenowe (Rokafenol N-8) lub etery poliglikolowe alkoholi tluszczowych (Igepal), jako substancje pomocnicze stosuje sie metyloceluloze o nazwie Glikocel oraz kwasy organiczne takie jak octowy lub mlekowy i nieorganiczne takie jak fosforowy.Anionactive substances such as lignin acid salts are used as surfactants. phonics (klutan), naphthalenesulfonic acid (Nekalin S) or methyl taurine (Sapogen T), non-ionic substances surfactants, for example, alkylphenols containing oxyethylene groups (Rokafenol N-8) or ethers polyglycol fatty alcohols (Igepal), as auxiliary substances are methylcellulose called Glycocel and organic acids such as acetic or lactic and inorganic acids such as phosphoric.
Przyklad I. Wytracona krzemionke w ilosci 28 czesci wagowych miesza sie z kartapem w ilosci 31 czesci wagowych i fosforanem 0,0-dwumetylo-0-l(2,4~dwuchlorofenylo) -2-bromowinylowym w ilosci 11 czesci wagowych. Do otrzymanej mieszaniny dodaje sie 20 czesci wagowych diatomitu wymieszanego uprzednio z Alfanolem N-8 w ilosci 2 czesci wagowych, klutanem- 6 czesci wag. i Glikocelem w ilosci 2 czesci wagowych.Example I. Precipitated silica in an amount of 28 parts by weight is mixed with a card in an amount of 31 parts by weight and 11 parts 0.0-dimethyl-0-l (2,4-dichlorophenyl) -2-bromovinyl phosphate by weight. 20 parts by weight of the diatomite, previously mixed with 2 parts by weight with alfanol N-8, 6 parts by weight with klutan. and Glycocelem in the amount of 2 parts by weight.
Calosc miele sie przy uzyciu mlyna strumieniowego. Otrzymany srodek owadobójczy stosuje sie jako proszek do sporzadzania zawiesin wodnych.Everything is ground using a jet mill. The resulting insecticide is used as a powder for preparation of aqueous suspensions.
Przyklad II. Naturalna krzemionke w ilosci 37 czesci wagowych miesza sie z 1 czescia wagowa kwasu fosforowego, 3 czesciami Sapogenu T, 3 czesciami Glikocelu i 4 czesciami Klutanu oraz 16 czesciami fosforanu Q,0-dwumetylo-0~l(2,4-dwuchlorofenylo) -2-bromowinylowego i 36 czesciami Kartapu. Calosc miesza sie w mieszalniku np. wstegowym a nastepnie mikronizuje w mlynie strumieniowym. Otrzymany srodek owadobójczy jest gotowy do stosowania jako proszek zawiesinowy..4 101 630Example II. 37 parts by weight of natural silica is mixed with 1 part by weight of acid phosphorus, 3 parts Sapogen T, 3 parts Glikocel and 4 parts Klutan and 16 parts phosphate Q, O-dimethyl-0-1 (2,4-dichlorophenyl) -2-bromovinyl and 36 parts Kartap. Everything is mixed in in a ribbon mixer, and then micronized in a jet mill. Received insecticide it is ready to use as a wettable powder..4 101 630
Claims (1)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL19085376A PL101630B1 (en) | 1976-06-30 | 1976-06-30 | AN INSECTICIDE SPECIALLY AGAINST COLORADO POTATO BEETLE |
| RO7790874A RO71239A (en) | 1976-06-30 | 1977-06-30 | SINERGETIC INSECTICIDE COMPOSITION IN PARTICULAR AGAINST THE DORYPHORUS OF THE POTATO |
| BG036763A BG28018A3 (en) | 1976-06-30 | 1977-06-30 | Insecticide means for colorado beetle fighting |
| FR7720130A FR2356367A1 (en) | 1976-06-30 | 1977-06-30 | Synergistic insecticidal mixts. - contg. di:methyl di:chloro phenyl bromo vinyl phosphate and di:carbamoyl thio di:methyl amino propane hydrochloride |
| JP7846077A JPS5332121A (en) | 1976-06-30 | 1977-06-30 | Insecticide |
| SU772498505A SU688105A3 (en) | 1976-06-30 | 1977-06-30 | Insecticide |
| CS435777A CS190345B2 (en) | 1976-06-30 | 1977-06-30 | Insecticide means applicable notably against the colorado potato beetle |
| IN1067/CAL/77A IN146441B (en) | 1976-06-30 | 1977-07-12 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL19085376A PL101630B1 (en) | 1976-06-30 | 1976-06-30 | AN INSECTICIDE SPECIALLY AGAINST COLORADO POTATO BEETLE |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL190853A1 PL190853A1 (en) | 1978-01-30 |
| PL101630B1 true PL101630B1 (en) | 1979-01-31 |
Family
ID=19977580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL19085376A PL101630B1 (en) | 1976-06-30 | 1976-06-30 | AN INSECTICIDE SPECIALLY AGAINST COLORADO POTATO BEETLE |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5332121A (en) |
| BG (1) | BG28018A3 (en) |
| CS (1) | CS190345B2 (en) |
| FR (1) | FR2356367A1 (en) |
| IN (1) | IN146441B (en) |
| PL (1) | PL101630B1 (en) |
| RO (1) | RO71239A (en) |
| SU (1) | SU688105A3 (en) |
-
1976
- 1976-06-30 PL PL19085376A patent/PL101630B1/en not_active IP Right Cessation
-
1977
- 1977-06-30 FR FR7720130A patent/FR2356367A1/en active Pending
- 1977-06-30 SU SU772498505A patent/SU688105A3/en active
- 1977-06-30 BG BG036763A patent/BG28018A3/en unknown
- 1977-06-30 CS CS435777A patent/CS190345B2/en unknown
- 1977-06-30 JP JP7846077A patent/JPS5332121A/en active Pending
- 1977-06-30 RO RO7790874A patent/RO71239A/en unknown
- 1977-07-12 IN IN1067/CAL/77A patent/IN146441B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2356367A1 (en) | 1978-01-27 |
| BG28018A3 (en) | 1980-02-25 |
| JPS5332121A (en) | 1978-03-27 |
| CS190345B2 (en) | 1979-05-31 |
| IN146441B (en) | 1979-06-02 |
| SU688105A3 (en) | 1979-09-25 |
| PL190853A1 (en) | 1978-01-30 |
| RO71239A (en) | 1982-03-24 |
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| Date | Code | Title | Description |
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| LAPS | Decisions on the lapse of the protection rights |
Effective date: 20070916 |