PL3751646T3 - Materiał aktywny katody dla baterii akumulatorowej, sposób jego wytwarzania i zawierająca go litowa bateria akumulatorowa - Google Patents
Materiał aktywny katody dla baterii akumulatorowej, sposób jego wytwarzania i zawierająca go litowa bateria akumulatorowaInfo
- Publication number
- PL3751646T3 PL3751646T3 PL19804127.9T PL19804127T PL3751646T3 PL 3751646 T3 PL3751646 T3 PL 3751646T3 PL 19804127 T PL19804127 T PL 19804127T PL 3751646 T3 PL3751646 T3 PL 3751646T3
- Authority
- PL
- Poland
- Prior art keywords
- secondary battery
- manufacturing
- active material
- same
- cathode active
- Prior art date
Links
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title 1
- 239000006182 cathode active material Substances 0.000 title 1
- 229910052744 lithium Inorganic materials 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Complex oxides containing nickel and at least one other metal element
- C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
- C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Complex oxides containing nickel and at least one other metal element
- C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
- C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
- C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
- C01G53/82—Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/60—Compounds characterised by their crystallite size
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/32—Thermal properties
- C01P2006/37—Stability against thermal decomposition
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020180056751A KR20190131842A (ko) | 2018-05-17 | 2018-05-17 | 이차전지용 양극 활물질, 그 제조방법 및 이를 포함하는 리튬 이차전지 |
| PCT/KR2019/005807 WO2019221497A1 (ko) | 2018-05-17 | 2019-05-15 | 이차전지용 양극 활물질, 그 제조방법 및 이를 포함하는 리튬 이차전지 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL3751646T3 true PL3751646T3 (pl) | 2024-07-15 |
Family
ID=68540521
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL19804127.9T PL3751646T3 (pl) | 2018-05-17 | 2019-05-15 | Materiał aktywny katody dla baterii akumulatorowej, sposób jego wytwarzania i zawierająca go litowa bateria akumulatorowa |
| PL24155268.6T PL4339164T3 (pl) | 2018-05-17 | 2019-05-15 | Materiał aktywny katody dla baterii akumulatorowej, sposób jego otrzymywania i litowa bateria akumulatorowa zawierająca ten materiał aktywny |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL24155268.6T PL4339164T3 (pl) | 2018-05-17 | 2019-05-15 | Materiał aktywny katody dla baterii akumulatorowej, sposób jego otrzymywania i litowa bateria akumulatorowa zawierająca ten materiał aktywny |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US12308415B2 (pl) |
| EP (2) | EP3751646B1 (pl) |
| JP (1) | JP7139008B2 (pl) |
| KR (2) | KR20190131842A (pl) |
| CN (2) | CN111819718B (pl) |
| ES (2) | ES2980221T3 (pl) |
| HU (1) | HUE066540T2 (pl) |
| PL (2) | PL3751646T3 (pl) |
| WO (1) | WO2019221497A1 (pl) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020260102A1 (en) * | 2019-06-28 | 2020-12-30 | Basf Se | Lithium nickel oxide particulate material, method for its manufacture and use |
| WO2021107684A1 (ko) * | 2019-11-28 | 2021-06-03 | 주식회사 엘지화학 | 리튬 이차전지용 양극 활물질의 제조 방법 및 상기 방법에 의해 제조된 리튬 이차전지용 양극 활물질 |
| KR102406391B1 (ko) * | 2019-12-20 | 2022-06-07 | 주식회사 포스코 | 이차 전지 양극재 제조 방법 |
| CN113224271B (zh) * | 2020-01-21 | 2022-04-22 | 宁德新能源科技有限公司 | 正极材料和包含所述正极材料的电化学装置及电子装置 |
| EP4099444B1 (en) * | 2020-01-31 | 2025-06-25 | SANYO Electric Co., Ltd. | Positive electrode active material for nonaqueous electrolyte secondary batteries, and nonaqueous electrolyte secondary battery |
| JP7365565B2 (ja) * | 2020-03-18 | 2023-10-20 | トヨタ自動車株式会社 | 正極活物質および該正極活物質を備える二次電池 |
| CN114068912B (zh) * | 2020-08-10 | 2023-09-05 | 巴斯夫杉杉电池材料有限公司 | 一种二元高镍单晶正极材料及其制备方法 |
| CN115529825B (zh) * | 2020-09-24 | 2024-03-08 | 株式会社Lg化学 | 单粒子形式的富镍锂复合过渡金属氧化物正极活性材料、其固相合成方法、包含其的正极和锂二次电池 |
| WO2022119314A1 (ko) * | 2020-12-01 | 2022-06-09 | 주식회사 엘지화학 | 양극 활물질 전구체, 이의 제조방법 및 이를 이용한 양극 활물질의 제조방법 |
| KR102649190B1 (ko) * | 2020-12-21 | 2024-03-18 | 포스코홀딩스 주식회사 | 리튬 이차 전지용 양극 활물질, 이의 제조방법 및 이를 포함하는 리튬 이차 전지 |
| KR20220092435A (ko) * | 2020-12-24 | 2022-07-01 | 주식회사 엘지에너지솔루션 | 리튬 이차 전지용 양극 및 이를 포함하는 리튬 이차 전지 |
| WO2022196039A1 (ja) * | 2021-03-18 | 2022-09-22 | パナソニックIpマネジメント株式会社 | 非水電解質二次電池 |
| KR20220133512A (ko) * | 2021-03-25 | 2022-10-05 | 에스케이온 주식회사 | 리튬 이차 전지용 양극 활물질 및 이를 포함하는 리튬 이차 전지 |
| CN117941095A (zh) * | 2021-09-10 | 2024-04-26 | 株式会社Lg新能源 | 正极活性材料、包含其的正极和锂二次电池 |
| WO2023038472A1 (ko) * | 2021-09-10 | 2023-03-16 | 주식회사 엘지에너지솔루션 | 리튬 이차 전지용 양극 활물질 분말, 이의 제조 방법, 리튬 이차 전지용 양극, 및 리튬 이차 전지 |
| KR20230038123A (ko) * | 2021-09-10 | 2023-03-17 | 주식회사 엘지에너지솔루션 | 양극 활물질, 그 제조 방법, 이를 포함하는 양극 및 리튬 이차 전지 |
| US20240243278A1 (en) * | 2021-11-19 | 2024-07-18 | Lg Energy Solution, Ltd. | Composition for cathode active material layer, and lithium secondary battery |
| CA3207888A1 (en) * | 2021-11-24 | 2023-06-01 | Min Kyu You | Method of preparing positive electrode active material for lithium secondary battery, positive electrode active material for lithium secondary battery, and positive electrode for lithium secondary battery and lithium secondary battery which include the same |
| US20240379937A1 (en) * | 2021-12-08 | 2024-11-14 | Lg Energy Solution, Ltd. | Lithium secondary battery |
| EP4318641A4 (en) * | 2021-12-09 | 2025-05-21 | LG Energy Solution, Ltd. | LITHIUM SECONDARY BATTERY |
| US20230207799A1 (en) * | 2021-12-24 | 2023-06-29 | Lg Energy Solution, Ltd. | Positive Electrode Active Material, and Positive Electrode and Lithium Secondary Battery Including the Same |
| KR20230107145A (ko) | 2022-01-07 | 2023-07-14 | 주식회사 엘지에너지솔루션 | 양극재 분말, 이를 포함하는 양극 및 리튬 이차 전지 |
| US20250266443A1 (en) * | 2022-04-20 | 2025-08-21 | Lg Energy Solution, Ltd. | Positive Electrode and Secondary Battery Including the Positive Electrode |
| KR20240002815A (ko) * | 2022-06-30 | 2024-01-08 | 주식회사 엘지화학 | 양극 활물질, 이의 제조방법, 및 이를 포함하는 양극 및 리튬 이차전지 |
| WO2024004709A1 (ja) * | 2022-06-30 | 2024-01-04 | パナソニックIpマネジメント株式会社 | 非水電解質二次電池用正極活物質及び非水電解質二次電池 |
| US20240021781A1 (en) * | 2022-07-15 | 2024-01-18 | Ford Global Technologies, Llc | Intermixing pre-sintered precursors |
| KR20240035001A (ko) * | 2022-09-08 | 2024-03-15 | 주식회사 엘지화학 | 양극 활물질, 이를 포함하는 양극 및 리튬이차전지 |
| EP4604212A4 (en) * | 2022-12-02 | 2025-10-15 | Lg Energy Solution Ltd | Cathode active material, method for producing the same, cathode therewith and lithium secondary battery |
| KR102724217B1 (ko) | 2022-12-16 | 2024-10-31 | 주식회사 엘지에너지솔루션 | 리튬 이차전지, 전지 팩 및 이를 포함하는 전자 기기 |
| CN116130591A (zh) * | 2022-12-16 | 2023-05-16 | 格林美(无锡)能源材料有限公司 | 一种单晶正极材料及其制备方法和锂离子电池 |
| WO2024144188A1 (ko) * | 2022-12-27 | 2024-07-04 | 주식회사 엘지에너지솔루션 | 리튬 이차 전지 |
| CN115821388A (zh) * | 2022-12-29 | 2023-03-21 | 江苏耀宁新能源创新科技有限公司 | 一种单晶正极活性材料及其制备方法与应用 |
| KR20240148287A (ko) * | 2023-04-03 | 2024-10-11 | 주식회사 엘지화학 | 양극 활물질, 및 이를 포함하는 양극 및 리튬 이차전지 |
| JP7756677B2 (ja) * | 2023-04-11 | 2025-10-20 | プライムプラネットエナジー&ソリューションズ株式会社 | 正極用ニッケルコバルトマンガン系活物質の選別方法及び製造方法 |
| CN120883393A (zh) * | 2023-06-02 | 2025-10-31 | 株式会社Lg化学 | 正极活性材料、以及包含其的正极和锂二次电池 |
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| KR20250000697A (ko) * | 2023-06-27 | 2025-01-03 | (주)포스코퓨처엠 | 리튬 이차 전지용 양극 활물질 및 이를 포함하는 리튬 이차 전지 |
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| US20210135187A1 (en) | 2021-05-06 |
| US12308415B2 (en) | 2025-05-20 |
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| JP2021516424A (ja) | 2021-07-01 |
| WO2019221497A1 (ko) | 2019-11-21 |
| CN111819718A (zh) | 2020-10-23 |
| HUE066540T2 (hu) | 2024-08-28 |
| EP3751646B1 (en) | 2024-04-24 |
| EP4339164A3 (en) | 2024-06-12 |
| KR20190131842A (ko) | 2019-11-27 |
| EP3751646A4 (en) | 2021-04-21 |
| CN118099413A (zh) | 2024-05-28 |
| ES2980221T3 (es) | 2024-09-30 |
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