PL420348A1 - Sposób syntezy eterów 1-propenylowych - Google Patents
Sposób syntezy eterów 1-propenylowychInfo
- Publication number
- PL420348A1 PL420348A1 PL420348A PL42034817A PL420348A1 PL 420348 A1 PL420348 A1 PL 420348A1 PL 420348 A PL420348 A PL 420348A PL 42034817 A PL42034817 A PL 42034817A PL 420348 A1 PL420348 A1 PL 420348A1
- Authority
- PL
- Poland
- Prior art keywords
- ethers
- pph3
- rucl2
- allyl
- synthesis
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- -1 1-propylene ethers Chemical class 0.000 title 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title 1
- ZKJNETINGMOHJG-UHFFFAOYSA-N 1-prop-1-enoxyprop-1-ene Chemical class CC=COC=CC ZKJNETINGMOHJG-UHFFFAOYSA-N 0.000 abstract 2
- DHCWLIOIJZJFJE-UHFFFAOYSA-L dichlororuthenium Chemical compound Cl[Ru]Cl DHCWLIOIJZJFJE-UHFFFAOYSA-L 0.000 abstract 2
- 238000006317 isomerization reaction Methods 0.000 abstract 2
- 150000003303 ruthenium Chemical class 0.000 abstract 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 abstract 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 1
- 101100030361 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) pph-3 gene Proteins 0.000 abstract 1
- 229910052786 argon Inorganic materials 0.000 abstract 1
- 239000012300 argon atmosphere Substances 0.000 abstract 1
- MLIYPCQSOXNTLJ-UHFFFAOYSA-N carbon monoxide;ruthenium dihydride;triphenylphosphane Chemical compound [RuH2].[O+]#[C-].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 MLIYPCQSOXNTLJ-UHFFFAOYSA-N 0.000 abstract 1
- FMJNZRCLIZWWJP-UHFFFAOYSA-N carbon monoxide;ruthenium;triphenylphosphane Chemical compound [Ru].[O+]#[C-].[O+]#[C-].[O+]#[C-].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 FMJNZRCLIZWWJP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 239000012299 nitrogen atmosphere Substances 0.000 abstract 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 abstract 1
- 239000012041 precatalyst Substances 0.000 abstract 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- BPLUKJNHPBNVQL-UHFFFAOYSA-N triphenylarsine Chemical compound C1=CC=CC=C1[As](C=1C=CC=CC=1)C1=CC=CC=C1 BPLUKJNHPBNVQL-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Przedmiotem zgłoszenia jest sposób syntezy eterów 1-propenylowych funkcjonalizowanych grupą sililową lub siloksanową, polegający na bezrozpuszczalnikowej izomeryzacji eterów allilowo-sililowych lub eterów allilowo-siloksanowych katalizowanej przez kompleksy rutenu, prowadzonej pod ciśnieniem autogenicznym, w środowisku beztlenowym z zastosowaniem gazu obojętnego. Przedmiotowy sposób charakteryzuje się tym, że jako prekatalizatory reakcji stosuje się proste kompleksu rutenu takie jak [RuHCl(CO)(AsPh3)3], [RuH2(CO)(PPh3)3], {[RuCl2(p-Cym)]2}, [RuCl2(PPh3)4] lub [Ru(CO)3(PPh3)2]. Reakcję izomeryzacji prowadzi się wysoce selektywnie i wydajnie w kierunku odpowiednich eterów 1-propenylowych, w szerokim zakresie umiarkowanych temperatur 80°C-140°C, w szerokim zakresie stężeń katalizatora 0,01 - 1,00% mol., w czasie 1-24 godzin oraz różnej skali procesu, bez rozpuszczalników, w atmosferze argonu lub azotu, przy użyciu mieszadła magnetycznego.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL420348A PL236163B1 (pl) | 2017-01-31 | 2017-01-31 | Sposób syntezy eterów 1-propenylowych |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL420348A PL236163B1 (pl) | 2017-01-31 | 2017-01-31 | Sposób syntezy eterów 1-propenylowych |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL420348A1 true PL420348A1 (pl) | 2018-08-13 |
| PL236163B1 PL236163B1 (pl) | 2020-12-14 |
Family
ID=63112875
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL420348A PL236163B1 (pl) | 2017-01-31 | 2017-01-31 | Sposób syntezy eterów 1-propenylowych |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL236163B1 (pl) |
-
2017
- 2017-01-31 PL PL420348A patent/PL236163B1/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL236163B1 (pl) | 2020-12-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Mangion et al. | Gold (I) catalysis of X–H bond insertions | |
| Kokko et al. | Effects of wastewater constituents and operational conditions on the composition and dynamics of anodic microbial communities in bioelectrochemical systems | |
| Banerjee et al. | Melanin from the nitrogen-fixing bacterium Azotobacter chroococcum: a spectroscopic characterization | |
| WO2010031076A3 (en) | Conversion of prenyl derivatives to isoprene | |
| Gogoi et al. | Copper–Schiff base complex catalyzed oxidation of sulfides with hydrogen peroxide | |
| MX2014001887A (es) | Catalizador de hidrogenacion y deshidrogenacion, y metodos para hacerlo y usarlo. | |
| MY189593A (en) | Improvements in biological conversion and product recovery processes | |
| Schleker et al. | Catalytic Dehydrogenative Amide and Ester Formation with Rhenium-Triphos Complexes. | |
| IL200968A0 (en) | Process for the preparation of optically active ethenylphenyl alcohols | |
| MY161093A (en) | A process for preparing methanol, dimethyl ether and low carbon olefins from syngas | |
| CO6620029A2 (es) | Proceso para la preparación de etanol y alcoholes superiores | |
| MX2010009196A (es) | Metodo para producir compuestos de carbonilo olefinicamente insaturados mediante la deshidrogenacion oxidante de alcoholes. | |
| CA2510093A1 (en) | Novel process for the preparation of.alpha.-chlorovinyl, .alpha.,.alpha.-dichloro, and acetylenes from ketones | |
| MX2016001241A (es) | Un metodo aerobico para producir alcoholes. | |
| ATE410404T1 (de) | Neue resorcinolderivate für die haut | |
| GB0508314D0 (en) | Organic compounds | |
| PL420348A1 (pl) | Sposób syntezy eterów 1-propenylowych | |
| EP3904367A8 (en) | Tetrapeptide compound, preparation method and use thereof | |
| WO2008093392A1 (ja) | ２，３'－ビピリジル－６'－オンの製造方法 | |
| MY193459A (en) | Catalyst for reduction reaction of 3,4-dihydroxytetrahydrofuran, and method for producing 3,4-dihydroxytetrahydrofuran reduced product | |
| AU2015359691A8 (en) | Fischer-Tropsch process using reductively-activated cobalt catalyst | |
| Huang et al. | Selective photochemical reduction of nitroarenes to N-arylhydroxylamines with γ-terpinene | |
| Zhang et al. | CuI/N4 ligand/TEMPO derivatives: A mild and highly efficient system for aerobic oxidation of primary alcohols | |
| PH12020550544A1 (en) | Synthesis of boronate ester derivatives and uses thereof | |
| MY166433A (en) | Method for producing hydrogenation catalyst |