PL1220B1 - The method of obtaining products soluble in water or producing colloidal solutions from petroleum and mineral oils, paraffins, waxes, fats and tar. - Google Patents
The method of obtaining products soluble in water or producing colloidal solutions from petroleum and mineral oils, paraffins, waxes, fats and tar. Download PDFInfo
- Publication number
- PL1220B1 PL1220B1 PL1220A PL122021A PL1220B1 PL 1220 B1 PL1220 B1 PL 1220B1 PL 1220 A PL1220 A PL 1220A PL 122021 A PL122021 A PL 122021A PL 1220 B1 PL1220 B1 PL 1220B1
- Authority
- PL
- Poland
- Prior art keywords
- water
- tar
- fats
- petroleum
- waxes
- Prior art date
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 13
- 239000002480 mineral oil Substances 0.000 title claims description 9
- 239000003208 petroleum Substances 0.000 title claims description 7
- 239000003925 fat Substances 0.000 title claims description 5
- 239000011269 tar Substances 0.000 title claims description 5
- 239000001993 wax Substances 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 3
- -1 paraffins Substances 0.000 title claims description 3
- 239000003921 oil Substances 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 3
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 3
- 239000003502 gasoline Substances 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 235000019198 oils Nutrition 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002641 tar oil Substances 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003460 sulfonic acids Chemical class 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Description
Dla otrzymania olei mineralnych roz¬ puszczalnych w wodzie lub tez tworzacych z woda roztwory koloidalne oleje mineral¬ ne miesza sie, jak wiadomo, z kwasami tluszczowemi, olejami smolnemi, kalafo- nja, zmydla sie silnemi roztworami sody zracej lub amonjakiem, a dla nadania im jednostajnej przezroczystosci dodaje sie alkoholu etylowego lub tez sulfonowane¬ go oleju rycynowego.Przyklad 1. 20 kg jasnego oleju smolnego, 20 kg oleiny, 100 kg oleju mineralnego o ciezarze gatunkowym 0,900 miesza sie przy umiar- kowanem podgrzewaniu i dolewa sie do nich naprzemian 20 kg spirytusu i 5 1 roz¬ tworu 33$ sody zracej dopóty, az otrzy¬ mamy olej, tworzacy z woda trwala emulsje.Przyklad 2.Do 10 kg topionej kalafonji, dodaje sie po ochlodzeniu 30 kg sulfonowanego oleju rycynowego, oleju smolowego i 30 kg oleiny. Mieszajac powoli lecz ciagle, dodaje sie roztwór 30°Be sody zracej, az olej sta¬ nie sie zupelnie przezroczystym i zacznie z woda dawac emulsje.Wynalazca wykazal, ze dla otrzymania t. zw. olejów mineralnych rozpuszczal¬ nych w wodzie, jak równiez i parafiny, tluszczów, wosków i smól w charakterze substancji sprzyjajacej powstawaniu sta¬ nu koloidalnego olejów oraz innych po- mienionych wyzej produktów z woda,najlepiej sie nadaja kwasy sulfonowe ole¬ jów naftowych i mineralnych, otrzymy¬ wane metoda Petroff a, stanowiaca przed¬ miot patentu niemieckiego Ws 264785, lub tez sole alkaliczne lub amoniakalne tych¬ ze otrzymane z nich lub z destylatów sul¬ fonowanych olejów naftowych i mineral¬ nych. Do otrzymania wskazanych powy¬ zej produktów wzmiankowane kwasy sul¬ fonowane lub tez sole ich alkaliczne i amo¬ niakowe w stanie bezwodnym rozpuszczo¬ ne w benzolu, benzynie, acetonie, eterze lub tez wprost nierozpuszczalne, wprowadzaja sie do olejów, tluszczów, smól i t. p. mate- rjalów. Jesli byly wprowadzone w to po¬ laczenie roztwory tych soli, to odpowie¬ dnie rozpuszczalniki mozna usunac przez nagrzewanie lub przedmuchiwanie po¬ wietrzem.Przyklad 1. 90 czesci oleju wazelinowego (oczy¬ szczany solarowy) o c. wl. 0,865 miesza sie z 20 czesciami roztworu benzolowego za¬ wierajacego 50^ kwasów sulfonowych i benzol odpedza sie w aparacie próznio¬ wym.Przyklad 2. 50 czesci parafiny, 20 czesci terpentyny i 30 czesci sulfokwasów amonjakalnycii bezwodnych topi sie przez lekkie podgrze¬ wanie.Przyklad 3. 60 czesci oleju maszynowego o c. wl. 0,906, 20 czesci nafty i 20 czesci bezwod¬ nych soli potasowych sulfokwasów topi sie przez lekkie podgrzewanie.Przyklad 4. 95 czesci oleju antracenowego, otrzyma¬ nego z wegla kamiennego, 5 czesci bez¬ wodnych soli sodowych mydel sulfokwa¬ sów, 10 czesci wody roztapia sie umiar- kowanem nagrzewaniem.Otrzymane tym sposobem mieszaniny tluszczów, wosków, smól i olejów, sto¬ sownie do ilosci dodanych do nich sulfo¬ kwasów lub ich soli, daja z woda roz¬ twory zupelnie przezroczyste, albo tez bardzo trwale emulsje. Zwiazki te swoje- mi wlasnosciami tak chemicznemi, jak i fizycznemi róznia sie od wszystkich po¬ dobnych im a znanych juz preparatów.Tak np., dzieki obecnosci kwasów siarko- wo-naftowych, olejów naftowych i mine\ ralnych, odznaczajacych sie wieksza zdolnoscia emulgowania i zwilzania, ani¬ zeli mydla tluste i sulfonowane oleje ro¬ slinne, staja sie one odporniejsze na pod¬ grzewanie i trwalsze przy stosowaniu ich do obrabiania tkanin i latwiej przenikaja w pory materjalów. Oprócz tego kwasne te emulsje wskutek dowiedzionej trudno- - sci, z jaka sulfogrupy odczepiaja sie od kwasów sulfonaftowych przy zwyczaj- nem gotowaniu, w roztworach wodnych nie wytwarzaja kwasu siarczanego a o- bojetne rozcienczone woda nie dysocjuja, wydzielajac niezwiazane alkalja. Na tej zasadzie produkty te moga znalezc sze¬ rokie zastosowanie w przemysle meta¬ lurgicznym, garbarskim, wlókienniczym oraz przy konserwacji podkladów kolejo¬ wych. PLIn order to obtain mineral oils which are soluble in water or form colloidal solutions with water, mineral oils are, as is known, mixed with fatty acids, tar oils, rosin, saponified with strong solutions of caustic soda or ammonia, and to give them of uniform transparency, add ethyl alcohol or sulphonated castor oil. Example 1. 20 kg of light tar oil, 20 kg of olein, 100 kg of mineral oil with a specific weight of 0.900 are mixed with moderate heating and 20 kg are added alternately. of spirit and 5 liters of a 33% solution of baking soda until an oil is obtained, forming a stable emulsion with the water. Example 2 To 10 kg of molten rosin, add after cooling 30 kg of sulphonated castor oil, tar oil and 30 kg of olein . While stirring slowly but steadily, a 30 ° solution of baking soda is added until the oil becomes completely transparent and starts to form an emulsion with the water. The inventor has shown that to obtain the so-called mineral oils soluble in water, as well as paraffins, fats, waxes and tar as substances promoting the formation of the colloidal state of oils and other products mentioned above with water, sulfonic acids of petroleum and mineral oils are best suited, obtained by the Petroff method, which is the subject of the German patent Ws 264785, or also alkaline or ammoniacal salts obtained therefrom or from distillates of sulfonated petroleum and mineral oils. In order to obtain the above-mentioned products, the abovementioned sulfonated acids or their anhydrous alkali and ammonia salts dissolved in benzol, gasoline, acetone, ether or otherwise directly insoluble are incorporated into oils, fats, tar, etc. materials. If solutions of these salts have been included in this combination, the respective solvents can be removed by heating or blowing with air. Example 1.90 parts of vaseline oil (solar treated) approx. 0.865 is mixed with 20 parts of a benzol solution containing 50% sulfonic acids and the benzol is stripped off in a vacuum apparatus. Example 2. 50 parts of paraffin, 20 parts of turpentine and 30 parts of ammonium sulphacids and anhydrous are melted by light heating. 3.60 parts of machine oil with total volume 0.906, 20 parts of kerosene and 20 parts of anhydrous potassium sulfo acid salts are melted by gentle heating. Example 4. 95 parts of anthracene oil, obtained from coal, 5 parts of anhydrous sodium salts, sulfo acid soap, 10 parts of water is melted with moderate heating. The mixtures obtained in this way of fats, waxes, tar and oils, according to the amount of sulfa acids or their salts added thereto, give with water completely transparent solutions or very stable emulsions. These compounds, with their chemical and physical properties, differ from all similar and known preparations, such as, for example, due to the presence of sulfur-petroleum acids, petroleum and mineral oils, characterized by a greater emulsifying capacity and wetting, rather than greasy soaps and sulfonated vegetable oils, they become more resistant to heat and more durable when used in fabric treatment and penetrate the pores of materials more easily. Moreover, these acidic emulsions, due to the proven difficulty with which sulfogroups detach from sulfonaphtic acids in ordinary boiling, do not produce sulfuric acid in aqueous solutions and reactive diluted water does not dissociate, giving off free alkali. On this basis, these products can be widely used in the metallurgical, tanning, and textile industries and in the maintenance of railway sleepers. PL
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| Publication Number | Publication Date |
|---|---|
| PL1220B1 true PL1220B1 (en) | 1925-01-31 |
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