PL14059B1 - Wetting, cleansing, disintegrating agents and the like for the textile industry. - Google Patents
Wetting, cleansing, disintegrating agents and the like for the textile industry. Download PDFInfo
- Publication number
- PL14059B1 PL14059B1 PL14059A PL1405929A PL14059B1 PL 14059 B1 PL14059 B1 PL 14059B1 PL 14059 A PL14059 A PL 14059A PL 1405929 A PL1405929 A PL 1405929A PL 14059 B1 PL14059 B1 PL 14059B1
- Authority
- PL
- Poland
- Prior art keywords
- wetting
- acids
- acid
- cleansing
- salts
- Prior art date
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- 238000009736 wetting Methods 0.000 title claims description 6
- 239000004753 textile Substances 0.000 title claims description 5
- 150000003460 sulfonic acids Chemical class 0.000 claims description 12
- 239000007859 condensation product Substances 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 8
- 239000000344 soap Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- -1 heterocyclic amines Chemical class 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 239000000047 product Substances 0.000 claims description 4
- NRFFMWTVYMKWPU-UHFFFAOYSA-N 2-sulfonaphthalene-1-carboxylic acid Chemical class C1=CC=C2C(C(=O)O)=C(S(O)(=O)=O)C=CC2=C1 NRFFMWTVYMKWPU-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- CJAJEZSCULAKCB-UHFFFAOYSA-N 2-sulfohexadecanoic acid Chemical compound CCCCCCCCCCCCCCC(C(O)=O)S(O)(=O)=O CJAJEZSCULAKCB-UHFFFAOYSA-N 0.000 claims description 2
- XQITUXIEASXIMZ-UHFFFAOYSA-N 2-sulfooctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(C(O)=O)S(O)(=O)=O XQITUXIEASXIMZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- CJKRXEBLWJVYJD-UHFFFAOYSA-N N,N'-diethylethylenediamine Chemical compound CCNCCNCC CJKRXEBLWJVYJD-UHFFFAOYSA-N 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003931 anilides Chemical class 0.000 description 1
- 150000001454 anthracenes Chemical class 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000009950 felting Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- ZOLJFBQEKSZVCB-UHFFFAOYSA-N n-phenyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NC1=CC=CC=C1 ZOLJFBQEKSZVCB-UHFFFAOYSA-N 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Description
Wiadomo, ze produkty kondensacji wysokocza$teczkowych kwasów tluszczo¬ wych i alifatycznych, aromatycznych, hy- droaromatycznych lub heterocyklicznych a- min lub ich pochodnych, albo produktów podstawiania, lub ich soli posiadaja wla¬ snosci mydla. Wymienione srodki maja jednak w wiekszej czesci te wade, ze sa albo nierozpuszczalne albo tez w alkalicz^ nie reagujacych cieczach nietrwale, tak ze nie moga byc czesto zastosowane w prze* mysle wlókienniczym, Stwierdzono, ze wymienione produkty kondensacji staja sie w znacznie wiekszym zakresie uzyteczne, gdy stosuje sie je w mieszaninie z mydlami lub srodkami w ro¬ dzaju mydel, jak olej turecki lub kwasy sulfonowe lub tez sole kwasów sulfono¬ wych. Zwlaszcza nadaja sie takie kwasy sulfonowe, które posiadaja wielka zdolnosc rozszczepiania i zwilzania. Tak np. nadaja sie kwasy sulfonowe cial alifatycznych, a- romatycznych, hydroaromatycznych lub he¬ terocyklicznych, jak kwasy sulfonowe wyz-szych kwasów tluszczowych wzglednie ich pochodnych, .kwasy ^sulfo - naftalenowe, kwas^^llonb^^yejóW ze smoly wegla, brunatnego lub weglowodorów naftowych, kwasy sulfonowe szeregu benzolowego, naftalenowego i antracenowego, zwlaszcza takie, które posiadaja jeden lub wiecej lan¬ cuchów bocznych tego samego lub róznego rodzaju, Mb w których kilka czasteczek mo¬ ze byc polaczonych mostkiem, wreszcie kwasy sulfonowe czterohydronaftalenu i t. d., oraz sole tych kwasów sulfonowych.Wymienione produkty kondensacji mo¬ ga byc badz dodawane oddzielnie do kapie¬ li roboczej, badz tez uzyte w postaci goto¬ wych mieszanin z mydlami lub ze srodka¬ mi w rodzaju mydel, jak oleje czerwieni tureckiej lub kwasy sulfonowe, wzgL sole kwasów sulfonowych, zwlaszcza takich, które posiadaja duza zdolnosc zwilzania i rozszczepiania, jak np, alkylowane kwasy sulfonaftalenowe, kwas sulfostearynowy, kwas sulfopalmitynowy. W niektórycfi przy¬ padkach, np. przy anilidzie kwasu steary¬ nowego, okazalo sie celowem uprzednie roz¬ puszczanie anilidu w rozpuszczalniku orga¬ nicznym,1 a nastepnie dodawanie roztworu tego do kwasu sulfonowego.Wytworzone wedlug wynalazku miesza¬ niny produktów kondensacji nadaja sie do róznych celów, przedewszystkiem do ob¬ róbki materjalów, zwlaszcza wlókienni¬ czych, np. do emulgowania, prania, spilsnia- nia, bielenia, barwienia, merceryzowania i wykonczania; umozliwiaja one otrzymywa¬ nie nowych efektów, a czesto mniej ko¬ sztowne przeprowadzenie procesu w sto¬ sunku do dotychczas znanych sposobów pracy.Do opisanych mieszanin mozna doda¬ wac organiczne srodki rozpuszczajace, wzglednie mieszaniny tychze; powoduja one czesto zmiane, wzglednie zwiekszenie efektu.Podczas gdy mieszaniny wymienionych produktów kondensacji i mydel lub olejów tureckich moga byc glównie uzyte w obo¬ jetnych lub alkalicznych srodkach, miesza¬ niny produktów 'kondensacji z wyzej wy- mienionemi kwasami sulfonowemi lub ich solami uzywac mozna zarówno w obojet¬ nych lub alkalicznych, jak i kwasnych sro¬ dowiskach.Sposób wedlug niniejszego wynalazku nie obejmuje stosowania produktów kon¬ densacji amin, zawierajacych oksygrupy, i kwasów tluszczowych o wysokim ciezarze czasteczkowym.Przyklad I. 1 czesc amidu kwasu stea¬ rynowego rozpuszcza sie przy ogrzaniu z 5 czesciami 50% roztworu produktu sulfono¬ wania, otrzymanego z kwasu olejowego przez traktowanie kwasem siarkowym, S0Ó, kwasem chlorosulfonowym, ewentualnie w obecnosci organiczinych rozpuszczalników.Mieszanina rozpuszcza sie w alkalicznych, obojetnych lub kwasnych kapielach farbier- skich.Przyklad II. 1 czesc dwuetyloetyleno- dwuaminy kwasu oleinowego (produkt kon¬ densacji kwasu oleinowego i dwuetyloetyle- nodwuaminy) miesza sie intensywnie z 5 czesciami soli Sodowej propylowanego kwasu naftaleno-sulfonowego przy ogrza¬ niu, z malym dodatkiem wody. Powstajaca przy tern mieszanina uzyteczna jest w przemysle wlókienniczym jako srodek zwilzajacy, emulgujacy lub czyszczacy do pracy w alkalicznych, jak równiez obojet¬ nych lub kwasnych srodowiskach. Zamiast wymienlionej dwuetyloetylenodwuaminy kwasu oleinowego mozna stosowac równiez jej sole. PLIt is known that the condensation products of high molecular weight fatty acids and aliphatic, aromatic, hydroaromatic or heterocyclic amines or their derivatives or substitution products or their salts have soap properties. However, the above-mentioned agents have, to a greater extent, the disadvantages that they are either insoluble or unstable in alkaline reacting liquids, so that they cannot often be used in the textile industry. It has been found that the condensation products mentioned become useful to a much greater extent when used in admixture with soaps or soap-type agents such as Turkish oil or sulfonic acids or also salts of sulfonic acids. Especially suitable are those sulfonic acids which have a great splitting and wetting ability. For example, the sulfonic acids of aliphatic, aromatic, hydroaromatic or heterocyclic bodies are suitable, such as the sulfonic acids of higher fatty acids or their derivatives, sulfo-naphthalenic acids, llonal acid, coal tar, etc. lignite or petroleum hydrocarbons, sulfonic acids of the benzol, naphthalene and anthracene series, especially those having one or more side chains of the same or a different type, Mb in which several molecules may be bridged, finally sulfonic acids of tetrahydronaphthalene, etc. and the salts of these sulfonic acids. The condensation products mentioned can be added separately to the working bath, or used in the form of ready-mixed mixtures with soaps or with soap-like agents, such as Turkish red oils or sulfonic acids. , or salts of sulfonic acids, especially those that have a high wetting and splitting ability, such as, for example, alkylated sulfonaphthalenic acids, sulfostearic acid, sulfopalmitic acid. In some cases, for example in the case of stearic acid anilide, it has proved expedient to first dissolve the anilide in an organic solvent and then add this solution to the sulphonic acid. The condensation product mixtures prepared according to the invention are suitable for use in for various purposes, in particular for the treatment of materials, in particular of textiles, for example for emulsifying, washing, felting, bleaching, dyeing, mercerizing and finishing; They make it possible to obtain new effects, and often less necessary to carry out the process in relation to the previously known methods of work. To the described mixtures, it is possible to add organic dissolving agents, or mixtures of these; they often change or increase the effect. While mixtures of the above-mentioned condensation products and Turkish soaps or oils can mainly be used in neutral or alkaline means, mixtures of condensation products with the above-mentioned sulfonic acids or their salts can be used in neutral or alkaline as well as acidic rinses. The method of the present invention does not involve the use of amine condensation products containing oxygroups and fatty acids with a high molecular weight. Example 1 1 part of the amide of the steatoric acid dissolves is heated with 5 parts of a 50% solution of the sulfonation product, obtained from oleic acid by treatment with sulfuric acid, SOO, chlorosulfonic acid, possibly in the presence of organic solvents. The mixture is dissolved in alkaline, inert or acid dye baths. Example II . 1 part of oleic acid diethylethylene diamine (a condensation product of oleic acid and diethylethylenediamine) is mixed intensively with 5 parts of propylated naphthalene sulphonic acid sodium salt with heating, with a little addition of water. The resulting mixture is useful in the textile industry as a wetting, emulsifying or cleaning agent for use in alkaline as well as neutral or acidic environments. The salts thereof may also be used in place of the aforementioned diethyl ethylenediamine oleic acid. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL14059B1 true PL14059B1 (en) | 1931-08-31 |
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