PL20450B1 - The method of wetting, cleaning and refining textiles. - Google Patents
The method of wetting, cleaning and refining textiles. Download PDFInfo
- Publication number
- PL20450B1 PL20450B1 PL20450A PL2045030A PL20450B1 PL 20450 B1 PL20450 B1 PL 20450B1 PL 20450 A PL20450 A PL 20450A PL 2045030 A PL2045030 A PL 2045030A PL 20450 B1 PL20450 B1 PL 20450B1
- Authority
- PL
- Poland
- Prior art keywords
- wetting
- aliphatic
- cleaning
- compounds
- textiles
- Prior art date
Links
- 238000009736 wetting Methods 0.000 title claims description 5
- 238000004140 cleaning Methods 0.000 title claims 2
- 238000000034 method Methods 0.000 title claims 2
- 238000007670 refining Methods 0.000 title claims 2
- 239000004753 textile Substances 0.000 title claims 2
- 239000002253 acid Substances 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- -1 aliphatic alcohols Chemical class 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 238000006277 sulfonation reaction Methods 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 235000021313 oleic acid Nutrition 0.000 claims 1
- 150000002889 oleic acids Chemical class 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 239000001828 Gelatine Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
Description
Jako srodki zwilzajace, oczyszczajace, rozpraszajace i rozpuszczajace moga sluzyc kwasne estry kwasu siarkowego wzglednie ich sole, otrzymane przez sulfonowanie zwiazków alifatycznych, cykloalifatycznych albo alifatyczno-aromatycznych, zawieraja¬ cych przynajmniej jedno podwójne wiaza¬ nie olefinowe oraz jedna lub kilka grup wo¬ dorotlenowych, lecz niezawierajacych grup karboksylowych lub tez zwiazków, które la¬ two mozna przeprowadzic w tego rodzaju zwiazki, z wyjatkiem alifatycznych alkoho¬ li, odpowiadajacych kwasom tluszczowym lub olejowym.Produkty, otrzymane w opisany sposób, odznaczaja sie tern, ze ich zdolnosc zwilza¬ nia jest równie dobra w kapieli obojetnej, kwasnej lub zasadowej. Ponadto posiadaja one zdolnosc zmiekczania wody, czyniac ja bardziej przydatna do prania. Wobec tego nadaja sie one do uszlachetniania wlókien roslinnych, zwierzecych oraz sztucznych wszelkiego rodzaju, czyniac je szczególnie zdatnemi do dalszej przeróbki, to jest far¬ bowania, drukowania i t. d. Przy drukowa¬ niu powoduja one równomierne zabarwie¬ nie tkaniny lub nici i traktowane materja- ly czynia miekkiemi i pelnemi w dotyku.Estry kwasu siarkowego lub ich sole, roz¬ puszczalne w wodzie, mozna zastosowaclacznic z mydlami lub srodkami do mydel podobnemi, jak olejem tureckim, cialami zwilzajacemi, alkylówariemi sulfokwasami aromatycznenii, lub razem z organicznemi rozpuszczalnikami, jak szesciohydrofeno- iem, czterochlorkiem wegla, lub razem z so¬ lami obojetnemi, organicznemi lub nieorga- nicznemi, ulatwiajacemi mycie lub wreszcie z cialami ochronnemi, jak klejem, zelatyna i id.Przyklad. Plynne olefiny, otrzymane z czesci produktu utleniania weglowodorów parafinowych i naftenowych, nierozpu¬ szczalnej w eterze naftowym, wykazujace wskutek odczepienia wody lub dwutlenku wegla liczbe jodowa ponad 100, sulfonuje sie w zwykly sposób, uwalnia od nadmiaru srodka sulfonujacego i zobojetnia alkalja- mi. 5 g otrzymanego produktu rozpuszcza sie w 1 litrze wody.Otrzymany roztwór zwilza kazde wlókno doskonale zarówno w kapieli obojetnej, jak kwasnej lub zasadowej. PLAs wetting, purifying, dispersing and dissolving agents, acid esters of sulfuric acid or their salts, obtained by sulfonation of aliphatic, cycloaliphatic or aliphatic-aromatic compounds containing at least one olefinic double bond and one or more hydroxyl groups, can be used. but not containing carboxyl groups or compounds which can easily be converted into such compounds, with the exception of aliphatic alcohols corresponding to fatty or oleaginous acids. The products obtained in this manner are distinguished by the fact that their wetting capacity is equally good in neutral, acid or alkaline baths. In addition, they have the ability to soften water, making it more suitable for washing. Therefore, they are suitable for upgrading plant, animal and artificial fibers of all kinds, making them particularly suitable for further processing, i.e. dyeing, printing, etc. They make them soft and soft to the touch. Sulfuric acid esters or their salts, soluble in water, can be used with soaps or soap agents similar to Turkish oil, wetting bodies, aromatic alkylsulfo acids, or together with organic solvents, such as - iem, carbon tetrachloride, or together with inert, organic or inorganic salts that facilitate washing or, finally, with protective bodies such as glue, gelatine, etc. Example. Liquid olefins, obtained from part of the oxidation product of paraffinic and naphthenic hydrocarbons, which are insoluble in petroleum ether, have an iodine number of more than 100 due to the cleavage of water or carbon dioxide, are sulfonated in the usual way, freed from excess sulfonating agent and neutralized with alkali. 5 g of the product obtained is dissolved in 1 liter of water. The obtained solution wets each fiber perfectly in an neutral bath, as well as an acid or alkaline bath. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL20450B1 true PL20450B1 (en) | 1934-09-29 |
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