PL1674440T3 - Proces tlenowego, pozbawionego metalu przejściowego, katalitycznego utleniania alkoholi w łagodnych warunkach, z zastosowaniem trwałych wolnych rodników nitroksylowych - Google Patents
Proces tlenowego, pozbawionego metalu przejściowego, katalitycznego utleniania alkoholi w łagodnych warunkach, z zastosowaniem trwałych wolnych rodników nitroksylowychInfo
- Publication number
- PL1674440T3 PL1674440T3 PL05110134T PL05110134T PL1674440T3 PL 1674440 T3 PL1674440 T3 PL 1674440T3 PL 05110134 T PL05110134 T PL 05110134T PL 05110134 T PL05110134 T PL 05110134T PL 1674440 T3 PL1674440 T3 PL 1674440T3
- Authority
- PL
- Poland
- Prior art keywords
- transition metal
- under mild
- mild conditions
- aerobic oxidation
- nitroxyl radicals
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 150000001298 alcohols Chemical class 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 title 1
- 230000003647 oxidation Effects 0.000 title 1
- 238000007254 oxidation reaction Methods 0.000 title 1
- 229910052723 transition metal Inorganic materials 0.000 title 1
- 150000003624 transition metals Chemical class 0.000 title 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- YLFIGGHWWPSIEG-UHFFFAOYSA-N aminoxyl Chemical class [O]N YLFIGGHWWPSIEG-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 125000000075 primary alcohol group Chemical group 0.000 abstract 1
- 150000003333 secondary alcohols Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/019,257 US7030279B1 (en) | 2004-12-23 | 2004-12-23 | Process for transition metal free catalytic aerobic oxidation of alcohols under mild conditions using stable free nitroxyl radicals |
| EP05110134A EP1674440B1 (en) | 2004-12-23 | 2005-10-28 | Process for transition metal free catalytic aerobic oxidation of alcohols under mild conditions using stable free nitroxyl radicals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL1674440T3 true PL1674440T3 (pl) | 2008-10-31 |
Family
ID=36147029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL05110134T PL1674440T3 (pl) | 2004-12-23 | 2005-10-28 | Proces tlenowego, pozbawionego metalu przejściowego, katalitycznego utleniania alkoholi w łagodnych warunkach, z zastosowaniem trwałych wolnych rodników nitroksylowych |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7030279B1 (pl) |
| EP (1) | EP1674440B1 (pl) |
| JP (1) | JP2006176527A (pl) |
| AT (1) | ATE394359T1 (pl) |
| DE (1) | DE602005006511D1 (pl) |
| PL (1) | PL1674440T3 (pl) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004023640A1 (de) * | 2004-05-10 | 2005-12-08 | Degussa Ag | Verfahren zur Herstellung von 4-substituierten 2,2,6,6-Tetramethyl-piperidin-N-oxy- und 2,2,6,6-Tetramethyl-piperidin-N-hydroxy-verbindungen |
| KR20080046276A (ko) * | 2005-11-07 | 2008-05-26 | 마쯔시다덴기산교 가부시키가이샤 | 와이프 패턴 생성 장치 |
| EP1787989A1 (de) * | 2005-11-17 | 2007-05-23 | Degussa GmbH | Triazinverbindungen mit Aminogruppen- und Carboxygruppen-haltigen Substituenten |
| DE102006010347A1 (de) * | 2006-03-03 | 2007-09-06 | Degussa Gmbh | Polymerisationsinhibitor zur Stabilisierung von olefinisch ungesättigten Monomeren |
| US20100152435A1 (en) * | 2007-03-14 | 2010-06-17 | Stapley Jonathan A | Compositions and processes for the selective catalytic oxidation of alcohols |
| DE102007052891A1 (de) | 2007-11-02 | 2009-05-07 | Evonik Degussa Gmbh | Verfahren zur Stabilisierung von olefinisch ungesättigten Monomeren |
| DE102009000662A1 (de) | 2009-02-06 | 2010-08-12 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Aldehyden und Ketonen aus primären und sekundären Alkoholen |
| DE102009000661A1 (de) | 2009-02-06 | 2010-08-12 | Evonik Degussa Gmbh | Verfahren zur Herstellung von 2,6-Dioxabicyclo-(3.3.0)-octan-4,8-dion[1S,5S] |
| WO2010101993A2 (en) * | 2009-03-03 | 2010-09-10 | University Of Florida Research Foundation, Inc. | Trianionic pincer ligands, a cr(iii)/cr(v) catalytic system and its use for catalytic aerobic oxidation of organic substrates |
| JP5635275B2 (ja) * | 2010-01-28 | 2014-12-03 | 日清紡ホールディングス株式会社 | アルコールの酸化方法 |
| DE102010030991A1 (de) | 2010-07-06 | 2012-01-12 | Evonik Degussa Gmbh | Verfahren zur Herstellung von 2,5-Diformylfuran und seiner Derivate |
| PL2697231T3 (pl) * | 2011-04-12 | 2015-07-31 | Evonik Degussa Gmbh | Zdolny do ciągłego działania sposób wytwarzania związków karbonylowych za pomocą katalizatorów zawierających rodnik nitroksylowy |
| FR2984889B1 (fr) * | 2011-12-22 | 2017-02-24 | Roquette Freres | Procede ameliore d'oxydation selective du 5-hydromethyl furaldehyde |
| US10081759B2 (en) | 2012-10-09 | 2018-09-25 | Eric John Wernimont | Method, apparatus, and composition for increased recovery of hydrocarbons by paraffin and asphaltene control from reaction of fuels and selective oxidizers in the subterranean environment |
| DE102013204950A1 (de) | 2013-03-20 | 2014-09-25 | Evonik Industries Ag | Verfahren und Zusammensetzung zur Inhibierung der Polymerisation von Cyclopentadienverbindungen |
| JP6535949B2 (ja) * | 2015-03-24 | 2019-07-03 | 国立大学法人山口大学 | 第二級アルコールの保管方法および充填体 |
| JP7007885B2 (ja) * | 2017-12-13 | 2022-02-10 | 株式会社日本触媒 | 芳香環を有するアルデヒド化合物の製造方法 |
| WO2023054702A1 (ja) * | 2021-09-30 | 2023-04-06 | クミアイ化学工業株式会社 | アルデヒド化合物及びジヒドロイソキサゾール化合物の製造方法 |
| CN115215737B (zh) * | 2022-07-21 | 2023-06-27 | 嘉兴学院 | 一种醇选择性氧化制醛或酮的方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5155280A (en) * | 1991-09-30 | 1992-10-13 | Shell Oil Company | Process for the oxidation of alcohols to aldehydes |
| US5155279A (en) * | 1991-10-18 | 1992-10-13 | Shell Oil Company | Process for the oxidation of alcohols to aldehydes |
| US5821374A (en) | 1995-11-21 | 1998-10-13 | Hoffmann-La Roche Inc. | Process for the oxidation of alcohols |
| US6335464B1 (en) * | 1997-09-08 | 2002-01-01 | Chugai Seiyaku Kabushiki Kaisha | Process for selectively oxidizing primary hydroxyl groups of organic compounds, and resin containing adsorbed catalyst for use therein |
| US6498269B1 (en) * | 2000-10-17 | 2002-12-24 | The University Of Connecticut | Method for the oxidation of aldehydes, hemiacetals and primary alcohols |
| ATE257136T1 (de) * | 2001-10-11 | 2004-01-15 | Consortium Elektrochem Ind | Verfahren zur oxidation von alkoholen unter katalyse von nitroxylverbindungen |
| US6825384B1 (en) * | 2004-01-29 | 2004-11-30 | The Nutrasweet Company | Bromine free TEMPO based catalyst system for oxidation of primary and secondary alcohols using NaOCl as an oxidant |
| ATE480510T1 (de) * | 2004-02-26 | 2010-09-15 | Nutrasweet Property Holdings I | Katalysatorsystem zur aeoroben oxidation von primären und sekundären alkoholen |
-
2004
- 2004-12-23 US US11/019,257 patent/US7030279B1/en not_active Expired - Fee Related
-
2005
- 2005-10-28 EP EP05110134A patent/EP1674440B1/en not_active Expired - Lifetime
- 2005-10-28 AT AT05110134T patent/ATE394359T1/de not_active IP Right Cessation
- 2005-10-28 PL PL05110134T patent/PL1674440T3/pl unknown
- 2005-10-28 DE DE602005006511T patent/DE602005006511D1/de not_active Expired - Lifetime
- 2005-12-26 JP JP2005373293A patent/JP2006176527A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| US7030279B1 (en) | 2006-04-18 |
| JP2006176527A (ja) | 2006-07-06 |
| ATE394359T1 (de) | 2008-05-15 |
| EP1674440B1 (en) | 2008-05-07 |
| DE602005006511D1 (de) | 2008-06-19 |
| EP1674440A1 (en) | 2006-06-28 |
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