PL2847529T3 - Sposób i przyrząd do rozdzielania przez destylację kriogeniczną mieszaniny metanu, tlenku węgla i wodoru - Google Patents

Sposób i przyrząd do rozdzielania przez destylację kriogeniczną mieszaniny metanu, tlenku węgla i wodoru

Info

Publication number
PL2847529T3
PL2847529T3 PL13721624T PL13721624T PL2847529T3 PL 2847529 T3 PL2847529 T3 PL 2847529T3 PL 13721624 T PL13721624 T PL 13721624T PL 13721624 T PL13721624 T PL 13721624T PL 2847529 T3 PL2847529 T3 PL 2847529T3
Authority
PL
Poland
Prior art keywords
methane
hydrogen
separation
mixture
carbon monoxide
Prior art date
Application number
PL13721624T
Other languages
English (en)
Inventor
Alain Briglia
Emmanuelle BROCHERIOU
Pascal Marty
Bhadri PRASAD
Original Assignee
L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude filed Critical L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Publication of PL2847529T3 publication Critical patent/PL2847529T3/pl

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0261Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of carbon monoxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0223H2/CO mixtures, i.e. synthesis gas; Water gas or shifted synthesis gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0233Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0252Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of hydrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J5/00Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants
    • F25J5/002Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger
    • F25J5/005Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger in a reboiler-condenser, e.g. within a column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/70Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/76Refluxing the column with condensed overhead gas being cycled in a quasi-closed loop refrigeration cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/90Details relating to column internals, e.g. structured packing, gas or liquid distribution
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/30Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2235/00Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams
    • F25J2235/60Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams the fluid being (a mixture of) hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2250/00Details related to the use of reboiler-condensers
    • F25J2250/02Bath type boiler-condenser using thermo-siphon effect, e.g. with natural or forced circulation or pool boiling, i.e. core-in-kettle heat exchanger
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/24Quasi-closed internal or closed external carbon monoxide refrigeration cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2280/00Control of the process or apparatus
    • F25J2280/02Control in general, load changes, different modes ("runs"), measurements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/62Details of storing a fluid in a tank

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
PL13721624T 2012-05-07 2013-04-29 Sposób i przyrząd do rozdzielania przez destylację kriogeniczną mieszaniny metanu, tlenku węgla i wodoru PL2847529T3 (pl)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP20120305503 EP2662652A1 (en) 2012-05-07 2012-05-07 Process and apparatus for the separation by cryogenic distillation of a mixture of methane, carbon dioxide and hydrogen
PCT/EP2013/058850 WO2013167406A2 (en) 2012-05-07 2013-04-29 Process and apparatus for the separation by cryogenic distillation of a mixture of methane, carbon dioxide and hydrogen
EP13721624.8A EP2847529B1 (en) 2012-05-07 2013-04-29 Process and apparatus for the separation by cryogenic distillation of a mixture of methane, carbon monoxide and hydrogen

Publications (1)

Publication Number Publication Date
PL2847529T3 true PL2847529T3 (pl) 2022-03-14

Family

ID=48407452

Family Applications (1)

Application Number Title Priority Date Filing Date
PL13721624T PL2847529T3 (pl) 2012-05-07 2013-04-29 Sposób i przyrząd do rozdzielania przez destylację kriogeniczną mieszaniny metanu, tlenku węgla i wodoru

Country Status (5)

Country Link
US (1) US10337791B2 (pl)
EP (2) EP2662652A1 (pl)
CN (1) CN104755865B (pl)
PL (1) PL2847529T3 (pl)
WO (1) WO2013167406A2 (pl)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10281203B2 (en) * 2016-08-05 2019-05-07 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for liquefaction of industrial gas by integration of methanol plant and air separation unit
US10288346B2 (en) * 2016-08-05 2019-05-14 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for liquefaction of industrial gas by integration of methanol plant and air separation unit
FR3058996B1 (fr) * 2016-11-18 2022-01-07 Air Liquide Procede et installation de separation cryogenique d’un melange gazeux par lavage au methane
US20210172678A1 (en) * 2019-12-09 2021-06-10 Andrew M. Warta Method for generating refrigeration for a carbon monoxide cold box
US20240417639A1 (en) * 2023-06-19 2024-12-19 Air Products And Chemicals, Inc. Apparatus and Process for Removal of Heavy Hydrocarbons from a Feed Gas

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2795536A (en) * 1955-03-29 1957-06-11 California Research Corp Liquid control for a fractionating column
US4102659A (en) * 1976-06-04 1978-07-25 Union Carbide Corporation Separation of H2, CO, and CH4 synthesis gas with methane wash
FR2636250B1 (fr) 1988-09-12 1992-01-17 Air Liquide Procede et installation de recuperation d'hydrogene et de monoxyde de carbone
US5260865A (en) * 1991-04-01 1993-11-09 Beauford Martin H Nonlinear model based distillation control
US6348637B1 (en) * 2000-09-26 2002-02-19 Uop Llc Multifunction fractionation column for adsorptive separation processes
ES2364242T3 (es) * 2003-05-19 2011-08-29 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Procedimientos e instalación para proporcionar monóxido de carbono gaseoso y/o una mezcla que contiene monóxido de carbono.
FR2860286A1 (fr) * 2004-01-12 2005-04-01 Air Liquide Procede de separation d'air par distillation cryogenique
US7617701B2 (en) * 2004-04-07 2009-11-17 L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Process and installation for providing a fluid mixture containing at least 10% carbon monoxide
FR2881063B1 (fr) * 2005-01-25 2007-04-20 Air Liquide Procede et installation de production de monoxyde de carbone par distillation cryogenique
DE102007013325A1 (de) * 2007-03-20 2008-09-25 Linde Ag Verfahren und Vorrichtung zur Gewinnung von Gasprodukten und flüssigem Methan aus Synthesegas
FR2916523B1 (fr) * 2007-05-21 2014-12-12 Air Liquide Capacite de stockage, appareil et procede de production de monoxyde de carbone et/ou d'hydrogene par separation cryogenique integrant une telle capacite.
EP2331898B1 (fr) * 2008-08-04 2017-12-27 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Procédé de génération et de séparation d'un mélange d'hydrogène et de monoxyde de carbone par distillation cryogénique
CN102374754B (zh) * 2011-09-24 2015-08-19 辽宁哈深冷气体液化设备有限公司 从焦炉煤气中制取液态天然气及一氧化碳的设备及方法

Also Published As

Publication number Publication date
CN104755865A (zh) 2015-07-01
WO2013167406A2 (en) 2013-11-14
EP2662652A1 (en) 2013-11-13
EP2847529A2 (en) 2015-03-18
US20150114035A1 (en) 2015-04-30
CN104755865B (zh) 2017-02-22
WO2013167406A3 (en) 2015-09-17
EP2847529B1 (en) 2021-10-13
US10337791B2 (en) 2019-07-02

Similar Documents

Publication Publication Date Title
EP2664373A4 (en) COMPOSITION FOR CARBON DIOXIDE SEPARATION MEMBRANE FORMATION, CARBON DIOXIDE SEPARATION MEMBRANE, PROCESS FOR MANUFACTURING THE SAME, AND CARBON DIOXIDE SEPARATION DEVICE
WO2013131778A3 (en) Apparatus for production of high purity carbon monoxide
PL2667277T3 (pl) Sposób i urządzenia do dostarczania mieszaniny gazu
PL2667276T3 (pl) Sposób i urządzenie do dostarczania mieszaniny gazu
PL2935098T3 (pl) Równoległe wytwarzanie wodoru, tlenku węgla i produktu zawierającego węgiel
IL233210A (en) A process and system for converting carbon dioxide to carbon monoxide
LT2847127T (lt) Nenutrūkstamas procesas, skirtas biogeniškai aktyvintos anglies gamybai
PL2729404T3 (pl) Sposób równoległego wytwarzania wodoru, tlenku węgla i zawierających węgiel produktów
IL232007A0 (en) Removal by cleaning of hydrogen and carbon monoxide from gas streams
SG11201408692VA (en) Reactor system for the production of carbon allotropes
PL2331898T3 (pl) Sposób wytwarzania i rozdzielania mieszaniny wodoru i monotlenku węgla drogą destylacji kriogenicznej
GB2511265B (en) Process for the conversion of carbon dioxide to methanol
GB2499338B (en) Process for improving the hydrogen content of a synthesis gas
WO2013111015A8 (en) Hydrogen generation
EP2705896A4 (en) METHANE TRENNMEMBRAN AND KOHLENDIOXID-SEPARATE MEMBRANE AND METHOD OF PREPARING THEREFOR
GB2490476B (en) Process and apparatus for the separation of carbon dioxide and hydrogen
PL2877587T3 (pl) Sposób wytwarzania metanu i stosowne urządzenie
PL2736840T3 (pl) Sposób wytwarzania mieszanin gazów bogatych w wodór
EP2665678A4 (en) Process and apparatus for production of ammonia synthesis gas and pure methane by cryogenic separation
PL2856050T3 (pl) Urządzenie i sposób kriogenicznego rozdzielania mieszaniny tlenku węgla i metanu oraz wodoru i opcjonalnie azotu
PL2847529T3 (pl) Sposób i przyrząd do rozdzielania przez destylację kriogeniczną mieszaniny metanu, tlenku węgla i wodoru
SG11201501712SA (en) Separating carbon dioxide from natural gas liquids
ZA201305390B (en) Catalyst recovery system, hydrocarbon synthesis reaction apparatus,hydrocarbon synthesis reaction system,and catalyst receovery process
PL2715260T3 (pl) Urządzenie i zintegrowany sposób rozdzielania mieszaniny dwutlenku węgla i co najmniej jednego innego gazu oraz rozdzielania powietrza przez destylację kriogeniczną
AP4062A (en) Hydrocarbon synthesis reaction apparatus, start-up process thereof, and hydrocarbon synthesis reaction system