PL20737B1 - A method of producing derivatives of higher fatty alcohols. - Google Patents
A method of producing derivatives of higher fatty alcohols. Download PDFInfo
- Publication number
- PL20737B1 PL20737B1 PL20737A PL2073733A PL20737B1 PL 20737 B1 PL20737 B1 PL 20737B1 PL 20737 A PL20737 A PL 20737A PL 2073733 A PL2073733 A PL 2073733A PL 20737 B1 PL20737 B1 PL 20737B1
- Authority
- PL
- Poland
- Prior art keywords
- fatty alcohols
- higher fatty
- producing derivatives
- derivatives
- alcohols
- Prior art date
Links
- 150000002191 fatty alcohols Chemical class 0.000 title claims description 4
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 claims description 3
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- ALSTYHKOOCGGFT-UHFFFAOYSA-N cis-oleyl alcohol Natural products CCCCCCCCC=CCCCCCCCCO ALSTYHKOOCGGFT-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
Przedmiotem niniejszego wynalazku jest sulfonowanie wyzszych al¬ koholi tluszczowych kwasem chlorosulfo- nowym w obecnosci weglowodorów alifa¬ tycznych, zawierajacych chlor.Przy traktowaniu taka mieszanina al¬ koholi tluszczowych nastepuje jednoczesnie kondensacja i sulfonowanie. W rezultacie otrzymuje sie produkty odporne w dowol¬ nej temperaturze na dzialanie soli wapnia, magnezu i kwasu siarkowego.Przyklad. 100 kg alkoholu oleinowego miesza sie ze 100 kg czterochloroetanu.Otrzymana mieszanke traktuje sie 100 kg kwasu chlorosulfonowego w temperaturze 0°C. Produkt reakcji po przeplókaniu woda i zobojetnieniu daje mydlo, zupelnie odpor¬ ne na dzialanie soli wapnia i kwasu siarko¬ wego. PLThe subject of the present invention is the sulfonation of higher fatty alcohols with chlorosulfonic acid in the presence of chlorine-containing aliphatic hydrocarbons. In the treatment, this mixture of fatty alcohols is simultaneously condensed and sulfonated. As a result, products are obtained which are resistant at any temperature to the action of calcium, magnesium and sulfuric acid salts. 100 kg of oleic alcohol is mixed with 100 kg of tetrachlorethane. The resulting mixture is treated with 100 kg of chlorosulfonic acid at 0 ° C. The reaction product, after rinsing with water and neutralization, gives a soap that is completely resistant to the action of calcium salts and sulfuric acid. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL20737B1 true PL20737B1 (en) | 1934-12-31 |
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