PL161782B2 - A polymere-mineral paint - Google Patents
A polymere-mineral paintInfo
- Publication number
- PL161782B2 PL161782B2 PL28356990A PL28356990A PL161782B2 PL 161782 B2 PL161782 B2 PL 161782B2 PL 28356990 A PL28356990 A PL 28356990A PL 28356990 A PL28356990 A PL 28356990A PL 161782 B2 PL161782 B2 PL 161782B2
- Authority
- PL
- Poland
- Prior art keywords
- amount
- weight
- weight percent
- calcium
- oleate
- Prior art date
Links
- 239000003973 paint Substances 0.000 title claims abstract description 22
- 229910052500 inorganic mineral Inorganic materials 0.000 title description 3
- 239000011707 mineral Substances 0.000 title description 3
- 239000004568 cement Substances 0.000 claims abstract description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920005551 calcium lignosulfonate Polymers 0.000 claims abstract description 7
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims abstract description 7
- ZCZLQYAECBEUBH-UHFFFAOYSA-L calcium;octadec-9-enoate Chemical compound [Ca+2].CCCCCCCCC=CCCCCCCCC([O-])=O.CCCCCCCCC=CCCCCCCCC([O-])=O ZCZLQYAECBEUBH-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000004202 carbamide Substances 0.000 claims abstract description 7
- 239000006185 dispersion Substances 0.000 claims abstract description 7
- 239000010440 gypsum Substances 0.000 claims abstract description 7
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 7
- 239000001023 inorganic pigment Substances 0.000 claims abstract description 7
- 229920000642 polymer Polymers 0.000 claims abstract description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 7
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 7
- 239000008119 colloidal silica Substances 0.000 claims abstract description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000005642 Oleic acid Substances 0.000 claims abstract description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011398 Portland cement Substances 0.000 claims abstract description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 5
- 235000010215 titanium dioxide Nutrition 0.000 claims abstract description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011787 zinc oxide Substances 0.000 claims abstract description 4
- 235000014692 zinc oxide Nutrition 0.000 claims abstract description 4
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 5
- 239000001110 calcium chloride Substances 0.000 claims description 5
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- MAQCMFOLVVSLLK-UHFFFAOYSA-N methyl 4-(bromomethyl)pyridine-2-carboxylate Chemical compound COC(=O)C1=CC(CBr)=CC=N1 MAQCMFOLVVSLLK-UHFFFAOYSA-N 0.000 claims description 5
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 4
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 3
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 3
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 abstract description 2
- UCUJUFDOQOJLBE-UHFFFAOYSA-N [Cl].[Ca] Chemical compound [Cl].[Ca] UCUJUFDOQOJLBE-UHFFFAOYSA-N 0.000 abstract 1
- 239000001164 aluminium sulphate Substances 0.000 abstract 1
- 235000011128 aluminium sulphate Nutrition 0.000 abstract 1
- IKCOOALACZVGLI-GNOQXXQHSA-K bis[[(z)-octadec-9-enoyl]oxy]alumanyl (z)-octadec-9-enoate Chemical compound [Al+3].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O IKCOOALACZVGLI-GNOQXXQHSA-K 0.000 abstract 1
- 235000013877 carbamide Nutrition 0.000 abstract 1
- 239000010499 rapseed oil Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 244000188595 Brassica sinapistrum Species 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004890 Hydrophobing Agent Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
Przedmiotem wynalazku jest farba mineralno-polimerowa o podwyższonych właściwościach technicznych przeznaczona głównie do malowania wyrobów budowlanych ceramicznych oraz wyrobów azbestowo-cementowych i ligno-cementowych.The subject of the invention is a mineral-polymer paint with improved technical properties, intended mainly for painting ceramic construction products as well as asbestos-cement and ligno-cement products.
Znana jest z opisu patentowego nr 117 209 farba cementowa składająca się z cementu, krzemionki syntetycznej, kurzu azbestowego, oksyetylowego alkoholu tłuszczowego oraz wody. Niedogodnością stosowanych dotychczas farb jest to, że hyrdrofobowość uzyskanych z nich powłok, tak cenna z punktu widzenia ich odporności na starzenie i działanie wód opadowych wpływa ujemnie na przyczepność tych powłok do wyrobów ceramicznych, płyt azbestowo-cementowych i ligno-cementowych. Powłoki te bowiem jako trudno zwilżalne przez wodę odznaczają się również niezadawalającą przyczepnością międzywarstwową, co poważnie utrudnia wykonanie tymi farbami dwu lub kilkuwarstwowych pokryć malarskich.It is known from the patent description No. 117 209 cement paint consisting of cement, synthetic silica, asbestos dust, fatty alcohol oxyethyl and water. The disadvantage of the paints used so far is that the hydrophobicity of the coatings obtained from them, so valuable in terms of their resistance to aging and rainwater, has a negative effect on the adhesion of these coatings to ceramic products, asbestos-cement and ligno-cement boards. These coatings, as they are difficult to wet by water, are also characterized by unsatisfactory interlayer adhesion, which makes it difficult to make two or several-layer paint coatings with these paints.
Nieoczekiwanie okazało się, że wprowadzenie nowych składników do farb cementowych umożliwiło uzyskanie doskonałej przyczepności powłoki farby do podłoża wszystkich materiałów budowlanych.Surprisingly, it turned out that the introduction of new ingredients into cement paints made it possible to obtain excellent adhesion of the paint coating to the substrate of all building materials.
Istotą farby mineralno-polimerowej według wynalazku jest to, że zawiera dyspersję winylową w ilości od 20-40% wagowo, krzemionkę koloidalną i/lub węglan wapniowy strącony i/lub biel cynkową i/lub biel tytanową i/lub pigmenty nieorganiczne w ilości od 15- 25% wagowo, cement portlandzki i/lub gips w ilości od 15-25% wagowo, kwas oleinowy i/lub oleinian wapnia i/lub oleinian glinu w ilości od 0,01-2,5% wagowo. Farba zawiera również w swym składzie lignosulfonian wapniowy i/lub glicerynę w ilości od 0,01- 0,5% wagowo, ftalan dwubutylu i/lub epoksydowy olej rzepakowy w ilości od 0,01-0,2% wagowo, mocznik i/lub chlorek wapnia i/lub siarczan glinu w ilości od 0,01-0,5% wagowo oraz wodę w ilości od 20-40% wagowo.The essence of the mineral-polymer paint according to the invention is that it contains a vinyl dispersion in an amount of 20-40% by weight, colloidal silica and / or precipitated calcium carbonate and / or zinc white and / or titanium white and / or inorganic pigments in an amount of 15 - 25% by weight, Portland cement and / or gypsum in an amount of 15-25% by weight, oleic acid and / or calcium oleate and / or aluminum oleate in an amount of 0.01-2.5% by weight. The paint also contains calcium lignosulfonate and / or glycerin in an amount of 0.01-0.5% by weight, dibutyl phthalate and / or epoxy rapeseed oil in an amount of 0.01-0.2% by weight, urea and / or calcium chloride and / or aluminum sulfate in an amount from 0.01-0.5% by weight and water in an amount from 20-40% by weight.
Zaletą farby mineralno-polimerowej według wynalazku jest doskonała przyczepność powłoki farby do podłoża prawie wszystkich materiałów budowlanych łącznie z drewnem i materiałami drewnopochodnymi. Zaletą farby jest również zupełny brak składników toksycznych skażających środowisko, odporność powłoki na ścieranie i długotrwałe działanie zmiennych czynników oraz korozję biologiczną.The advantage of the mineral-polymer paint according to the invention is the excellent adhesion of the paint coating to the substrate of almost all building materials, including wood and wood-based materials. The advantage of the paint is also the complete absence of toxic components contaminating the environment, resistance of the coating to abrasion and long-term action of variable factors and biological corrosion.
Farbę mineralno-polimerową według wynalazku otrzymuje się przez dokładne zmieszanie w mieszalniku dyspersji winylowej w wodzie, a następnie wprowadza się go do jednorodnej zawiesiny środki hydrofobujące zawierające kwas oleinowy i/lub oleinian wapnia i/lub oleinian glinu i ponownie miesza do uzyskania jednorodnego roztworu. Po czym ciągle mieszając dodaje się lignosulfonian wapniowy i/lub glicerynę a następnie ftalan dwubutylu i/lub epoksydowany olej rzepakowy, mocznik i/lub chlorek wapniowy i/lub siarczan glinowy. Do otrzymanejThe mineral-polymer paint according to the invention is prepared by thoroughly mixing a vinyl dispersion in water in a mixer, and then introducing hydrophobing agents containing oleic acid and / or calcium oleate and / or aluminum oleate into a homogeneous suspension and mixing it again until a homogeneous solution is obtained. Subsequently, with continued stirring, calcium lignosulfonate and / or glycerin are added followed by dibutyl phthalate and / or epoxidized rapeseed oil, urea and / or calcium chloride and / or aluminum sulfate. To received
161 782 mieszaniny wprowadza się krzemionkę koloidalną, węglan wapniowy strącony, biel cynkową, biel tytanową, talk i barwne pigmenty nieorganiczne. W ten sposób otrzymuje się bazową substancję farby mineralno-polimerowej. W młynie kulowym miesza się spoiwa mineralne zawierające cement szary lub biały lub mieszaninę cementu szarego i białego oraz gipsu. Przy czym stosunek poszczególnych cementów szarego i białego może być rożny ale ilość gipsu w mieszankach z cementami nie może przekraczać 10%. Farbę do malowania przygotowuje się bezpośrednio przed użyciem mieszając bazową substancję ze spoiwami mineralnymi do uzyskania jednolitej zawiesiny. Farba nadaje się do malowania w okresie 7 godzin od chwili zmieszania wszystkich składników.The mixture is mixed with colloidal silica, precipitated calcium carbonate, zinc white, titanium white, talc and colored inorganic pigments. In this way, the base substance of the mineral-polymer paint is obtained. In the ball mill, mineral binders containing gray or white cement or a mixture of gray and white cement and gypsum are mixed. The ratio of the individual gray and white cements may be different, but the amount of gypsum in mixtures with cements may not exceed 10%. The paint for painting is prepared immediately before use by mixing the base substance with mineral binders until a uniform suspension is obtained. The paint is suitable for painting within 7 hours from mixing all the ingredients.
Przykład I. Farba według wynalazku ma następujący skład: woda - 25% wag., dyspersja winylowa - 25% wag., krzemionka koloidalna - 10% wag., węglan wapniowy - 10% wag., biel tytanowa - 5% wag., kwas oleinowy - 0,05% wag., oleinian wapnia - 0,05% wag., lignosulfonian wapniowy - 0,05% wag., gliceryna - 0,05% wag., ftalan dwubutylu - 0,05% wag., epoksydowany olej rzepakowy - 0,05% wag., mocznik - 0,05% wag., chlorek wapnia - 0,05% wag., cement portlandzki szary - 24,6% wag.Example I. The paint according to the invention has the following composition: water - 25% by weight, vinyl dispersion - 25% by weight, colloidal silica - 10% by weight, calcium carbonate - 10% by weight, titanium white - 5% by weight, acid oleic - 0.05 wt.%, calcium oleate - 0.05 wt.%, calcium lignosulfonate - 0.05 wt.%, glycerin - 0.05 wt.%, dibutyl phthalate - 0.05 wt.%, epoxidized oil rapeseed - 0.05 wt.%, urea - 0.05 wt.%, calcium chloride - 0.05 wt.%, gray Portland cement - 24.6 wt.%.
Przykład II. Farba według wynalazku ma następujący skład: woda - 20% wag., dyspersja winylowa - 35% wag., krzemionka koloidalna - 10% wag., węglan wapniowy - 10% wag., talk - 5% wag., kwas oleinowy - 0,1% wag., oleinian wapniowy - 0,1% wag., oleinian glinu - 0,05% wag., lignosulfonian wapniowy - 0,1% wag., gliceryna - 0,3% wag., ftalan dwubutylu - 0,2% wag., mocznik - 0,1% wag., chlorek wapnia - 0,2% wag., siarczan glinu 0,2% wag., cement portlandzki szary - 10% wag., cement biały - 7% wag., gips - 1,25% wag.Example II. The paint according to the invention has the following composition: water - 20% by weight, vinyl dispersion - 35% by weight, colloidal silica - 10% by weight, calcium carbonate - 10% by weight, talc - 5% by weight, oleic acid - 0, 1 wt.%, Calcium oleate - 0.1 wt.%, Aluminum oleate - 0.05 wt.%, Calcium lignosulfonate - 0.1 wt.%, Glycerin - 0.3 wt.%, Dibutyl phthalate - 0.2 % by weight, urea - 0.1% by weight, calcium chloride - 0.2% by weight, aluminum sulphate 0.2% by weight, gray Portland cement - 10% by weight, white cement - 7% by weight, gypsum - 1.25 wt.%
Przykład DI. Farba według wynalazku ma następujący skład: woda - 35% wag., dyspersja winylowa - 33% wag., pigmenty nieorganiczne - 15% wag., oleinian wapnia - 0,1% wag., oleinian glinu - 0,5% wag., lignosulfonian wapnia - 0,5% wag., epoksydowany olej rzepakowy - 0,2% wag., mocznik - 0,5% wag., gips - 15,2% wag.Example DI. The paint according to the invention has the following composition: water - 35% by weight, vinyl dispersion - 33% by weight, inorganic pigments - 15% by weight, calcium oleate - 0.1% by weight, aluminum oleate - 0.5% by weight, calcium lignosulfonate - 0.5% by weight, epoxidized rapeseed oil - 0.2% by weight, urea - 0.5% by weight, gypsum - 15.2% by weight.
161 782161 782
Zakład Wydawnictw UP RP. Nakład 90 egz. Cena 10 000 złDepartment of Publishing of the UP RP. Circulation of 90 copies. Price: PLN 10,000
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL28356990A PL161782B2 (en) | 1990-02-01 | 1990-02-01 | A polymere-mineral paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL28356990A PL161782B2 (en) | 1990-02-01 | 1990-02-01 | A polymere-mineral paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL161782B2 true PL161782B2 (en) | 1993-07-30 |
Family
ID=20050088
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL28356990A PL161782B2 (en) | 1990-02-01 | 1990-02-01 | A polymere-mineral paint |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL161782B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101089057B (en) * | 2007-06-29 | 2010-12-08 | 黄衍贵 | Wall surface powder material |
-
1990
- 1990-02-01 PL PL28356990A patent/PL161782B2/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101089057B (en) * | 2007-06-29 | 2010-12-08 | 黄衍贵 | Wall surface powder material |
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