PL421984A1 - Method for isomerization of limonene - Google Patents
Method for isomerization of limoneneInfo
- Publication number
- PL421984A1 PL421984A1 PL421984A PL42198417A PL421984A1 PL 421984 A1 PL421984 A1 PL 421984A1 PL 421984 A PL421984 A PL 421984A PL 42198417 A PL42198417 A PL 42198417A PL 421984 A1 PL421984 A1 PL 421984A1
- Authority
- PL
- Poland
- Prior art keywords
- limonene
- isomerization
- catalyst
- sba
- rpm
- Prior art date
Links
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 title abstract 6
- 238000006317 isomerization reaction Methods 0.000 title abstract 3
- 229940087305 limonene Drugs 0.000 title abstract 3
- 235000001510 limonene Nutrition 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Przedmiotem zgłoszenia jest sposób izomeryzacji limonenu, który polega na tym, że w obecności katalizatora, pod ciśnieniem atmosferycznym, jako katalizator stosuje się katalizator tytanowo-silikalitowy Ti-SBA-15 w ilości 5 - 15% wagowy w mieszaninie reakcyjnej. Proces izomeryzacji prowadzi się w temperaturze 140 - 160°C, w czasie od 0,5 do 23 godzin, stosując intensywność mieszania 500 obr/min. Do reaktora wprowadza się w pierwszej kolejności limonen, a później katalizator.The subject of the application is a method of isomerization of limonene, which consists in the fact that in the presence of a catalyst at atmospheric pressure, a titanium-silicalite catalyst Ti-SBA-15 in the amount of 5 - 15% by weight in the reaction mixture is used. The isomerization process is carried out at a temperature of 140 - 160 ° C for 0.5 to 23 hours using a stirring intensity of 500 rpm. Limonene is introduced into the reactor first, followed by the catalyst.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL421984A PL233234B1 (en) | 2017-06-22 | 2017-06-22 | Method for isomerization of limonene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL421984A PL233234B1 (en) | 2017-06-22 | 2017-06-22 | Method for isomerization of limonene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL421984A1 true PL421984A1 (en) | 2019-01-02 |
| PL233234B1 PL233234B1 (en) | 2019-09-30 |
Family
ID=64899003
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL421984A PL233234B1 (en) | 2017-06-22 | 2017-06-22 | Method for isomerization of limonene |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL233234B1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4551570A (en) * | 1985-01-14 | 1985-11-05 | Scm Corporation | Process for the isomerization of limonene to terpinolene |
| EP0235804A2 (en) * | 1986-03-07 | 1987-09-09 | BASF Aktiengesellschaft | Improved process for the preparation of P-cymen and homologous alkylbenzenes |
| JPH01319431A (en) * | 1988-06-22 | 1989-12-25 | Yasuhara Yushi Kogyo Kk | Production of terpinolene |
| JPH02115133A (en) * | 1988-10-26 | 1990-04-27 | Yasuhara Yushi Kogyo Kk | Production of terpinolene |
| JPH02292230A (en) * | 1989-05-08 | 1990-12-03 | Yasuhara Chem Kk | Production of terpinolene |
-
2017
- 2017-06-22 PL PL421984A patent/PL233234B1/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4551570A (en) * | 1985-01-14 | 1985-11-05 | Scm Corporation | Process for the isomerization of limonene to terpinolene |
| EP0235804A2 (en) * | 1986-03-07 | 1987-09-09 | BASF Aktiengesellschaft | Improved process for the preparation of P-cymen and homologous alkylbenzenes |
| JPH01319431A (en) * | 1988-06-22 | 1989-12-25 | Yasuhara Yushi Kogyo Kk | Production of terpinolene |
| JPH02115133A (en) * | 1988-10-26 | 1990-04-27 | Yasuhara Yushi Kogyo Kk | Production of terpinolene |
| JPH02292230A (en) * | 1989-05-08 | 1990-12-03 | Yasuhara Chem Kk | Production of terpinolene |
Also Published As
| Publication number | Publication date |
|---|---|
| PL233234B1 (en) | 2019-09-30 |
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