PL3166986T3 - Kompozycja zmniejszająca ilość aldehydów emitowanych z pianek poliuretanowych - Google Patents

Kompozycja zmniejszająca ilość aldehydów emitowanych z pianek poliuretanowych

Info

Publication number
PL3166986T3
PL3166986T3 PL15736820.0T PL15736820T PL3166986T3 PL 3166986 T3 PL3166986 T3 PL 3166986T3 PL 15736820 T PL15736820 T PL 15736820T PL 3166986 T3 PL3166986 T3 PL 3166986T3
Authority
PL
Poland
Prior art keywords
composition
reduce
amount
polyurethane foams
aldehydes emitted
Prior art date
Application number
PL15736820.0T
Other languages
English (en)
Inventor
Geert Lodewijk Dries
Eugene P. Wiltz Jr.
Robert Allison Grigsby Jr.
Original Assignee
Huntsman Petrochemical Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Petrochemical Llc filed Critical Huntsman Petrochemical Llc
Publication of PL3166986T3 publication Critical patent/PL3166986T3/pl

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/325—Polyamines containing secondary or tertiary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1833—Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271—Hydroxyamines
    • C08G18/3275—Hydroxyamines containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271—Hydroxyamines
    • C08G18/3293—Hydroxyamines containing heterocyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3842—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
    • C08G18/3848—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3878—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus
    • C08G18/3882—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus having phosphorus bound to oxygen only
    • C08G18/3887—Phosphite compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/105—Esters; Ether-esters of monocarboxylic acids with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
PL15736820.0T 2014-07-10 2015-07-09 Kompozycja zmniejszająca ilość aldehydów emitowanych z pianek poliuretanowych PL3166986T3 (pl)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462022928P 2014-07-10 2014-07-10
EP14178274 2014-07-24
PCT/EP2015/065657 WO2016005479A1 (en) 2014-07-10 2015-07-09 A composition to reduce the amount of aldehydes emitted from polyurethane foams

Publications (1)

Publication Number Publication Date
PL3166986T3 true PL3166986T3 (pl) 2023-07-31

Family

ID=51220465

Family Applications (1)

Application Number Title Priority Date Filing Date
PL15736820.0T PL3166986T3 (pl) 2014-07-10 2015-07-09 Kompozycja zmniejszająca ilość aldehydów emitowanych z pianek poliuretanowych

Country Status (11)

Country Link
US (1) US10472456B2 (pl)
EP (1) EP3166986B1 (pl)
JP (1) JP6722168B2 (pl)
KR (1) KR102390574B1 (pl)
CN (2) CN117106151A (pl)
BR (1) BR112016030534B1 (pl)
CA (1) CA2954558C (pl)
MX (1) MX389249B (pl)
PL (1) PL3166986T3 (pl)
RU (1) RU2712184C2 (pl)
WO (1) WO2016005479A1 (pl)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2703421A1 (en) * 2012-08-28 2014-03-05 Huntsman Petrochemical LLC A composition for making foams with reduced aldehyde emission
BR112018015556B1 (pt) * 2016-02-05 2022-05-31 Huntsman International Llc Método para reduzir a emissão de formaldeído, acetaldeído e propionaldeído de uma espuma de poliuretano ou poliureia
EP3293218A1 (de) * 2016-09-13 2018-03-14 Covestro Deutschland AG Verfahren zur erniedrigung der aldehydemissionen von polyurethanschaumstoffen
US20200031983A1 (en) * 2017-02-09 2020-01-30 Dow Global Technologies Llc Polyurethanes having low levels of aldehyde emissions
WO2018234348A1 (en) 2017-06-21 2018-12-27 Huntsman International Llc Formulation for reduction of formaldehyde emission in pu foam
EP3728368B1 (en) 2017-12-18 2025-10-22 Huntsman International LLC Method for reduction of aldehyde emission in polyurethane comprising materials
PT110585B (pt) * 2018-02-22 2021-04-22 Hovione Farmaciencia Sa Processo de produção contínua de partículas compreendendo secagem por atomização com preparação contínua da solução de atomização
FR3081469B1 (fr) * 2018-05-28 2021-09-03 Groupe Fp Bois Utilisation de derives cycliques d'uree pour diminuer la teneur en composes organiques volatils dans l'air ambiant
US11453742B2 (en) * 2018-08-02 2022-09-27 Dow Global Technologies Llc Methods for reducing aldehyde emissions in polyurethane foams
US11603428B2 (en) * 2018-08-02 2023-03-14 Dow Global Technologies Llc Methods for reducing aldehyde emissions in polyurethane foams
GB2579405B (en) 2018-11-30 2022-09-14 Si Group Switzerland Chaa Gmbh Antioxidant compositions
EP4118128A4 (en) * 2020-03-12 2023-11-29 Dow Global Technologies LLC METHOD FOR REDUCING ALDEHYDE EMISSIONS IN POLYETHER POLYOLS AND POLYURETHANE FOAM
JP7757954B2 (ja) * 2020-03-16 2025-10-22 東ソー株式会社 軟質ポリウレタンフォーム形成用二液型組成物、並びに、軟質ポリウレタンフォーム及びその製造方法
JP2022022758A (ja) * 2020-07-06 2022-02-07 東ソー株式会社 ポリウレタンフォーム製造用のアミン触媒組成物及びその用途
EP4267642A1 (de) * 2020-12-23 2023-11-01 Basf Se Neuer katalysator zur herstellung von polyurethanen
CN118434796A (zh) 2021-08-31 2024-08-02 迈图高新材料公司 用于聚氨酯泡沫的组合物、由其制备的泡沫及其方法
AU2023251714A1 (en) * 2022-04-14 2024-10-24 Huntsman Petrochemical Llc Mixture for inhibiting the emission of aldehydes from polyurethane foam for an extended period of time.

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US5143954A (en) * 1990-11-27 1992-09-01 Rohm And Haas Company Low-formaldehyde, self-crosslinking polymer latex composition
BR9611992A (pt) * 1995-12-11 1999-03-02 Ici Plc Processo para produzir uma unidade de isolamento térmico e a respectiva unidade
JP3703262B2 (ja) 1997-08-19 2005-10-05 三井化学株式会社 ポリオキシアルキレンポリオール、軟質ポリウレタンフォーム及び非発泡ポリウレタンの製造方法
JPH11197501A (ja) * 1998-01-07 1999-07-27 Nippon Synthetic Chem Ind Co Ltd:The アルデヒド吸着剤及びその用途、その使用方法
DE10003157B4 (de) 2000-01-26 2006-10-26 Basf Ag Verfahren zur Herstellung von funktionalisierten Polyurethanschaumstoffen
US6818675B2 (en) * 2002-08-06 2004-11-16 General Electric Company Process for preparing polyurethane foam
JP3959092B2 (ja) * 2004-12-27 2007-08-15 住化バイエルウレタン株式会社 ポリウレタン成形品およびその製造方法
WO2006111492A2 (en) * 2005-04-19 2006-10-26 Ciba Specialty Chemicals Holding Inc. Polyether polyols, polyester polyols and polyurethanes of low residual aldehyde content
JP4971677B2 (ja) 2006-05-01 2012-07-11 協同油脂株式会社 グリース組成物
PL2106415T3 (pl) * 2007-01-19 2016-10-31 Trzeciorzędowe aminy zablokowane kwasami polimerowymi
CN101622292A (zh) * 2007-02-27 2010-01-06 东曹株式会社 软质聚氨酯泡沫制造用的催化剂组合物
EP2257592A4 (en) 2008-03-20 2013-06-05 Huntsman Petrochemical Llc REDUCTION OF ALDEHYDE IN AMINES
BR112012016114B8 (pt) * 2010-01-08 2020-11-24 Huntsman Petrochemical Llc método para formar uma amina tratada com inibidor
US10066047B2 (en) * 2012-02-02 2018-09-04 Covestro Llc Polyurethane foams with decreased aldehyde emissions, a process for preparing these foams and a method for decreasing aldehyde in polyurethane foams
EP2703421A1 (en) 2012-08-28 2014-03-05 Huntsman Petrochemical LLC A composition for making foams with reduced aldehyde emission

Also Published As

Publication number Publication date
MX389249B (es) 2025-03-20
US10472456B2 (en) 2019-11-12
KR102390574B1 (ko) 2022-04-26
BR112016030534A8 (pt) 2021-05-04
MX2017000340A (es) 2017-04-27
RU2017104242A3 (pl) 2019-01-23
BR112016030534A2 (pt) 2017-08-22
CA2954558A1 (en) 2016-01-14
RU2712184C2 (ru) 2020-01-24
JP6722168B2 (ja) 2020-07-15
RU2017104242A (ru) 2018-08-15
US20170129988A1 (en) 2017-05-11
EP3166986B1 (en) 2023-04-19
CN107075062A (zh) 2017-08-18
KR20170032346A (ko) 2017-03-22
CA2954558C (en) 2023-09-26
JP2017521527A (ja) 2017-08-03
BR112016030534B1 (pt) 2021-08-17
CN117106151A (zh) 2023-11-24
WO2016005479A1 (en) 2016-01-14
EP3166986A1 (en) 2017-05-17

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