PL410375A1 - (alkoxymethyl)[3-(methcryloylamino)propyl]dimethylammonium chlorides and method for obtaining them - Google Patents
(alkoxymethyl)[3-(methcryloylamino)propyl]dimethylammonium chlorides and method for obtaining themInfo
- Publication number
- PL410375A1 PL410375A1 PL410375A PL41037514A PL410375A1 PL 410375 A1 PL410375 A1 PL 410375A1 PL 410375 A PL410375 A PL 410375A PL 41037514 A PL41037514 A PL 41037514A PL 410375 A1 PL410375 A1 PL 410375A1
- Authority
- PL
- Poland
- Prior art keywords
- solvent
- alkoxymethyl
- propyl
- polar solvent
- preparation
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- -1 dimethylammonium chlorides Chemical class 0.000 title abstract 2
- 125000004849 alkoxymethyl group Chemical group 0.000 title 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 title 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 abstract 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000012454 non-polar solvent Substances 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000005956 quaternization reaction Methods 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Przedmiotem wynalazku są chlorki alkoksymetylo[3(metakryloiloamino)propylo]-dimetyloamoniowe o wzorze ogólnym 1, w którym R oznacza podstawnik alkilowy o długości łańcucha węglowego od jednego do dwudziestu dwóch atomów węgla i sposób ich otrzymywania, mające zastosowanie jako środek antyelektrostatyczny. Sposób ich otrzymywania polega na tym, że 3-(dimetyloamino)metakryloamid, poddaje się reakcji czwartorzędowania czynnikiem czwartorzędującym, którym jest eter chlorometylowoalkilowy, w stosunku molowym aminy do eteru od 0,8:1 do 1:1,2, korzystnie 1:1, w temperaturze co najmniej 20°C, w czasie co najmniej 2 godzin, w środowisku bezwodnym, gdzie rozpuszczalnikiem jest aceton, lub acetonitryl, lub niepolarny rozpuszczalnik z grupy: prosty lub rozgałęziony alkan o długości łańcucha od pięciu do czternastu atomów węgla, lub benzen, lub toluen, lub ich mieszanina, a następnie produkt oddziela się od rozpuszczalnika i kilkakrotnie przemywa niepolarnym rozpuszczalnikiem, po czym niepolarny rozpuszczalnik usuwa się.The present invention relates to alkoxymethyl [3- (methacryloylamino) propyl] dimethylammonium chlorides of the general formula 1 in which R is an alkyl substituent with a carbon chain length of one to twenty-two carbon atoms and a method for their preparation which is applicable as an anti-electrostatic agent. The method of their preparation is that 3- (dimethylamino) methacrylamide is subjected to a quaternization reaction with a quaternizing agent, which is chloromethylalkyl ether, in a molar ratio of amine to ether of 0.8: 1 to 1: 1.2, preferably 1: 1 , at a temperature of at least 20 ° C, for at least 2 hours, in an anhydrous environment where the solvent is acetone or acetonitrile, or a non-polar solvent from the group: a straight or branched alkane with a chain length of five to fourteen carbon atoms, or benzene or toluene, or a mixture thereof, and then the product is separated from the solvent and washed several times with a non-polar solvent, after which the non-polar solvent is removed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL410375A PL229158B1 (en) | 2014-12-04 | 2014-12-04 | (alkoxymethyl)[3-(methcryloylamino)propyl]dimethylammonium chlorides and method for obtaining them |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL410375A PL229158B1 (en) | 2014-12-04 | 2014-12-04 | (alkoxymethyl)[3-(methcryloylamino)propyl]dimethylammonium chlorides and method for obtaining them |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL410375A1 true PL410375A1 (en) | 2016-06-06 |
| PL229158B1 PL229158B1 (en) | 2018-06-29 |
Family
ID=56086961
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL410375A PL229158B1 (en) | 2014-12-04 | 2014-12-04 | (alkoxymethyl)[3-(methcryloylamino)propyl]dimethylammonium chlorides and method for obtaining them |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL229158B1 (en) |
-
2014
- 2014-12-04 PL PL410375A patent/PL229158B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL229158B1 (en) | 2018-06-29 |
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