PL1674440T3 - Proces tlenowego, pozbawionego metalu przejściowego, katalitycznego utleniania alkoholi w łagodnych warunkach, z zastosowaniem trwałych wolnych rodników nitroksylowych - Google Patents
Proces tlenowego, pozbawionego metalu przejściowego, katalitycznego utleniania alkoholi w łagodnych warunkach, z zastosowaniem trwałych wolnych rodników nitroksylowychInfo
- Publication number
- PL1674440T3 PL1674440T3 PL05110134T PL05110134T PL1674440T3 PL 1674440 T3 PL1674440 T3 PL 1674440T3 PL 05110134 T PL05110134 T PL 05110134T PL 05110134 T PL05110134 T PL 05110134T PL 1674440 T3 PL1674440 T3 PL 1674440T3
- Authority
- PL
- Poland
- Prior art keywords
- transition metal
- under mild
- mild conditions
- aerobic oxidation
- nitroxyl radicals
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 150000001298 alcohols Chemical class 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 title 1
- 230000003647 oxidation Effects 0.000 title 1
- 238000007254 oxidation reaction Methods 0.000 title 1
- 229910052723 transition metal Inorganic materials 0.000 title 1
- 150000003624 transition metals Chemical class 0.000 title 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- YLFIGGHWWPSIEG-UHFFFAOYSA-N aminoxyl Chemical class [O]N YLFIGGHWWPSIEG-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 125000000075 primary alcohol group Chemical group 0.000 abstract 1
- 150000003333 secondary alcohols Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/019,257 US7030279B1 (en) | 2004-12-23 | 2004-12-23 | Process for transition metal free catalytic aerobic oxidation of alcohols under mild conditions using stable free nitroxyl radicals |
| EP05110134A EP1674440B1 (en) | 2004-12-23 | 2005-10-28 | Process for transition metal free catalytic aerobic oxidation of alcohols under mild conditions using stable free nitroxyl radicals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL1674440T3 true PL1674440T3 (pl) | 2008-10-31 |
Family
ID=36147029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL05110134T PL1674440T3 (pl) | 2004-12-23 | 2005-10-28 | Proces tlenowego, pozbawionego metalu przejściowego, katalitycznego utleniania alkoholi w łagodnych warunkach, z zastosowaniem trwałych wolnych rodników nitroksylowych |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7030279B1 (pl) |
| EP (1) | EP1674440B1 (pl) |
| JP (1) | JP2006176527A (pl) |
| AT (1) | ATE394359T1 (pl) |
| DE (1) | DE602005006511D1 (pl) |
| PL (1) | PL1674440T3 (pl) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004023640A1 (de) * | 2004-05-10 | 2005-12-08 | Degussa Ag | Verfahren zur Herstellung von 4-substituierten 2,2,6,6-Tetramethyl-piperidin-N-oxy- und 2,2,6,6-Tetramethyl-piperidin-N-hydroxy-verbindungen |
| WO2007052771A1 (ja) * | 2005-11-07 | 2007-05-10 | Matsushita Electric Industrial Co., Ltd. | ワイプパターン生成装置 |
| EP1787989A1 (de) * | 2005-11-17 | 2007-05-23 | Degussa GmbH | Triazinverbindungen mit Aminogruppen- und Carboxygruppen-haltigen Substituenten |
| DE102006010347A1 (de) * | 2006-03-03 | 2007-09-06 | Degussa Gmbh | Polymerisationsinhibitor zur Stabilisierung von olefinisch ungesättigten Monomeren |
| US20100152435A1 (en) * | 2007-03-14 | 2010-06-17 | Stapley Jonathan A | Compositions and processes for the selective catalytic oxidation of alcohols |
| DE102007052891A1 (de) | 2007-11-02 | 2009-05-07 | Evonik Degussa Gmbh | Verfahren zur Stabilisierung von olefinisch ungesättigten Monomeren |
| DE102009000661A1 (de) | 2009-02-06 | 2010-08-12 | Evonik Degussa Gmbh | Verfahren zur Herstellung von 2,6-Dioxabicyclo-(3.3.0)-octan-4,8-dion[1S,5S] |
| DE102009000662A1 (de) | 2009-02-06 | 2010-08-12 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Aldehyden und Ketonen aus primären und sekundären Alkoholen |
| US8846950B2 (en) | 2009-03-03 | 2014-09-30 | University Of Florida Research Foundation, Inc. | Trianionic pincer ligands, a CR(III)/CR(V) catalytic system and its use for catalytic aerobic oxidation of organic substrates |
| JP5635275B2 (ja) * | 2010-01-28 | 2014-12-03 | 日清紡ホールディングス株式会社 | アルコールの酸化方法 |
| DE102010030991A1 (de) | 2010-07-06 | 2012-01-12 | Evonik Degussa Gmbh | Verfahren zur Herstellung von 2,5-Diformylfuran und seiner Derivate |
| JP6021892B2 (ja) * | 2011-04-12 | 2016-11-09 | エボニック デグサ ゲーエムベーハーＥｖｏｎｉｋ Ｄｅｇｕｓｓａ ＧｍｂＨ | ニトロキシルラジカルを含む触媒を用いてカルボニル化合物を製造する、連続運転可能な方法 |
| FR2984889B1 (fr) * | 2011-12-22 | 2017-02-24 | Roquette Freres | Procede ameliore d'oxydation selective du 5-hydromethyl furaldehyde |
| US10081759B2 (en) | 2012-10-09 | 2018-09-25 | Eric John Wernimont | Method, apparatus, and composition for increased recovery of hydrocarbons by paraffin and asphaltene control from reaction of fuels and selective oxidizers in the subterranean environment |
| DE102013204950A1 (de) | 2013-03-20 | 2014-09-25 | Evonik Industries Ag | Verfahren und Zusammensetzung zur Inhibierung der Polymerisation von Cyclopentadienverbindungen |
| JP6535949B2 (ja) * | 2015-03-24 | 2019-07-03 | 国立大学法人山口大学 | 第二級アルコールの保管方法および充填体 |
| JP7007885B2 (ja) * | 2017-12-13 | 2022-02-10 | 株式会社日本触媒 | 芳香環を有するアルデヒド化合物の製造方法 |
| JPWO2023054702A1 (pl) * | 2021-09-30 | 2023-04-06 | ||
| CN115215737B (zh) * | 2022-07-21 | 2023-06-27 | 嘉兴学院 | 一种醇选择性氧化制醛或酮的方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5155280A (en) * | 1991-09-30 | 1992-10-13 | Shell Oil Company | Process for the oxidation of alcohols to aldehydes |
| US5155279A (en) * | 1991-10-18 | 1992-10-13 | Shell Oil Company | Process for the oxidation of alcohols to aldehydes |
| US5821374A (en) | 1995-11-21 | 1998-10-13 | Hoffmann-La Roche Inc. | Process for the oxidation of alcohols |
| WO1999012644A1 (en) * | 1997-09-08 | 1999-03-18 | Chugai Seiyaku Kabushiki Kaisha | Process for selectively oxidizing primary hydroxyl groups of organic compounds, and resin containing adsorbed catalyst for use therein |
| US6498269B1 (en) * | 2000-10-17 | 2002-12-24 | The University Of Connecticut | Method for the oxidation of aldehydes, hemiacetals and primary alcohols |
| EP1302456B1 (de) * | 2001-10-11 | 2004-01-02 | Consortium für elektrochemische Industrie GmbH | Verfahren zur Oxidation von Alkoholen unter Katalyse von Nitroxylverbindungen |
| US6825384B1 (en) * | 2004-01-29 | 2004-11-30 | The Nutrasweet Company | Bromine free TEMPO based catalyst system for oxidation of primary and secondary alcohols using NaOCl as an oxidant |
| WO2005082825A1 (en) * | 2004-02-26 | 2005-09-09 | The Nutrasweet Company | Catalyst system for aeorobic oxidation of primary and secondary alcohols. |
-
2004
- 2004-12-23 US US11/019,257 patent/US7030279B1/en not_active Expired - Fee Related
-
2005
- 2005-10-28 EP EP05110134A patent/EP1674440B1/en not_active Expired - Lifetime
- 2005-10-28 AT AT05110134T patent/ATE394359T1/de not_active IP Right Cessation
- 2005-10-28 PL PL05110134T patent/PL1674440T3/pl unknown
- 2005-10-28 DE DE602005006511T patent/DE602005006511D1/de not_active Expired - Lifetime
- 2005-12-26 JP JP2005373293A patent/JP2006176527A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006176527A (ja) | 2006-07-06 |
| EP1674440A1 (en) | 2006-06-28 |
| ATE394359T1 (de) | 2008-05-15 |
| EP1674440B1 (en) | 2008-05-07 |
| US7030279B1 (en) | 2006-04-18 |
| DE602005006511D1 (de) | 2008-06-19 |
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