PL18239B1 - The method of obtaining acid alkali metal salts and phosphorus was used, e.g. from organic substances containing phosphorus, especially from oily plants or their marc. - Google Patents
The method of obtaining acid alkali metal salts and phosphorus was used, e.g. from organic substances containing phosphorus, especially from oily plants or their marc. Download PDFInfo
- Publication number
- PL18239B1 PL18239B1 PL18239A PL1823932A PL18239B1 PL 18239 B1 PL18239 B1 PL 18239B1 PL 18239 A PL18239 A PL 18239A PL 1823932 A PL1823932 A PL 1823932A PL 18239 B1 PL18239 B1 PL 18239B1
- Authority
- PL
- Poland
- Prior art keywords
- phosphorus
- alkali metal
- organic substances
- metal salts
- containing phosphorus
- Prior art date
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- 239000002253 acid Substances 0.000 title claims description 11
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims description 7
- 238000000034 method Methods 0.000 title claims description 7
- 239000011574 phosphorus Substances 0.000 title claims description 7
- 229910052698 phosphorus Inorganic materials 0.000 title claims description 7
- 239000000126 substance Substances 0.000 title claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 title claims description 3
- -1 alkali metal salts Chemical class 0.000 title claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 238000000605 extraction Methods 0.000 claims description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 2
- 229920000715 Mucilage Polymers 0.000 claims 1
- 239000000853 adhesive Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 159000000014 iron salts Chemical class 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 235000020094 liqueur Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Description
Wynalazek niniejszy dotyczy sposobu o- trzymywania latwo rozpuszczalnych w wo¬ dzie soli metali alkalicznych kwasu inozy- tofosforowego z substancyj organicznych, zawierajacych fosfor, z roslin i nasion, zwlaszcza z roslin oleistych lub ich wytlo¬ czyn.Patenty Nr 11053 i Nr 14184 opisuja sposoby otrzymywania substancyj, zawie¬ rajacych fosfor, które sa malorozpuszezal- ne w wodzie, zas patent Nr 14185 opisuje sposób, wedlug którego, przez czesciowe za¬ stapienie magnezu w substancjach orga¬ nicznych zawierajacych fosfor wapniem, o- trzymuje sie substancje te w stanie calko¬ wicie rozpuszczalnym w wodzie.Sposoby wedlug wymienionych paten¬ tów przedstawiaja jednak pewne niedogod¬ nosci, polegajace na tern, ze zwiazki we¬ dlug patentów Nr 11053 i 14184 sa malo rozpuszczalne w wodzie, zas wedlug paten¬ tu Nr 14185 jakkolwiek rozpuszczalne w wodzie ulegaja pod wplywem ciepla samo¬ czynnie wytraceniu z roztworu wodnego.Wlasciwosci jednego i drugiego rodza¬ ju zwiazków ograniczaja mozliwosc stoso¬ wania tych zwiazków w postaci preparatów farmaceutycznych.Sposób wedlug wynalazku usuwa te niedogodnosci i polega na tern, ze ekstra¬ huje sie wytloczyny z nasion oleistych roz¬ tworami kwasów, nastepnie otrzymane wy¬ ciagi wytraca sie przy pomocy soli zelaza bezposrednio, lub tez posrednio, zadajac je najpierw alkaljami, nastepnie rozpuszczajac otrzymany strat, w kwasie, a dopiero potem zadajac ten kwasny rozczyn solami zelaza.Oddzielone straty zelazowe przemywa sie woda i rozklada w roztworach wodorotlen¬ ku metalu alkalicznego w aparaturze chro¬ niacej mase reakcyjna od wplywu C02 z powietrza. Z alkalicznego roztworu tych stratów otrzymuje sie przy pomocy plynów organicznych, np. alkoholu, osad, który po wysuszeniu przedstawia soba czysta sól al¬ kaliczna kwasu inozytofosforowego w po¬ staci bialego proszku latwo rozpuszczalne¬ go w wodzie.Przyklad L 100 czesci wytloczyn na¬ sion oleistych ekstrahuje sie 300 czesciami dowolnego kwasu mineralnego, np. kwasu solnego lub odpowiedniego kwasu organicz¬ nego np. octowego i uzyskany plyn poeks¬ trakcyjny zadaje sie roztworem chlorku ze¬ laza do calkowitego wytracenia. Przemyty osad zelazowy przenosi sie do aparatury, chroniacej zawartosc od wplywu C02 znaj¬ dujacego sie w powietrzu, zadajac stopnio¬ wo roztworem lugu sodowego, ogrzewajac na lazni wodnej i utrzymujac stale alka¬ licznosc plynu, wskutek czego nastepuje rozklad osadu zelazowego i wytwarza sie o- sad wodorotlenku zelaza. Tym sposobem o- siaga sie slabo-alkaliczny roztwór inozyto- fosforanu sodowego, który przelewa sie do alkoholu, co daje moznosc uzyskania soli sodowej kwasu inozytofosforowego w posta¬ ci stalej, wolnej od obcych domieszek i la¬ two rozpuszczalnej w wodzie.Przyklad II. Otrzymany wedlug pa¬ tentu Nr 11053 zapomoca ekstrakcji kwaso¬ wej surowca, a nastepnie przez zadanie al¬ kaljami osad, rozpuszcza sie w 10%-owym kwasie solnym, dodawanym w ilosci po¬ trzebnej do uzyskania kwasnej reakcji na papierek kongo, nastepnie roztwór filtruje sie i wytraca roztworem chlorku zelazowe¬ go, poczem otrzymany osad rozklada sie zapomoca roztworu lugu sodowego na go¬ raco, tak, jak w przykladzie I. PLThe present invention relates to a process for obtaining easily water-soluble alkali metal salts of inositophosphoric acid from phosphorus-containing organic substances from plants and seeds, in particular from oil plants or their cultivation. Patents No. 11053 and No. 14184 describe the methods of to obtain phosphorus-containing substances that are not soluble in water, and patent No. 14185 describes a method according to which, by partially replacing magnesium in organic substances containing phosphorus with calcium, these substances are kept completely The methods of these patents present some disadvantages, however, that the compounds according to patents Nos. 11053 and 14184 are slightly soluble in water, and according to patent No. 14185, although soluble in water under the influence of heat, they are automatically released from the aqueous solution. The properties of both types of compounds limit the possibility of The method according to the invention removes these drawbacks and consists in extracting oilseed mash with acid solutions, then crushing the resulting extracts with iron salts directly or also indirectly, first by treating them with alkali, then by dissolving the resulting loss in acid, and then by adding this acid solution with iron salts. The separated iron losses are washed with water and decomposed in the alkali metal hydroxide solutions in an apparatus protecting the reaction mass from the influence of CO 2 from the air. From the alkaline solution of these losses, a precipitate is obtained with the aid of organic liquids, e.g. alcohol, which after drying shows the pure alkaline salt of inositophosphoric acid in the form of a white powder easily soluble in water. The oily seeds are extracted with 300 parts of any mineral acid, for example hydrochloric acid or a suitable organic acid, for example acetic acid, and the resulting extraction fluid is mixed with a solution of iron chloride until complete precipitation. The washed iron sludge is transferred to the equipment that protects its content from the influence of CO 2 present in the air, gradually applying a solution of soda lye, heating it in a water bath and constantly maintaining the alkalinity of the fluid, as a result of which the decomposition of the iron sludge occurs and produces - iron hydroxide orchard. In this way, a weakly alkaline solution of sodium inositophosphate is obtained, which is poured into alcohol, which makes it possible to obtain the sodium salt of inositophosphoric acid in a solid form, free from foreign impurities and water-soluble lattice. Example II. The obtained according to the patent No. 11053 by means of acidic extraction of the raw material, and then by adding alkalis to the precipitate, is dissolved in 10% hydrochloric acid, added in an amount necessary to obtain an acid reaction on the congo paper, then the solution is filtered and triturated with ferric chloride solution, then the obtained precipitate is decomposed with the sodium liqueur solution on a warm basis, as in example I. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL18239B1 true PL18239B1 (en) | 1933-04-29 |
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