PL402385A1 - New monofunctional poly(diallyldimethylammonium herbicidal ionic liquids), process for their preparation and use as herbicides - Google Patents
New monofunctional poly(diallyldimethylammonium herbicidal ionic liquids), process for their preparation and use as herbicidesInfo
- Publication number
- PL402385A1 PL402385A1 PL402385A PL40238513A PL402385A1 PL 402385 A1 PL402385 A1 PL 402385A1 PL 402385 A PL402385 A PL 402385A PL 40238513 A PL40238513 A PL 40238513A PL 402385 A1 PL402385 A1 PL 402385A1
- Authority
- PL
- Poland
- Prior art keywords
- diallyldimethylammonium
- ionic liquids
- herbicides
- preparation
- poly
- Prior art date
Links
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 title abstract 5
- 230000002363 herbicidal effect Effects 0.000 title abstract 5
- 239000002608 ionic liquid Substances 0.000 title abstract 4
- 239000004009 herbicide Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 150000001450 anions Chemical class 0.000 abstract 2
- SMYMJHWAQXWPDB-UHFFFAOYSA-M (2,4,5-trichlorophenoxy)acetate Chemical compound [O-]C(=O)COC1=CC(Cl)=C(Cl)C=C1Cl SMYMJHWAQXWPDB-UHFFFAOYSA-M 0.000 abstract 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-M (2,4-dichlorophenoxy)acetate Chemical compound [O-]C(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-M 0.000 abstract 1
- WNTGYJSOUMFZEP-UHFFFAOYSA-N 2-(4-chloro-2-methylphenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1C WNTGYJSOUMFZEP-UHFFFAOYSA-N 0.000 abstract 1
- YIVXMZJTEQBPQO-UHFFFAOYSA-M 4-(2,4-dichlorophenoxy)butanoate Chemical compound [O-]C(=O)CCCOC1=CC=C(Cl)C=C1Cl YIVXMZJTEQBPQO-UHFFFAOYSA-M 0.000 abstract 1
- LLWADFLAOKUBDR-UHFFFAOYSA-M 4-(4-chloro-2-methylphenoxy)butanoate Chemical compound CC1=CC(Cl)=CC=C1OCCCC([O-])=O LLWADFLAOKUBDR-UHFFFAOYSA-M 0.000 abstract 1
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Przedmiotem wynalazku są nowe jednofunkcyjne poli(diallilodimetyloamoniowe herbicydowe ciecze jonowe) sposób ich otrzymywania oraz zastosowanie jako herbicydów do ochrony roślin. Nowe jednofunkcyjne poli(diallilodimetyloamoniowe herbicydowe ciecze jonowe) są związkami o wzorze ogólnym 1, gdzie A- oznacza anion herbicydowy a sposób ich otrzymywania polega na tym, że poli(diallilodimetyloamoniowy wodorotlenek) rozpuszcza się w metanolu, a następnie poddaje się reakcji zobojętniania w stosunku molowym 1:1 roztworem o stężeniu co najmniej 1%, kwasu zawierającego anion: (4-chloro-2-metylofenoksy)octanowy, lub (2,4-dichlorofenoksy)octanowy, lub (4-chloro-2-metylo-fenoksy)-propionianowy, lub 4-(2,4- dichlorofenoksy)butanianowy, lub (2,4,5-trichlorofenoksy)octanowy, lub 4-(4-chloro-2-metylofenoksy)-butanianowy. Wynalazek obejmuje również zastosowanie poli(diallilodimetyloamoniowych herbicydowych cieczy jonowych), w postaci czystej, lub w postaci roztworów wodnych, lub alkoholowych, lub wodno-alkoholowych o stężeniu substancji czynnej od 0,1% do 50%, jako herbicydów.The subject of the invention are new monofunctional poly(diallyldimethylammonium herbicidal ionic liquids), a method for their preparation and use as herbicides for plant protection. The new monofunctional poly(diallyldimethylammonium herbicidal ionic liquids) are compounds of the general formula 1 where A- is the herbicidal anion and the method of their preparation is that poly(diallyldimethylammonium hydroxide) is dissolved in methanol and then subjected to a neutralization reaction in a molar ratio 1:1 solution with a concentration of at least 1%, an acid containing the anion: (4-chloro-2-methylphenoxy)acetate, or (2,4-dichlorophenoxy)acetate, or (4-chloro-2-methyl-phenoxy)propionate or 4-(2,4-dichlorophenoxy)butanoate, or (2,4,5-trichlorophenoxy)acetate, or 4-(4-chloro-2-methylphenoxy)butanoate. The invention also includes the use of poly(diallyldimethylammonium herbicidal ionic liquids), in pure form or in the form of aqueous or alcoholic or aqueous-alcoholic solutions with an active ingredient concentration of 0.1% to 50%, as herbicides.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL402385A PL224026B1 (en) | 2013-01-08 | 2013-01-08 | New monofunctional poly(diallyldimethylammonium herbicidal ionic liquids), process for their preparation and use as herbicides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL402385A PL224026B1 (en) | 2013-01-08 | 2013-01-08 | New monofunctional poly(diallyldimethylammonium herbicidal ionic liquids), process for their preparation and use as herbicides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL402385A1 true PL402385A1 (en) | 2014-07-21 |
| PL224026B1 PL224026B1 (en) | 2016-11-30 |
Family
ID=51179255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL402385A PL224026B1 (en) | 2013-01-08 | 2013-01-08 | New monofunctional poly(diallyldimethylammonium herbicidal ionic liquids), process for their preparation and use as herbicides |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL224026B1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL422886A1 (en) * | 2017-09-18 | 2019-03-25 | Politechnika Poznańska | Phenoxy carboxylates with 1-dodecyl-3-carbamoylpyridinium cation, methods for obtaining them and application as herbicides |
| CN114340391A (en) * | 2019-09-03 | 2022-04-12 | 巴斯夫欧洲公司 | Polymers for spray drift control of pesticide sprays |
-
2013
- 2013-01-08 PL PL402385A patent/PL224026B1/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL422886A1 (en) * | 2017-09-18 | 2019-03-25 | Politechnika Poznańska | Phenoxy carboxylates with 1-dodecyl-3-carbamoylpyridinium cation, methods for obtaining them and application as herbicides |
| CN114340391A (en) * | 2019-09-03 | 2022-04-12 | 巴斯夫欧洲公司 | Polymers for spray drift control of pesticide sprays |
Also Published As
| Publication number | Publication date |
|---|---|
| PL224026B1 (en) | 2016-11-30 |
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