PL421842A1 - Derivatives of silsesquioxanes with the structure of completely condensed cage and a germanium atom built in the cage edge and the method for obtaining derivatives of silsesquioxanes with the structure of completely condensed cage and a germanium atom built in the cage edge - Google Patents
Derivatives of silsesquioxanes with the structure of completely condensed cage and a germanium atom built in the cage edge and the method for obtaining derivatives of silsesquioxanes with the structure of completely condensed cage and a germanium atom built in the cage edgeInfo
- Publication number
- PL421842A1 PL421842A1 PL421842A PL42184217A PL421842A1 PL 421842 A1 PL421842 A1 PL 421842A1 PL 421842 A PL421842 A PL 421842A PL 42184217 A PL42184217 A PL 42184217A PL 421842 A1 PL421842 A1 PL 421842A1
- Authority
- PL
- Poland
- Prior art keywords
- cage
- silsesquioxanes
- derivatives
- germanium atom
- edge
- Prior art date
Links
- 229910052732 germanium Inorganic materials 0.000 title abstract 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 239000002841 Lewis acid Substances 0.000 abstract 1
- 239000003849 aromatic solvent Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- GKOZKEKDBJADSV-UHFFFAOYSA-N disilanol Chemical compound O[SiH2][SiH3] GKOZKEKDBJADSV-UHFFFAOYSA-N 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 125000005394 methallyl group Chemical group 0.000 abstract 1
- 150000008648 triflates Chemical class 0.000 abstract 1
Landscapes
- Silicon Polymers (AREA)
Abstract
Przedmiotem zgłoszenia są pochodne silseskwioksanów o strukturze całkowicie skondensowanej klatki i wbudowanym atomie germanu w krawędź klatki o ogólnym wzorze 2, w którym: R1, R2 są równe i oznaczają: Me lub Et lub nBu. Przedmiotem zgłoszenia jest też sposób otrzymywania pochodnych silseskwioksanów o wzorze ogólnym 2, polegający na reakcji disilanolu POSS z bis(2-metyloallilo)germananami w obecności kwasu Lewisa z grupy triflatów jako katalizatora, przy czym reakcję prowadzi się w niepolarnym rozpuszczalniku aromatycznym.The subject of the application are derivatives of silsesquioxanes with a fully condensed cage structure and a built-in germanium atom in the cage edge with the general formula 2, in which: R1, R2 are equal and mean: Me or Et or nBu. The subject of the application is also a method for obtaining silsesquioxane derivatives of general formula 2, consisting of the reaction of POSS disilanol with bis (2-methylallyl) germanates in the presence of Lewis acid from the group of triflates as a catalyst, the reaction being carried out in a non-polar aromatic solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL421842A PL234806B1 (en) | 2017-06-08 | 2017-06-08 | Derivatives of silsesquioxanes with the structure of completely condensed cage and a germanium atom built in the cage edge and the method for obtaining derivatives of silsesquioxanes with the structure of completely condensed cage and a germanium atom built in the cage edge |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL421842A PL234806B1 (en) | 2017-06-08 | 2017-06-08 | Derivatives of silsesquioxanes with the structure of completely condensed cage and a germanium atom built in the cage edge and the method for obtaining derivatives of silsesquioxanes with the structure of completely condensed cage and a germanium atom built in the cage edge |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL421842A1 true PL421842A1 (en) | 2017-12-04 |
| PL234806B1 PL234806B1 (en) | 2020-04-30 |
Family
ID=60473204
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL421842A PL234806B1 (en) | 2017-06-08 | 2017-06-08 | Derivatives of silsesquioxanes with the structure of completely condensed cage and a germanium atom built in the cage edge and the method for obtaining derivatives of silsesquioxanes with the structure of completely condensed cage and a germanium atom built in the cage edge |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL234806B1 (en) |
-
2017
- 2017-06-08 PL PL421842A patent/PL234806B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL234806B1 (en) | 2020-04-30 |
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