PL407231A1 - Photochromic butyl methacrylate copolymers and their obtaining - Google Patents
Photochromic butyl methacrylate copolymers and their obtainingInfo
- Publication number
- PL407231A1 PL407231A1 PL407231A PL40723114A PL407231A1 PL 407231 A1 PL407231 A1 PL 407231A1 PL 407231 A PL407231 A PL 407231A PL 40723114 A PL40723114 A PL 40723114A PL 407231 A1 PL407231 A1 PL 407231A1
- Authority
- PL
- Poland
- Prior art keywords
- butyl methacrylate
- photochromic
- diazenyl
- methylisoxazol
- methylprop
- Prior art date
Links
- SOGAXMICEFXMKE-UHFFFAOYSA-N alpha-Methyl-n-butyl acrylate Natural products CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 title abstract 9
- 229920001577 copolymer Polymers 0.000 title abstract 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 4
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 3
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 239000004005 microsphere Substances 0.000 abstract 2
- 239000002070 nanowire Substances 0.000 abstract 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- 229920001410 Microfiber Polymers 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- -1 microducts Substances 0.000 abstract 1
- 239000003658 microfiber Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000002121 nanofiber Substances 0.000 abstract 1
- 239000002077 nanosphere Substances 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
- 229940124530 sulfonamide Drugs 0.000 abstract 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Wynalazek ujawnia fotochromowe kopolimery metakrylanu butylu będące fotochromowym kopolimerem azobenzenowym metakrylanu butylu z 2- metyloprop-2-enianem 4-[(E)-(4-hydroksyfenylo)diazenylo]-N -(5-metyloizoksazol-3-ilo)benzeno-sulfonoamidu o wzorze 1, w którym n oznacza liczbę merów od 1 do 50 2-metyloprop-2-enianu 4-[(E)-(4-hydroksyfenylo)diazenylo]-N -(5-metyloizoksazol-3-ilo)benzeno-sulfonoamidu natomiast y oznacza liczbę merów od 1 do 50 metakrylanu butylu. Kopolimery znajdują zastosowanie w optycznym zapisie i przetwarzaniu informacji, a także do wytwarzania mikroobiektów i nanoobiektów takich jak: mikrosfery, nanosfery, mikropręty, nanopręty, mikrodruty, nanodruty, mikrowłókna i nanowłókna. Wynalazek dotyczy również sposobu wytwarzania fotochromowych kopolimerów metakrylanu butylu będących fotochromowym kopolimerem azobenzenowym metakrylanu butylu z 2-metyloprop-2-enianem 4-[(E)-(4-hydroksyfenylo)diazenylo]-N -(5-metyloizoksazol-3-ilo)benzeno-sulfonoamidu o wzorze 1. Sposób charakteryzuje się tym, że metakrylan butylu w stosunku molowym 1:1 rozpuszcza się w mieszaninie tetrahydrofuranu, ?-butyrolaktonu i N,N-dimetyloformamidu o zawartości 58% objętościowych tetrahydrofuranu i 17% objętościowych N,N-dimetyloformamidu i poddaje się polimeryzacji rodnikowej w obecności inicjatora w postaci nadtlenku dibenzoilu, przy czym reakcję prowadzi się w atmosferze gazu inertnego, w temperaturze od 70 do 100°C.The invention discloses photochromic butyl methacrylate copolymers which are a photochromic butyl methacrylate copolymer with 4 - [(E) - (4-hydroxyphenyl) diazenyl] -N - (5-methylisoxazol-3-yl) benzene sulfonamide 2-methylprop-2-enoate. Formula 1, in which n is the number of units from 1 to 50 4 - [(E) - (4-hydroxyphenyl) diazenyl] -N - (5-methylisoxazol-3-yl) benzenesulfonamide 2-methylprop-2-enate 2 - methyl y is the number of units from 1 to 50 butyl methacrylate. The copolymers are used in the optical recording and processing of information, as well as for the production of microobjects and nanoobjects such as microspheres, nanospheres, microspheres, nanowires, microducts, nanowires, microfibers and nanofibers. The invention also relates to a method for producing photochromic butyl methacrylate copolymers which are a photochromic butyl methacrylate copolymer with 4 - [(E) - (4-hydroxyphenyl) diazenyl] -N - (5-methylisoxazol-3-yl) benzene 2-methylprop-2-enoate. -sulfonamide of formula 1. The method is characterized in that butyl methacrylate in a 1: 1 molar ratio is dissolved in a mixture of tetrahydrofuran, β-butrolactone and N, N-dimethylformamide with 58% by volume tetrahydrofuran and 17% by volume N, N-dimethylformamide and subjected to radical polymerization in the presence of an initiator in the form of dibenzoyl peroxide, the reaction being carried out in an inert gas atmosphere at a temperature of 70 to 100 ° C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL407231A PL407231A1 (en) | 2014-02-18 | 2014-02-18 | Photochromic butyl methacrylate copolymers and their obtaining |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL407231A PL407231A1 (en) | 2014-02-18 | 2014-02-18 | Photochromic butyl methacrylate copolymers and their obtaining |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL407231A1 true PL407231A1 (en) | 2014-09-01 |
Family
ID=51417830
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL407231A PL407231A1 (en) | 2014-02-18 | 2014-02-18 | Photochromic butyl methacrylate copolymers and their obtaining |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL407231A1 (en) |
-
2014
- 2014-02-18 PL PL407231A patent/PL407231A1/en unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CY1124638T1 (en) | CYCLIC DINUCLEOTIDE COMPOUNDS | |
| CY1121937T1 (en) | HETEROARYL INHIBITORS OF SIK | |
| CU24411B1 (en) | COMPOSITE DERIVED FROM BENZAMIDE REPLACED WITH 1,3-TIAZOL-2-ILO USEFUL FOR THE TREATMENT OF NEUROGENIC DISORDERS | |
| MX372962B (en) | NEW BICYCLIC COMPOUNDS AS DUAL AUTOTAXIN (ATX)/CARBONIC ANHYDRASE (CA) INHIBITORS. | |
| FR3036398B1 (en) | COMPOSITIONS BASED ON 1,1,3,3-TETRACHLOROPROPENE | |
| EA201691071A1 (en) | PHENILTRIAZOLOPIRIDINE COMPOUNDS | |
| MX378847B (en) | NEW GAMMA-AMANITINE DERIVATIVES | |
| EP3623396A4 (en) | COMPOSITION OF BLOCK COPOLYMER OBTAINED BY MODIFICATION TREATMENT, PROCESS FOR THE PRODUCTION OF THE LATTER, COMPOSITION OF MODIFIED BLOCK COPOLYMER USED FOR THE LATTER, AND PROCESS FOR THE PRODUCTION OF SUCH COMPOSITION OF MODIFIED BLOCK COPOLYMER | |
| MX381844B (en) | Ultrapurified DSBA and DSBC and methods of preparing and using them | |
| CU20200038A7 (en) | COMPOUNDS DERIVED FROM PYRAZOLO-PIRROLO-PYRIMIDINE-DIONA AS INHIBITORS OF P2X3 | |
| CL2017000774A1 (en) | Method for producing potassium sulfate granules and the potassium granulate derived therefrom, as well as the use thereof. | |
| EA201591881A1 (en) | Heterocyclic Compound | |
| AR103317A1 (en) | MELATONINE RECEPTORS DIHYDROBENZOFURAN CYCLOPROPIL MODULATORS | |
| EP3571180C0 (en) | PRODUCTION OF HIGH PURITY META,META-COUPLED BIS(4-ALKYLPHENOL) DERIVATIVES AND USES THEREOF | |
| EA201691632A1 (en) | PIRASINS AS GPR6 MODULATORS | |
| MX2020013849A (en) | Novel sulfonylaminobenzamide compounds as anthelmintics. | |
| PL407231A1 (en) | Photochromic butyl methacrylate copolymers and their obtaining | |
| EP3980386C0 (en) | PRODUCTION OF GLASS BODIES FROM POLYMERIZABLE SOLUTIONS | |
| MA45137A (en) | METHOD OF MANUFACTURING A RUBBER PELLET, RUBBER PELLET AS WELL AS A PRODUCT MADE FROM THIS RUBBER PELLET | |
| PL407230A1 (en) | Photochromic butyl methacrylate copolymers and their preparation | |
| KR20180084460A (en) | NOVEL COMPOUND having VINYLPHENYLOXY moiety AND PHOTOSENSITIVE PHOTORESIST COMPOSITION INCLUDING THE SAME | |
| PL407234A1 (en) | Azobenzene photochromic methacrylic homopolymers and their preparation | |
| MX2020012065A (en) | Cyclopentane compounds. | |
| PL407232A1 (en) | Azobenzene photochromic methacrylate homopolymers and their obtaining | |
| MX380217B (en) | CXCR3 RECEPTOR AGONISTS. |