PL228357B1 - Paper layer for stream printing - Google Patents
Paper layer for stream printingInfo
- Publication number
- PL228357B1 PL228357B1 PL405943A PL40594313A PL228357B1 PL 228357 B1 PL228357 B1 PL 228357B1 PL 405943 A PL405943 A PL 405943A PL 40594313 A PL40594313 A PL 40594313A PL 228357 B1 PL228357 B1 PL 228357B1
- Authority
- PL
- Poland
- Prior art keywords
- paper
- coating
- chloride
- printer
- inkjet
- Prior art date
Links
- 238000000576 coating method Methods 0.000 claims description 16
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 229920000768 polyamine Polymers 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 claims description 3
- 239000000429 sodium aluminium silicate Substances 0.000 claims description 3
- 235000012217 sodium aluminium silicate Nutrition 0.000 claims description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 3
- 239000005871 repellent Substances 0.000 claims 1
- 239000000976 ink Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 102200150779 rs200154873 Human genes 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- -1 vinyl acetal resin Chemical compound 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000984082 Amoreuxia Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000011354 acetal resin Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000010981 turquoise Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/02—Metal coatings
- D21H19/06—Metal coatings applied as liquid or powder
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/84—Paper comprising more than one coating on both sides of the substrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/34—Both sides of a layer or material are treated, e.g. coated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Ink Jet (AREA)
- Paper (AREA)
Description
(21) Numer zgłoszenia: 405943(21) Filing number: 405943
Urząd Patentowy Rzeczypospolitej Polskiej (22) Data zgłoszenia: 06.11.2013 (51) Int CI.Patent Office of the Republic of Poland (22) Application date: November 6, 2013 (51) Int CI.
B41M 5/52 (2006.01) D21H 19/06 (2006.01) D21H 19/84 (2006.01) D21H 21/16 (2006.01) (54)B41M 5/52 (2006.01) D21H 19/06 (2006.01) D21H 19/84 (2006.01) D21H 21/16 (2006.01) (54)
Powłoka papieru do druku strumieniowegoInkjet paper coating
rm co corm what what
CMCM
CMCM
Ω.Ω.
PL 228 357 B1PL 228 357 B1
Opis wynalazkuDescription of the invention
Przedmiotem wynalazku jest powłoka papieru do druku strumieniowego (ink-jet) i jej zastosowanie.The present invention relates to the coating of ink-jet paper and its use.
Zapoczątkowana w drugiej połowie dwudziestego wieku technika druku strumieniowego wywołała zapotrzebowanie na papier o odpowiedniej jakości. W ostatnich latach minionego wieku zaczęto stosować specjalne powłoki przystosowane do przyjmowania tuszu w czasie druku, aby poprawić jakość wydruku. Osiągnięto ten cel stosując na podkłady papierowe powłoki o charakterze hydrofilnym, stosując żel krzemionkowy, alkohol poliwinylowy i/lub karboksymetylocelulozę plus niskocząsteczkowy polimer kationowy (np. zmodyfikowaną polietylenoiminę, poliwinyloaminę, produkt kondensacji organicznych amidów z formaldehydem, poliakryloamidem) [Handbook of Paper and Board. Pod red. H. Holik, WILEY-VCH Verlag GmbH & Co. KgaA, 2006, Weinheim, str. 98-98], Literatura patentowa i fachowa podaje wiele wersji powłok papieru do druku strumieniowego.The inkjet technique, which was initiated in the second half of the twentieth century, created a demand for paper of the appropriate quality. In the last years of the last century, special coatings adapted to receiving ink during printing began to be used in order to improve the print quality. This goal was achieved by using hydrophilic coatings on paper backings using silica gel, polyvinyl alcohol and / or carboxymethyl cellulose plus a low molecular weight cationic polymer (e.g. modified polyethyleneimine, polyvinylamine, organic amide-formaldehyde condensation product, polyacrylamide Paper and Board) [Handbook of Paper and Board). Edited by H. Holik, WILEY-VCH Verlag GmbH & Co. KgaA, 2006, Weinheim, pp. 98-98], Patent and specialist literature gives many versions of inkjet paper coatings.
Znany jest z opisu patentowego nr US 4,554,181 podkład papierowy do druku strumieniowego posiadający dwuskładnikową kationową powierzchnię. Kationowe polimery stosowane w rozwiązani u tego wynalazku charakteryzują się tym, że grupy kationowe są dostępne dla anionowych składników barwnika(ów) atramentu. Drugim źródłem kationów według tego opisu są wielowartościowe sole metali z II, III i przejściowej grupy układu okresowego, o rozpuszczalności większej niż 5 g w 100 ml wody o temperaturze 23°C. Z powodu zabarwiania papieru niezbyt korzystne są sole Fe2-, Fe3+ i Cu2+. Ujawniono, że sole mocnych kwasów (w tym chlorowodorowego) mogą być stosowane jako związki wiążące części anionowe tuszu, ale części anionowe tych mocnych kwasów przyspieszają rozkład papieru.It is known from US Patent No. 4,554,181 an inkjet paper backing having a two-component cationic surface. The cationic polymers used in the practice of this invention are characterized in that the cationic groups are accessible to the anionic components of the ink dye (s). The second source of cations according to this description are multivalent metal salts of II, III and transition group of the periodic table, having a solubility greater than 5 g in 100 ml of water at 23 ° C. Because scorch paper not suitable salts are Fe 2, Fe + 3 and Cu + 2. It has been disclosed that salts of strong acids (including hydrochloric) can be used as binders for the anionic parts of the ink, but the anionic parts of these strong acids accelerate the decomposition of the paper.
Z japońskiego opisu zgłoszenia wynalazku JP 2001315433 znana jest powłoka dla papieru do druku strumieniowego, która składa się z 2-10 części wagowych nieorganicznego elektrolitu (korzystnie chlorku sodu), 0-100 części wagowych porowatego materiału adsorbującego (np. ziarna krzemionki) do 100 części wagowych hydrofitowej żywicy lub żywicy winyloacetalowej. Mieszanina jest przygotowywana na folii polietylenowej, a następnie przenoszona na papier.From the Japanese description of the invention application JP 2001315433 a coating for inkjet paper is known, which consists of 2-10 parts by weight of an inorganic electrolyte (preferably sodium chloride), 0-100 parts by weight of a porous adsorbent material (e.g. silica grains) to 100 parts by weight of a hydrophilic vinyl acetal resin or resin. The mixture is prepared on a polyethylene film and then transferred to paper.
Powłoka papieru do druku strumieniowego według niniejszego wynalazku, składająca się z glinokrzemianu sodowego, chlorku sodu, alkoholu poliwinylowego, poliaminy alifatycznej i chlorku poliglinu, o właściwościach hydrofitowych, charakteryzuje się, że stosunek masowy chlorku sodu i chlorku poliglinu do poliaminy alifatycznej wynosi 9,6 : 1. Powłoka papieru jest nakładana maszynowo na podkład papierowy jedno- lub dwustronnie.The inkjet coating of the present invention, consisting of sodium aluminosilicate, sodium chloride, polyvinyl alcohol, aliphatic polyamine and polyaluminium chloride, with hydrophytic properties, is characterized by a weight ratio of sodium chloride and polyaluminium chloride to aliphatic polyamine being 9.6: 1. The paper coating is applied by machine to the paper backing on one or both sides.
Nieoczekiwanie, pomimo tak wysokiej zawartości chlorków i sodu, papier powleczony powłoką według wynalazku z jednej strony jest trwały, z drugiej strony zapewnia dobrą jakość druku. Ponadto nadaje się do bezpośredniego, maszynowego nakładania na papier standardowymi maszynami. W badaniach laboratoryjnych papierów z powłokami do druku strumieniowego zmierzono następujące parametry: jednorodność zadruku (mottling), przebijanie druku (show through), ostrość (bleeding), gęstość optyczną. Papier z powłoką według wynalazku przygotowano na prasie zaklejającej maszyny papierniczej. Ocena powłok polegała na ocenie zadruku papieru przy użyciu:Surprisingly, despite such a high content of chloride and sodium, the paper coated with the coating according to the invention on the one hand is durable and on the other hand provides good print quality. Moreover, it is suitable for direct, mechanical application to paper with standard machines. In laboratory tests of papers with inkjet coatings, the following parameters were measured: print homogeneity (mottling), print show through, bleeding, optical density. Paper with the coating according to the invention was prepared on the size press of a papermaking machine. The evaluation of the coatings consisted of evaluating the printing of the paper using:
a) przemysłowych atramentów INK JET (OCE) i głowicy piezoelektrycznej drukarki biurowej (Epson Stylus),a) industrial INK JET inks (OCE) and piezoelectric head of an office printer (Epson Stylus),
b) drukarki przemysłowej Kodak Versmark,b) Kodak Versmark industrial printer,
c) drukarki przemysłowej OCE.c) OCE industrial printer.
Wyniki badań przedstawiono na rysunku w formie wykresów, gdzie wykres fig. 1 przedstawia jednorodność zadruku czarnego na drukarce KODAK, wykres fig. 2 - jednorodność zadruku turkusowego na drukarce KODAK, wykres fig. 3 - gęstość optyczną koloru czarnego na drukarce KODAK, wykres fig. 4 - gęstość optyczną koloru turkusowego na drukarce KODAK, wykres fig. 5 - przebijanie druku przez papier po wydrukowaniu drukarką KODAK, wykres fig. 6 - gęstość optyczną zadruku czarnego na drukarce Epson Stylus, wykres fig. 7 - jednorodność zadruku czarnego na drukarce Epson Stylus, wykres fig. 8 - ostrość zadruku na drukarce Epson Stylus, a wykres fig. 9 - przebijanie koloru czarnego i żółtego przez papier po wydrukowaniu na drukarce Epson Stylus. Oznaczenia na wykresach oznaczają: F 83 - papier z powłoką według wynalazku, APP standardowy papier, Mondi referencyjny papier do druku strumieniowego, CL3 - inny testowany produkt. Wszystkie wykresy i analiza została dokonana z wykorzystaniem oprogramowania IA VERITY.The test results are presented in the form of graphs in the drawing, where the graph of Fig. 1 shows the uniformity of black printing on a KODAK printer, the graph of Fig. 2 - uniformity of cyan printing on a KODAK printer, graph Fig. 3 - optical density of black on a KODAK printer, graph of Fig. 4 - turquoise optical density on a KODAK printer, diagram fig. 5 - print piercing through the paper after printing with a KODAK printer, diagram fig. 6 - optical density of black print on an Epson Stylus printer, diagram fig. 7 - uniformity of black print on an Epson Stylus printer Figure 8 shows the sharpness of the print on an Epson Stylus printer, and graph Figure 9 shows black and yellow show through the paper after printing on an Epson Stylus printer. The symbols in the graphs mean: F 83 - coated paper according to the invention, APP standard paper, Mondi reference inkjet paper, CL3 - other tested product. All graphs and analysis were done using the IA VERITY software.
Wyniki potwierdzają jakość druku porównywalną z referencyjnym papierem do druku strumieniowego. Nie stwierdzono też przyspieszonej degradacji papieru.The results confirm a print quality comparable to that of the reference inkjet paper. There was also no accelerated degradation of the paper.
PL 228 357 Β1PL 228 357 Β1
Wynalazek ilustruje następujący przykład wykonania.The invention is illustrated by the following embodiment.
Przykład.Example.
Do miksera z mieszadłem szybkoobrotowym wlewa się wodę w ilości zależnej od żądanego stężenia mieszanki powlekającej a następnie dodaje się kolejno składniki we wskazanych ilościach:Water is poured into the mixer with a high-speed stirrer in an amount depending on the desired concentration of the coating mixture, and then the ingredients are added in the indicated amounts:
Kolejne składniki dodaje się po dokładnym rozpuszczeniu poprzedniego w mieszaninie.The next ingredients are added after the previous one is thoroughly dissolved in the mixture.
Wstęga papieru będzie powlekana mieszanką na maszynie papierniczej lub maszynie powlekającej jedno- lub dwustronnie. Gramatura uzyskanego papieru: 70-160 g/m2, gramatura powłoki: 2-4 g/m2.The paper web will be coated with the mixture on a paper machine or a coater on one or both sides. The basis weight of the paper obtained: 70-160 g / m 2, coating weight: 2-4 g / m 2.
Claims (2)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL405943A PL228357B1 (en) | 2013-11-06 | 2013-11-06 | Paper layer for stream printing |
| EP14460082.2A EP2871283B1 (en) | 2013-11-06 | 2014-11-05 | Ink-jet paper coating |
| PL14460082T PL2871283T3 (en) | 2013-11-06 | 2014-11-05 | Ink-jet paper coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL405943A PL228357B1 (en) | 2013-11-06 | 2013-11-06 | Paper layer for stream printing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL405943A1 PL405943A1 (en) | 2015-05-11 |
| PL228357B1 true PL228357B1 (en) | 2018-03-30 |
Family
ID=52021149
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL405943A PL228357B1 (en) | 2013-11-06 | 2013-11-06 | Paper layer for stream printing |
| PL14460082T PL2871283T3 (en) | 2013-11-06 | 2014-11-05 | Ink-jet paper coating |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL14460082T PL2871283T3 (en) | 2013-11-06 | 2014-11-05 | Ink-jet paper coating |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP2871283B1 (en) |
| PL (2) | PL228357B1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL435843A1 (en) * | 2020-11-01 | 2022-05-02 | Arctic Paper Kostrzyn Spółka Akcyjna | Biocidal coating of paper |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4554181A (en) | 1984-05-07 | 1985-11-19 | The Mead Corporation | Ink jet recording sheet having a bicomponent cationic recording surface |
| JP2001315433A (en) | 2000-05-12 | 2001-11-13 | Sekisui Chem Co Ltd | Composition for aqueous ink receiving layer and method for producing recording material for aqueous inkjet printer |
| US8012551B2 (en) * | 2008-05-29 | 2011-09-06 | International Paper Company | Fast dry coated inkjet paper |
| RU2541014C2 (en) * | 2010-07-23 | 2015-02-10 | Интернэшнл Пэйпа Кампани | Bases for printing with coating providing improved printing quality and resolution capability at reduced consumption of ink |
-
2013
- 2013-11-06 PL PL405943A patent/PL228357B1/en unknown
-
2014
- 2014-11-05 EP EP14460082.2A patent/EP2871283B1/en active Active
- 2014-11-05 PL PL14460082T patent/PL2871283T3/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL2871283T3 (en) | 2018-09-28 |
| PL405943A1 (en) | 2015-05-11 |
| EP2871283A1 (en) | 2015-05-13 |
| EP2871283B1 (en) | 2018-03-07 |
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