PL3898557T3 - Sposób wytwarzania butadienu z etanolu ze zoptymalizowaną regeneracją in situ katalizatora drugiego etapu reakcji - Google Patents

Sposób wytwarzania butadienu z etanolu ze zoptymalizowaną regeneracją in situ katalizatora drugiego etapu reakcji

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Publication number
PL3898557T3
PL3898557T3 PL19817723.0T PL19817723T PL3898557T3 PL 3898557 T3 PL3898557 T3 PL 3898557T3 PL 19817723 T PL19817723 T PL 19817723T PL 3898557 T3 PL3898557 T3 PL 3898557T3
Authority
PL
Poland
Prior art keywords
optimised
ethanol
catalyst
reaction step
situ regeneration
Prior art date
Application number
PL19817723.0T
Other languages
English (en)
Inventor
Kirill DROBYSHEV
Rejane Dastillung
Jean-Christophe GABELLE
Matthieu Rolland
Original Assignee
IFP Energies Nouvelles
Compagnie Generale Des Etablissements Michelin
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles, Compagnie Generale Des Etablissements Michelin filed Critical IFP Energies Nouvelles
Publication of PL3898557T3 publication Critical patent/PL3898557T3/pl

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
    • C07C1/2072—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by condensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/14—Production of inert gas mixtures; Use of inert gases in general
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2445—Stationary reactors without moving elements inside placed in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/14—Treating with free oxygen-containing gas with control of oxygen content in oxidation gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/002—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by dehydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/22—Moving bed, e.g. vertically or horizontally moving bulk
    • B01J38/24—Moving bed, e.g. vertically or horizontally moving bulk having mainly transverse, i.e. lateral, flow of oxygen-containing gas and material
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
PL19817723.0T 2018-12-21 2019-12-13 Sposób wytwarzania butadienu z etanolu ze zoptymalizowaną regeneracją in situ katalizatora drugiego etapu reakcji PL3898557T3 (pl)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1873771A FR3090632B1 (fr) 2018-12-21 2018-12-21 Procédé de production de butadiène à partir d’éthanol avec régénération in situ optimisée du catalyseur de la deuxième étape réactionnelle
PCT/EP2019/085113 WO2020126920A1 (fr) 2018-12-21 2019-12-13 Procédé de production de butadiène à partir d'éthanol avec régénération in situ optimisée du catalyseur de la deuxième étape réactionnelle

Publications (1)

Publication Number Publication Date
PL3898557T3 true PL3898557T3 (pl) 2023-07-03

Family

ID=67441191

Family Applications (1)

Application Number Title Priority Date Filing Date
PL19817723.0T PL3898557T3 (pl) 2018-12-21 2019-12-13 Sposób wytwarzania butadienu z etanolu ze zoptymalizowaną regeneracją in situ katalizatora drugiego etapu reakcji

Country Status (5)

Country Link
US (1) US11731918B2 (pl)
EP (1) EP3898557B1 (pl)
FR (1) FR3090632B1 (pl)
PL (1) PL3898557T3 (pl)
WO (1) WO2020126920A1 (pl)

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* Cited by examiner, † Cited by third party
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WO2020183359A1 (en) * 2019-03-13 2020-09-17 Sabic Global Technologies B.V. Programmable logic controller for dehydrogenation process with reduced houdry lumps
US12319878B2 (en) 2020-08-06 2025-06-03 Chevron U.S.A. Inc. Upgrading of low value lipid feedstocks for refinery processing
FR3114590B1 (fr) * 2020-09-25 2022-09-09 Ifp Energies Now Procédé de deshydrogenation de l’éthanol en reacteur multitubulaire
KR20240004425A (ko) * 2021-04-01 2024-01-11 신도스 두리 7 스폴카 츠 오그라니크초나 오드포비드치알노스치아 에탄올과 아세트알데히드의 혼합물로부터 1,3-부타디엔을 제조하기 위한 단열적으로 수행되는 방법
BR112023019552A2 (pt) * 2021-04-01 2023-10-31 Synthos Dwory 7 Spolka Z Ograniczona Odpowiedzialnoscia S K A Processo adiabaticamente conduzido para a produção de 1,3-butadieno a partir de misturas de etanol e acetaldeído com regeneração de catalisador
KR20250046299A (ko) 2022-08-02 2025-04-02 신도스 에스.에이. 높은 유리한 중량 공간 시속을 갖는 알루미늄 함유 담체를 포함하는 1,3-부타디엔 생산용 촉매
US20250276305A1 (en) 2022-08-02 2025-09-04 Synthos S.A. Catalyst for the production of 1,3-butadiene giving a high yield based on a support comprising aluminium and sodium
TW202547600A (zh) * 2024-02-07 2025-12-16 波蘭商西索斯公司 於１，３－丁二烯的生產具有高選擇性之包括鉭、鋁及鈉的負載型氧化物觸媒
TW202600244A (zh) * 2024-02-07 2026-01-01 波蘭商西索斯公司 於１，３－丁二烯的生產具有高產率之包括鉭的負載型氧化物觸媒
US12319881B1 (en) 2024-09-27 2025-06-03 Chevron U.S.A. Inc. Converting a renewable fuel intermediate composition to finished transportation fuel
US12582954B1 (en) 2024-12-13 2026-03-24 Chevron U.S.A. Inc. Processing feedstocks
US12590258B1 (en) 2025-02-28 2026-03-31 Chevron U.S.A. Inc. Converting a lipid feedstock to fuel

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2357365A (en) 1940-12-14 1944-09-05 Kellogg M W Co Catalytic method
US2915570A (en) 1955-10-17 1959-12-01 Houdry Process Corp Regeneration of butadiene catalyst
DE1291734B (de) 1960-07-12 1969-04-03 El Paso Natural Gas Prod Verfahren zur katalytischen Dehydrierung von gasfoermigen Kohlenwasserstoffen
FR3026101B1 (fr) 2014-09-19 2017-05-26 Ifp Energies Now Procede de production de butadiene a partir d'ethanol en une etape reactionnelle a faible consommation en eau et en energie
FR3026100B1 (fr) 2014-09-19 2016-12-09 Ifp Energies Now Procede de production de butadiene et d'hydrogene a partir d'ethanol en deux etapes reactionnelles a faible consommation en eau et en energie
FR3038851B1 (fr) 2015-07-13 2019-11-08 IFP Energies Nouvelles Catalyseur a base de tantale depose sur silice pour la transformation de l'ethanol en butadiene
EP3380587A4 (en) * 2015-11-23 2019-06-12 Inaeris Technologies, LLC METHOD OF PROCESSING LIGHT CARBOHOCKS AND OXYGENATES ARISING FROM THE BIOMASS CATALYTIC PYROLYSIS

Also Published As

Publication number Publication date
US20220048833A1 (en) 2022-02-17
US11731918B2 (en) 2023-08-22
WO2020126920A1 (fr) 2020-06-25
EP3898557A1 (fr) 2021-10-27
FR3090632B1 (fr) 2020-12-25
BR112021011120A2 (pt) 2021-08-31
FR3090632A1 (fr) 2020-06-26
EP3898557B1 (fr) 2023-02-08

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