PL414596A1 - Monodisperse fluorescent polymer microspheres and method to synthesize them - Google Patents
Monodisperse fluorescent polymer microspheres and method to synthesize themInfo
- Publication number
- PL414596A1 PL414596A1 PL414596A PL41459615A PL414596A1 PL 414596 A1 PL414596 A1 PL 414596A1 PL 414596 A PL414596 A PL 414596A PL 41459615 A PL41459615 A PL 41459615A PL 414596 A1 PL414596 A1 PL 414596A1
- Authority
- PL
- Poland
- Prior art keywords
- polymer matrix
- fluorescent
- acrylonitrile
- styrene
- weight
- Prior art date
Links
- 239000004005 microsphere Substances 0.000 title abstract 4
- 229920001109 fluorescent polymer Polymers 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 6
- 239000011159 matrix material Substances 0.000 abstract 5
- 229920000642 polymer Polymers 0.000 abstract 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 3
- 239000007850 fluorescent dye Substances 0.000 abstract 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 229910052786 argon Inorganic materials 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 239000002798 polar solvent Substances 0.000 abstract 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Przedmiotem zgłoszenia są monodyspersyjne fluorescencyjne mikrosfery polimerowe, zawierające matrycę polimerową oraz znacznik fluorescencyjny, cechujące się tym, że matrycę polimerową stanowi kopolimer zbudowany z co najmniej dwóch różnych monomerów, korzystnie kopolimer poli(styren-co-akrylonitryl), zwłaszcza zawierający 10 - 90% wagowych akrylonitrylu i 10 - 90% wagowych styrenu, korzystnie 50 - 85% wagowych akrylonitrylu i 15 - 50% wagowych styrenu, zaś w matrycy polimerowej znajduje się znacznik fluorescencyjny, który korzystnie jest trwale, chemicznie wbudowany w matrycę polimerową i równomiernie w niej rozproszony. Rozmiar mikrosfer według wynalazku zawiera się w przedziale 0,1 - 20 µm, korzystnie w przedziale 1 - 3 µm, a ich temperatura topnienia jest wyższa niż 130°C, korzystnie wynosi powyżej 145°C. Zgłoszenie obejmuje także sposób syntezy monodyspersyjnych fluorescencyjnych mikrosfer polimerowych, polegający na tym, że prowadzi się kopolimeryzację monomerów wchodzących w skład wyżej określonej matrycy polimerowej wspólnie ze związkiem organicznym wykazującym fluorescencję, wykorzystywanym jako znacznik fluorescencyjny, korzystnie metodą kopolimeryzacji dyspersyjnej styrenu, akrylonitrylu oraz odpowiedniego znacznika fluorescencyjnego, w obecności stabilizatora oraz inicjatora reakcji, w rozpuszczalniku polarnym, korzystnie bezwodnym, w atmosferze obojętnej, korzystnie argonu lub azotu.The subject of the application are monodisperse fluorescent polymer microspheres containing a polymer matrix and a fluorescent label, characterized in that the polymer matrix is a copolymer composed of at least two different monomers, preferably a poly (styrene-co-acrylonitrile) copolymer, especially containing 10 - 90% by weight acrylonitrile and 10-90% by weight styrene, preferably 50-85% by weight acrylonitrile and 15-50% by weight styrene, while the polymer matrix has a fluorescent label that is preferably permanently chemically embedded in the polymer matrix and evenly dispersed in it. The size of the microspheres according to the invention is in the range of 0.1-20 Pm, preferably in the range of 1-3 Pm, and their melting point is higher than 130 ° C, preferably above 145 ° C. The application also includes a method for the synthesis of monodisperse fluorescent polymer microspheres, in which the monomers included in the above-defined polymer matrix are copolymerized together with a fluorescent organic compound used as a fluorescent label, preferably by dispersion copolymerization of styrene, acrylonitrile and the appropriate fluorescence label in the presence of a stabilizer and a reaction initiator, in a polar solvent, preferably anhydrous, in an inert atmosphere, preferably argon or nitrogen.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL414596A PL414596A1 (en) | 2015-10-28 | 2015-10-28 | Monodisperse fluorescent polymer microspheres and method to synthesize them |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL414596A PL414596A1 (en) | 2015-10-28 | 2015-10-28 | Monodisperse fluorescent polymer microspheres and method to synthesize them |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL414596A1 true PL414596A1 (en) | 2017-05-08 |
Family
ID=58643729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL414596A PL414596A1 (en) | 2015-10-28 | 2015-10-28 | Monodisperse fluorescent polymer microspheres and method to synthesize them |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL414596A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018182437A1 (en) | 2017-03-27 | 2018-10-04 | Ergis S.A. | A coating material for marking plastics, a method for marking plastics, a method for identification of marked plastics and their application in sorting plastic waste |
-
2015
- 2015-10-28 PL PL414596A patent/PL414596A1/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018182437A1 (en) | 2017-03-27 | 2018-10-04 | Ergis S.A. | A coating material for marking plastics, a method for marking plastics, a method for identification of marked plastics and their application in sorting plastic waste |
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