PL123851B1 - Stabilizer for suspension polymerization of monomers - Google Patents

Stabilizer for suspension polymerization of monomers Download PDF

Info

Publication number: PL123851B1
Authority: PL; Poland
Prior art keywords: stabilizer; calcium; monomers; weight; calcium phosphate
Prior art date: 1980-05-15

Application number

PL22429280A

Other languages

English (en)

Polish (pl)

Other versions

PL224292A1 (fr

Inventor

Benedykt Kubica

Jerzy Wojcik

I Roman Jurczak

Maksymilian Durak

Ii Roman Jurczak

Jozef Grzeslo

Jerzy Muranski

Original Assignee

Osrodek Badawczo

Rozwojowy Kauczukow I Tworzyw Winylowych

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-05-15

Filing date

1980-05-15

Publication date

1982-12-31

1980-05-15 Application filed by Osrodek Badawczo, Rozwojowy Kauczukow I Tworzyw Winylowych filed Critical Osrodek Badawczo

1980-05-15 Priority to PL22429280A priority Critical patent/PL123851B1/pl

1981-05-13 Priority to GB8114595A priority patent/GB2075994B/en

1981-05-14 Priority to RO81104297A priority patent/RO82554A/fr

1981-05-15 Priority to DE19813119486 priority patent/DE3119486A1/de

1981-05-15 Priority to DD23000281A priority patent/DD158909A5/de

1981-11-27 Publication of PL224292A1 publication Critical patent/PL224292A1/xx

1982-12-31 Publication of PL123851B1 publication Critical patent/PL123851B1/pl

Links

239000003381 stabilizer Substances 0.000 title claims description 23
238000010557 suspension polymerization reaction Methods 0.000 title claims description 7
239000000178 monomer Substances 0.000 title claims description 5
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
239000001506 calcium phosphate Substances 0.000 claims description 14
229910000389 calcium phosphate Inorganic materials 0.000 claims description 14
235000011010 calcium phosphates Nutrition 0.000 claims description 14
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 14
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 8
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 8
159000000007 calcium salts Chemical class 0.000 claims description 7
235000019260 propionic acid Nutrition 0.000 claims description 4
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 4
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 3
150000002148 esters Chemical class 0.000 claims description 3
229910052588 hydroxylapatite Inorganic materials 0.000 claims description 3
XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
238000000034 method Methods 0.000 description 10
239000000725 suspension Substances 0.000 description 9
238000006116 polymerization reaction Methods 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 5
VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 5
239000001639 calcium acetate Substances 0.000 description 5
235000011092 calcium acetate Nutrition 0.000 description 5
229960005147 calcium acetate Drugs 0.000 description 5
239000012071 phase Substances 0.000 description 5
239000011324 bead Substances 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
230000008569 process Effects 0.000 description 4
230000000694 effects Effects 0.000 description 3
230000000379 polymerizing effect Effects 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000002245 particle Substances 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
239000000843 powder Substances 0.000 description 2
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
239000004132 Calcium polyphosphate Substances 0.000 description 1
BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propionate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
150000003868 ammonium compounds Chemical class 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
230000000903 blocking effect Effects 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
235000019827 calcium polyphosphate Nutrition 0.000 description 1
239000004330 calcium propionate Substances 0.000 description 1
235000010331 calcium propionate Nutrition 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
238000010494 dissociation reaction Methods 0.000 description 1
230000005593 dissociations Effects 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
238000000227 grinding Methods 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000010842 industrial wastewater Substances 0.000 description 1
239000006194 liquid suspension Substances 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
150000002735 metacrylic acids Chemical class 0.000 description 1
125000005397 methacrylic acid ester group Chemical group 0.000 description 1
239000000203 mixture Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000001473 noxious effect Effects 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000013049 sediment Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
229910000162 sodium phosphate Inorganic materials 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

PL22429280A 1980-05-15 1980-05-15 Stabilizer for suspension polymerization of monomers PL123851B1 (en)

Priority Applications (5)

Application Number	Priority Date	Filing Date	Title
PL22429280A PL123851B1 (en)	1980-05-15	1980-05-15	Stabilizer for suspension polymerization of monomers
GB8114595A GB2075994B (en)	1980-05-15	1981-05-13	Stabilizer for suspension polymerization of monomers
RO81104297A RO82554A (fr)	1980-05-15	1981-05-14	Stabilisateur pour la polymerisation en suspension des monomeres styreniques
DE19813119486 DE3119486A1 (de)	1980-05-15	1981-05-15	Stabilisator fuer die suspensionspolymerisation von monomeren
DD23000281A DD158909A5 (de)	1980-05-15	1981-05-15	Stabilisator zur suspensionspolymerisation von monomeren

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
PL22429280A PL123851B1 (en)	1980-05-15	1980-05-15	Stabilizer for suspension polymerization of monomers

Publications (2)

Publication Number	Publication Date
PL224292A1 PL224292A1 (fr)	1981-11-27
PL123851B1 true PL123851B1 (en)	1982-12-31

Family

ID=20003113

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
PL22429280A PL123851B1 (en)	1980-05-15	1980-05-15	Stabilizer for suspension polymerization of monomers

Country Status (5)

Country	Link
DD (1)	DD158909A5 (fr)
DE (1)	DE3119486A1 (fr)
GB (1)	GB2075994B (fr)
PL (1)	PL123851B1 (fr)
RO (1)	RO82554A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB9721603D0 (en)	1997-10-10	1997-12-10	Dyno Ind Asa	Method

1980
- 1980-05-15 PL PL22429280A patent/PL123851B1/pl unknown
1981
- 1981-05-13 GB GB8114595A patent/GB2075994B/en not_active Expired
- 1981-05-14 RO RO81104297A patent/RO82554A/fr unknown
- 1981-05-15 DE DE19813119486 patent/DE3119486A1/de not_active Withdrawn
- 1981-05-15 DD DD23000281A patent/DD158909A5/de unknown

Also Published As

Publication number	Publication date
DE3119486A1 (de)	1982-03-18
RO82554A (fr)	1983-10-15
GB2075994B (en)	1983-09-28
GB2075994A (en)	1981-11-25
DD158909A5 (de)	1983-02-09
PL224292A1 (fr)	1981-11-27
RO82554B (ro)	1983-09-30

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