PL101677B1 - A DETERGENT - Google Patents
A DETERGENT Download PDFInfo
- Publication number
- PL101677B1 PL101677B1 PL19180276A PL19180276A PL101677B1 PL 101677 B1 PL101677 B1 PL 101677B1 PL 19180276 A PL19180276 A PL 19180276A PL 19180276 A PL19180276 A PL 19180276A PL 101677 B1 PL101677 B1 PL 101677B1
- Authority
- PL
- Poland
- Prior art keywords
- weight
- amount
- wax
- washing
- low
- Prior art date
Links
- 239000003599 detergent Substances 0.000 title claims description 8
- 239000006260 foam Substances 0.000 claims description 6
- 238000005187 foaming Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000012188 paraffin wax Substances 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 230000000536 complexating effect Effects 0.000 claims description 4
- 239000002518 antifoaming agent Substances 0.000 claims description 2
- 239000003638 chemical reducing agent Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 description 11
- 239000001993 wax Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Description
Przedmiotem wynalazku jest slabo pieniacy srodek do prania bielizny w pralkach automatycznych.The subject of the invention is a low-foaming agent for washing linen in automatic washing machines.
Dotychczas znane sa i stosowane rózne slabo pieniace srodki do prania w sklad których wchodza: zwiazki powierzchniowo-czynne w ilosci 8—15% wagowych, zwiazki kompleksujace w ilosci 30—45% wagowych, wypelniacze aktywne w ilosci 30—60% wagowych oraz inne skladniki. Srodki te jako substancje obnizajace pienienie zawieraja silikony, wysokoczasteczkowe kwasy tluszczowe wzglednie niejonowe zwiazki powierzchnio¬ wo-czynne. Wada ich jest to, ze w niedostatecznym stopniu obnizaja wlasciwosci pianotwórcze co ma duze znaczenie przy praniu w pralkach automatycznych. Produkt o odpowiednio niskiej pianie mozna uzyskac wprowadzajac wieksze ilosci wspomnianych wyzej skladników np. powyzej 6% detergentów niejonowych, co jest jednak niemozliwe w warunkach suszenia rozpylowego. Produktu takiego nie da sie wysuszyc w wiekszych ilosciach w wiezy rozpylowej.So far, various low-foaming washing agents are known and used, the composition of which includes: surfactants in the amount of 8-15% by weight, complexing compounds in the amount of 30-45% by weight, builders in an amount of 30-60% by weight and other ingredients. These agents as depressants foams contain silicones, high-molecular fatty acids or non-ionic surface compounds open. Their disadvantage is that they insufficiently reduce the foaming properties of what is high importance when washing in automatic washing machines. A product with sufficiently low foam can be obtained by introducing larger amounts of the above-mentioned ingredients, e.g. over 6% of non-ionic detergents, which is however not possible under spray drying conditions. Such a product cannot be dried in larger ones quantities in the spray tower.
Srodek wedlug wynalazku nie posiada wyzej wymienionych cech ujemnych.The agent according to the invention does not have the above-mentioned disadvantages.
Stwierdzono, ze wprowadzenie do receptury srodka pioracego zawierajacego substancje powierzchnio¬ wo-czynne takie jak: alkiloarylosulfoniany, oksyetylenowane alkohole tluszczowe, blokowe kopolimery tlenku etylenu i propylenu, zwiazki kompleksujace czyli trójpolifosforan sodu, wypelniacze aktywne takie jak szklo wodne, siarczan sodu, karboksymetyloceluloze, oraz srodki zapachowe 0,5—1,5% syntetycznego wosku parafinowego w stopniu zadawalajacym obniza piane otrzymana przy uzyciu srodka pioracego, nie powodujac trudnosci przy wysuszeniu masy proszkowej w wiezy rozpylowej.It has been found that the incorporation of a detergent containing surface substances into a recipe active substances such as: alkylarylsulfonates, fatty alcohol ethoxylates, block oxide copolymers ethylene and propylene, complexing compounds, i.e. sodium tripolyphosphate, active fillers such as glass aqueous, sodium sulfate, carboxymethyl cellulose, and fragrances 0.5-1.5% synthetic wax of paraffin wax satisfactorily reduces the foam obtained with the use of a washing agent, without causing difficulties in drying the powder mass in the spray tower.
Znane jest z literatury i opisów patentowych zastosowanie wosku naturalnego pszczelnego i mikrokrysta¬ licznego jako srodka zbijajacego piane w procesie rafinacji ropy naftowej. Natomiast stosowanie substancji antypieniacych w srodkach detergentowych ma na celu obnizenie pienienia jako naturalnej cechy srodka powierzchniowo-czynnego przy zachowaniu jego wlasciwosci pioracych.It is known from literature and patents to use natural beeswax and microcrystalline numerous as a defoamer in the refining of crude oil. By contrast, the use of substances antifoam in detergents is intended to reduce foaming as a natural feature of the detergent surfactant while maintaining its washing properties.
Wosk mikrokrystaliczny, wymieniony wyzej, stanowi mieszanine weglowodorów n-i izoparaf inowych oraz naftenowych. Wosk ten otrzymywany jest z pozostalosci destylacyjnych wysoko wrzacych frakcji parafinowych rop naftowych. Cecha charakterystyczna tego wosku jest wysoka temperatura topnienia.Microcrystalline wax, mentioned above, is a mixture of n- and isoparaffin hydrocarbons and naphthenics. This wax is obtained from the distillation residues of high-boiling paraffinic fractions crude oil. The characteristic feature of this wax is its high melting point.
JV2 101 677 Natomiast wosk zastosowany w srodku wedlug wynalazku jest woskiem syntetycznym stanowiacym mieszanine weglowodorów i polietylenu. Wosk ten otrzymywany jest przez utlenianie powietrzem parafiny i polietylenu. Jego cecha charakterystyczna jest niska temperatura topnienia wynoszaca 60°C, która jest nieco nizsza od temperatury przygotowywanej masy proszkowej co pozwala na latwe wprowadzenie wymienionego wosku do masy proszkowej.JV2 101 677 In contrast, the wax used in the composition according to the invention is a synthetic wax mixture of hydrocarbons and polyethylene. This wax is obtained by oxidizing paraffin with air and polyethylene. Its characteristic feature is a low melting point of 60 ° C, which is slightly lower than the temperature of the prepared powder mass, which allows for easy introduction of the mentioned wax to the powder mass.
Obnizenie piany zwiazków powierzchniowo-czynnych nastepuje niezaleznie od ich budowy i twardosci wody, oraz niezaleznie od stopnia zabrudzenia bielizny, nawet przy calkowicie czystej bieliznie. Dodany wosk nie powoduje obnizenia zdolnosci pioracej i nie przyczynia sie do uszkodzenia tkaniny w procesie prania. Niska piana ulatwia proces prania w pralkach automatycznych, nie wydobywajac sie na zewnatrz.The reduction of the foam of surfactants is independent of their structure and hardness water, and regardless of the degree of soiling of the linen, even with completely clean linen. Wax added no causes a reduction in washing performance and does not damage the fabric during the washing process. Low foam Facilitates the washing process in automatic washing machines, without leaking out.
Wedlug wynalazku slabo pieniacy srodek do prania zawiera: % wagowy zwiazki powierzchniowo-czynne 8—15 zwiazki kompleksujace 30 -45 wypelniaczeaktywne 30 -60 syntetyczny wosk parafinowy 0,5— 1,5 Reszte do 100% stanowia rozjasniacze optyczne, srodki zapachowe i woda.According to the invention, a low-foaming detergent contains: % by weight surfactants 8-15 complexing compounds 30-45 fillers active 30 -60 synthetic paraffin wax 0.5-1.5 The rest up to 100% are optical brighteners, fragrances and water.
Przyklad. Receptura slabo pieniacego srodka do prania: % wagowy Dodecylobenzenosulfoniansodu 8,0 Mydlosodowe 3,0 Oksyetylowane alkoholetluszczowe 2,0 Blokowe kopolimery tlenku etylenu i propylenu 1,0 Syntetyczny woskparafinowy 1,0 Trójpolifosforansodu 45,0 Szklowodne 10,0 Karboksymetyloceluloza 1,5 Siarczansodu 18,0 Siarczanmagnezu 1,0 Reszte do 100% stanowia rozjasniacze optyczne, srodki zapachowe i woda.Example. Recipe for a low-foaming detergent: % by weight Dodecylobenzenesulfoniansodu 8.0 Sodium soap 3.0 Ethylated fatty alcohol 2.0 Block copolymers of ethylene oxide and propylene 1.0 Synthetic wax paraffin 1.0 Tripolyphosphate 45.0 Glass water 10.0 Carboxymethylcellulose 1.5 Sulfate sodium 18.0 Magnesium sulfate 1.0 The rest up to 100% are optical brighteners, fragrances and water.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL19180276A PL101677B1 (en) | 1976-08-12 | 1976-08-12 | A DETERGENT |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL19180276A PL101677B1 (en) | 1976-08-12 | 1976-08-12 | A DETERGENT |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL101677B1 true PL101677B1 (en) | 1979-01-31 |
Family
ID=19978189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL19180276A PL101677B1 (en) | 1976-08-12 | 1976-08-12 | A DETERGENT |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL101677B1 (en) |
-
1976
- 1976-08-12 PL PL19180276A patent/PL101677B1/en unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1274145A (en) | Detergent foam control agents | |
| US5238596A (en) | Detergent foam control agents | |
| US4556509A (en) | Light duty detergents containing an organic diamine diacid salt | |
| EP0210721B1 (en) | Detergent foam control agents | |
| US4576738A (en) | Hard surface cleaning compositions containing pianane | |
| US4599189A (en) | Paraffin-containing defoaming compositions and detergent compositions containing same | |
| KR910004608B1 (en) | Antifoam | |
| US4056481A (en) | Detergent composition | |
| JP2999262B2 (en) | Liquid detergent | |
| CA1071055A (en) | Liquid detergent compositions | |
| US5441662A (en) | Liquid detergent | |
| CN104818156A (en) | Tableware soaking powder composition for improving low-temperature greasy dirt cleaning effect | |
| JPS6369893A (en) | Novel surfactant mixture and its use | |
| US2875153A (en) | Detergent compositions | |
| US2483135A (en) | Impregnating agent- for metal | |
| JP3841431B2 (en) | Spray-dried detergent or its components | |
| JPS6215298A (en) | Carrier for liquid component and defoaming agent and detergent composition containing the same | |
| JP2547444B2 (en) | Concentrated high-density clothes powder detergent | |
| CN119256071A (en) | Diluted and thickened surfactant concentrates | |
| US3242091A (en) | Spray dried detergent concentrate | |
| JPH01182400A (en) | Liquid detergent composition | |
| EA036576B1 (en) | Aqueous hard surface cleaning composition | |
| RU2088646C1 (en) | Detergent for laundry | |
| JPH0229120B2 (en) | KONASETSUKENSOSEIBUTSU | |
| CN110199012B (en) | Aqueous hard surface cleaning compositions |