PL15110B1 - A method of obtaining liquid agents with strong wetting and penetrating properties. - Google Patents
A method of obtaining liquid agents with strong wetting and penetrating properties. Download PDFInfo
- Publication number
- PL15110B1 PL15110B1 PL15110A PL1511029A PL15110B1 PL 15110 B1 PL15110 B1 PL 15110B1 PL 15110 A PL15110 A PL 15110A PL 1511029 A PL1511029 A PL 1511029A PL 15110 B1 PL15110 B1 PL 15110B1
- Authority
- PL
- Poland
- Prior art keywords
- liquid agents
- obtaining liquid
- penetrating properties
- strong wetting
- wetting
- Prior art date
Links
- 238000009736 wetting Methods 0.000 title claims description 7
- 239000007788 liquid Substances 0.000 title claims description 4
- 230000000149 penetrating effect Effects 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000006277 sulfonation reaction Methods 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- -1 lauric Chemical class 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000000835 fiber Substances 0.000 description 5
- 238000004043 dyeing Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000000976 ink Substances 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012047 saturated solution Substances 0.000 description 2
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000000984 vat dye Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010020112 Hirsutism Diseases 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- PYUYQYBDJFMFTH-WMMMYUQOSA-N naphthol red Chemical compound CCOC1=CC=CC=C1NC(=O)C(C1=O)=CC2=CC=CC=C2\C1=N\NC1=CC=C(C(N)=O)C=C1 PYUYQYBDJFMFTH-WMMMYUQOSA-N 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Description
Wiadomo, ze produkty sulfonowania sposób, np., barwienia nawskros gestych tluszczów i olejów oraz ich kwasów karbo- tkanin lub pilsni. nowych posiadaja wlasnosci emulgujace i Stwierdzono, ze mozna otrzymac pre- zwilzajace, dzieki czemu stosuje sie je pod paraty tego rodzaju, ale o znacznie lep- postacia olejów tureckich i innych pokrew- szych wlasnosciach, jezeli stosuje sie za- nych preparatów, jako srodki emulgujace, miast wyzszych kwasów tluszczowych i ole- zwilzajace i przenikajace w celu spotego- jowych odpowiadajace im alkohole, jak wania wloskowatosci i ulatwienia w ten np.Iaurynowy CHJCHJ10CHJDH oleinowy CHJCHJ7CH = CH. (CHJ7CH2OH cetylowy CH./CH2)l4CH2OH stearynowy CH/CHJx,CH2OH w postaci ich produktów sulfonowania. kolo 15°C 220 kg stezonego kwasu siarkowe- Przyklad I. 270 kilogramów alkoholu go. Produkt rozklada sie lodem i przemy- oleinowego sulfonuje sie w temperaturze o- wa nasyconym roztworem soli glaub«rskiejcelem usuniecia nadmiaru kwasu siarko- ^^ ~ - , Pfrzyktód *II. 270 kilogramów alkoholu stearynowego sulfonuje sie w temperaturze 50°G 115 kg kwasu chlorosiarkowego. Pro¬ dukt rozklada sie lodem i przemywa nasy¬ conym roztworem soli glauberskiej.Te produkty sulfonowania wykazuja prócz duzej trwalosci, polegajacej na bra¬ ku wolnych lub mogacych sie estryfikowac grup karboksylowych, duza zdolnosc zwil¬ zania, pienienia, emulgowania i oczyszcza¬ nia oraz wlasnosc nadawania wlóknom przemyslowym i pokrewnym materjalom miekkiego, gladkiego i nieklejacego sie chwytu. Z tego powodu nadaja sie one do rozmaitych celów w przemysle wlókienni¬ czym i skórzanym oraz w innych dziedzi¬ nach.Przy traktowaniu materjalów wlókien¬ niczych obojetnemi, kwasnemi lub alkalicz- nemi plynami produkty te wzmagaja dzia¬ lanie plynów stosowanych do obróbki przez znacznie zwiekszone wykorzystanie ich, podwyzszajac przenikanie i przeprowadza¬ jac tluszcze, zanieczyszczenia i podobne ciala w wodna zawiesine.Przy failbowaniu barwnikami kadziowe- mi dodatek tych produktów umozliwia ka¬ dziowanie w obecnosci malych ilosci wzglednie slabych zasad, co ma wielkie znaczenie przy farbowaniu wlókien zwie¬ rzecych barwnikami kadziowemi. Ta dro¬ ga mozna równiez wlókna zwierzece far¬ bowac czerwienia naftolowa. Uzycie do¬ datku opisanych powyzej materjalów u- latwia znacznie nawilzanie, np. sproszko¬ wanych barwników przy przeprowadzaniu ich do wodnego roztworu, przy otrzymywa¬ niu past i t. d. Wodne zawiesiny tych pro¬ duktów, same lub z innemi dodatkami, sta¬ nowia w przedzalnictwie cenny srodek zwilzajacy. Dodatek sulfonowanych alko¬ holi tluszczowych przyspiesza, wzmacnia i pojepsza dzialanie plynów, stosowanych do traktowania skór przy ich przeróbce i uszla¬ chetnianiu. Zwiazki te nadaja sie w wielu dziedzinach przemyslu do zwilzania, wy¬ twarzania zawiesin lub przenoszenia czyn¬ nych skladników, a wiec, np., przy wytwa¬ rzaniu i przeróbce papieru, przy otrzymy¬ waniu farb pigmentowych do farbowania futer. Powyzsze wlasnosci tych produktów pozwalaja storowac je w farmacji w posta¬ ci emulgatorów, jak równiez w technice farmaceutycznej w charakterze srodków do ochrony skóry oraz skladników masci, kremów, zamiast wazenoli i t. d. Znamien- nem jest, ze wlókna przemyslowe i inne ma- terjaly,traktowane temi srodkami, staja sie miekkie i gietkie i nie posiadaja kleistego chwytu, dzieki czemu nadaja sie do zmiek¬ czania takich wyrobów. Dzieki silnym wla¬ snosciom zwilzajacym i przenikajacym srodki te nadaja sie równiez jako srodki do zwalczania szkodników. Produkty te sa równiez cenne, jako dodatki do zapraw o- raz jako oleje do borowania w przemysle metalowym. Prócz tego dzialaja one w za¬ wiesinie jako koloidy ochronne, np. przy wy¬ robie atramentów i przy rozszczepianiu tlu¬ szczów, oraz ze wzgledu na ich zdolnosci przenikania daja sie zastosowac do mas ce¬ ramicznych, a dzieki zdolnosci zwilzania— do srodków wiazacych pyl. PLIt is known that sulfonation products process, for example, the dyeing of residual thick fats and oils and their carbonic or fiber acids. new have emulsifying properties and it has been found that pre-moisturizing agents can be obtained, so they can be used for this type of paraty, but with a much higher form of Turkish oils and other related properties, if the other preparations are used as emulsifying agents , instead of higher fatty acids and oily, they moisturize and penetrate to increase the intensity of the corresponding alcohols, such as hairiness and ease, such as lauric CHJCHJ10CHJDH oleic CHJCHJ7CH = CH. (CHJ7CH2OH cetyl CH./CH2)14CH2OH stearic CH / CHJx, CH2OH as their sulfonation products. around 15 ° C 220 kg of concentrated sulfuric acid- Example I. 270 kg of alcohol of it. The product is decomposed with ice and the wash is sulfonated at room temperature with a saturated solution of Glaub's salt to remove excess sulfuric acid. 270 kg of stearic alcohol is sulfated at 50 ° G with 115 kg of chlorosulfuric acid. The product is decomposed with ice and washed with a saturated solution of Glauber's salt. These sulfonation products, apart from a long stability, consisting in the absence of free or esterifiable carboxyl groups, high wetting, foaming, emulsifying and cleansing properties, and the property of giving industrial fibers and related materials a soft, smooth and non-sticky hand. For this reason, they are suitable for a variety of purposes in the textile and leather industries and in other fields. When treating textile materials with inert, acidic or alkaline fluids, these products enhance the effect of the treatment fluids by significantly increasing using them, increasing the penetration and transferring fats, impurities and similar bodies into an aqueous suspension. In the case of failing with vat dyes, the addition of these products enables the dyeing in the presence of small amounts of relatively weak bases, which is of great importance when dyeing animal fibers. vat dyes. This path can also be dyed by animal fibers with naphthol red. The use of the additive of the above-described materials greatly facilitates the wetting of, for example, powdered dyes when bringing them into an aqueous solution for the preparation of pastes, etc. Aqueous suspensions of these products, alone or with other additives, constitute a valuable wetting agent for the forestry. The addition of sulfonated fatty alcohols accelerates, strengthens and accelerates the action of the liquids used for the treatment of leather in its processing and refining. These compounds are suitable in many industries for the wetting, suspending or transfer of active ingredients, ie, for example in the manufacture and processing of paper, in the preparation of pigment inks for dyeing fur. The above properties of these products allow them to be folded in pharmacy in the form of emulsifiers, as well as in pharmaceutical technology as skin protection agents and ingredients of ointments, creams, instead of vashenols, etc. It is characteristic that industrial fibers and other materials, treated with these substances, they become soft and pliable and do not have a sticky hand, making them suitable for softening such products. Due to their strong wetting and penetrating properties, these agents are also suitable as pest control agents. These products are also valuable as additives to mortars and as drilling oils in the metal industry. In addition, they act in suspension as protective colloids, e.g. for the production of inks and for the splitting of fat, and because of their penetrating properties, they can be used with ceramics, and thanks to their wetting properties - for binding agents dust. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL15110B1 true PL15110B1 (en) | 1931-12-31 |
Family
ID=
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE694178C (en) | Process for the preparation of condensation products which are soluble or easily dispersible in water | |
| DE2432296A1 (en) | LIQUID ADJUSTMENTS OF FATTY ACID ALKANOLAMINE CONDENSATES | |
| PL15110B1 (en) | A method of obtaining liquid agents with strong wetting and penetrating properties. | |
| US1715410A (en) | Process of preparing fulling liquors and emulsions | |
| DE575831C (en) | Process for the production of cleaning, emulsifying and wetting agents | |
| DE747667C (en) | Process for the production of water-soluble, fat-free, high-molecular products | |
| DE670096C (en) | Process for the production of pellets from protein substances and / or protein breakdown products | |
| PL14058B1 (en) | A method of obtaining liquid agents used in the textile, leather, paper and fat industries. | |
| AT136197B (en) | Treatment baths for all kinds of materials. | |
| DE566453C (en) | Process for the production of wetting agents, detergents, dispersants, plasticizers and the like. like | |
| DE1033827B (en) | Detergent mixture | |
| DE539265C (en) | Process to increase the spinnability of wool | |
| DE670822C (en) | Process for the production of aqueous emulsions | |
| DE604255C (en) | Process for the production of capillary-active sulfonation products from uncleaved waxes | |
| DE702242C (en) | Dispersants | |
| DE896645C (en) | Process for the production of dispersants, wetting agents and cleaning agents | |
| DE968790C (en) | Detergents, wetting agents and dispersants | |
| DE662092C (en) | Treatment baths | |
| DE599933C (en) | Process for the preparation of high molecular weight sulfonic acids and their salts | |
| DE862393C (en) | Process for the processing of dilute aqueous solutions of protein degradation products | |
| AT151302B (en) | Process for the production of as wetting, cleaning, emulsifying, finishing u. Like. Medium suitable products. | |
| DE825258C (en) | Process for cleaning anion-active wetting agents | |
| DE744611C (en) | Soap substitutes | |
| DE572283C (en) | Wetting agents, cleaning agents, emulsifying agents and solvents like | |
| DE718071C (en) | Process for the production of capillary-active substances |