PL422434A1 - New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of terbium (III) and method for producing them, application of complex compounds of terbium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materials - Google Patents

New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of terbium (III) and method for producing them, application of complex compounds of terbium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materials

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Publication number
PL422434A1
PL422434A1 PL422434A PL42243417A PL422434A1 PL 422434 A1 PL422434 A1 PL 422434A1 PL 422434 A PL422434 A PL 422434A PL 42243417 A PL42243417 A PL 42243417A PL 422434 A1 PL422434 A1 PL 422434A1
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Poland
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new
terbium
iii
complex compounds
processes
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PL422434A
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Polish (pl)
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PL243150B1 (en
Inventor
Joanna Ortyl
Anna Chachaj-Brekiesz
Katarzyna Kukuła
Maciej Pilch
Iwona Kamińska-Borek
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Politechnika Krakowska im. Tadeusza Kościuszki
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Priority to PL422434A priority Critical patent/PL243150B1/en
Publication of PL422434A1 publication Critical patent/PL422434A1/en
Publication of PL243150B1 publication Critical patent/PL243150B1/en

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Zgłoszenie dotyczy nowych systemów fotoinicjujących do procesów fotoinicjowanej polimeryzacji kationowej, rodnikowej, tiol-en i hybrydowej, nowych związków kompleksowych terbu(III), sposobu ich wytwarzania, zastosowań związków kompleksowych terbu(III), nowych luminescencyjnych sond molekularnych do monitorowania procesów polimeryzacji oraz nowych luminescencyjnych sensorów molekularnych do badań materiałów powłokowych. Nowe systemy fotoinicjujące do procesów fotoinicjowanej polimeryzacji kationowej, rodnikowej, tiol-en i hybrydowej, zawierające sole oniowe i ko-inicjator, charakteryzują się tym, że zawierają a) co najmniej jedną sól oniową wybraną spośród następujących: sole jodoniowe wybrane spośród heksafluorofosforanu difenylojodoniowego, heksafluoroantymonianu difenylojodoniowego, heksafluorofosforanu 4-metylo-4'-izopropylodifenylojodoniowego, heksafluorofosforanu 4,4'-dimetylodifenylojodoniowego, tetrakis pentafluorofenyloboranu 4-metylo-4'-izopropylodifenylojodoniowego; sole sulfoniowe wybrane spośród heksafluorofosforanu trifenylo-sulfoniowego i heksafluoroantymonianu trifenylosulfoniowego; oraz b) co najmniej jeden ko-inicjator wybrany z grupy związków kompleksowych terbu(III) o wzorze ogólnym (1), w którym: A1 oznacza ugrupowanie o wzorze ogólnym (2), w którym podstawnik R1 oznacza atom wodoru lub atom fluoru; podstawnik R2 oznacza atom wodoru, atom chloru, grupę metylową, grupę trifluorometylową; podstawnik R3 oznacza atom wodoru, atom bromu, grupę metylową; podstawnik R4 oznacza atom wodoru, atom fluoru, grupę metoksylową; A2 oznacza ugrupowanie o wzorze ogólnym (3), w którym podstawnik R5 oznacza grupę butylową lub grupę oktylową; albo A2 oznacza ugrupowanie o wzorze (4), x oznacza 0, 1 lub 2; n oznacza liczbę całkowitą od 0 do 7.The application concerns new photoinitiation systems for photoinitiated cationic, radical, thiol-hybrid and hybridization polymerization, new terbium (III) complex compounds, method of their production, applications of terbium (III) complex compounds, new luminescent molecular probes for monitoring polymerization processes and new luminescence molecular sensors for testing coating materials. New photo-initiating systems for the processes of photoinitiated cationic, radical, thiol-hybrid and hybrid polymerization, containing onium salts and a co-initiator, are characterized by containing a) at least one onium salt selected from the following: iodonium salts selected from diphenyl iodonium hexafluorophosphate, hexafluoroanthonate diphenyl iodonium, 4-methyl-4'-isopropyl diphenyl iodonium hexafluorophosphate, 4,4'-dimethyldiphenyl iodonium hexafluorophosphate, 4-methyl-4'-isopropyl diphenyl diodonium tetrakis pentafluorophenylborate; sulfonium salts selected from triphenyl sulfonium hexafluorophosphate and triphenyl sulfonium hexafluoroantimonate; and b) at least one co-initiator selected from the group of terbium (III) complex compounds of general formula (1), wherein: A1 is a moiety of general formula (2), wherein R1 is hydrogen or fluoro; R2 is a hydrogen atom, a chlorine atom, a methyl group, a trifluoromethyl group; R3 is a hydrogen atom, a bromine atom, a methyl group; R4 is a hydrogen atom, a fluorine atom, a methoxy group; A2 is a moiety of the general formula (3) in which R5 is a butyl group or octyl group; or A2 is a moiety of formula (4), x is 0, 1 or 2; n is an integer from 0 to 7.

PL422434A 2017-08-02 2017-08-02 New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of terbium (III) and method for producing them, application of complex compounds of terbium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materials PL243150B1 (en)

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PL422434A PL243150B1 (en) 2017-08-02 2017-08-02 New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of terbium (III) and method for producing them, application of complex compounds of terbium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materials

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PL422434A PL243150B1 (en) 2017-08-02 2017-08-02 New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of terbium (III) and method for producing them, application of complex compounds of terbium (III), new luminescent molecular probes for monitoring polymerization processes, new luminescent molecular sensors for tests of coating materials

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PL422434A1 true PL422434A1 (en) 2019-02-11
PL243150B1 PL243150B1 (en) 2023-07-10

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL407364A1 (en) * 2014-02-28 2015-08-31 Joanna Ortyl New derivatives of naphthalene, method for producing them and application, new intermediate compounds for producing new derivatives of naphthalene, new photosensitizers for the processes of photoinitiated cationic polymerization and new photoinitiating systems
PL412067A1 (en) * 2015-04-20 2016-10-24 Politechnika Krakowska im. Tadeusza Kościuszki New derivatives of 1-aminonaphthaleno-2-carbonitrile, methods for producing them and application, new photosensitizers for the processes of photoinitiated cationic, radical and hybrid polymerization and new photoinitiating systems for the processes of cationic, radical and hybrid photopolymerization

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL407364A1 (en) * 2014-02-28 2015-08-31 Joanna Ortyl New derivatives of naphthalene, method for producing them and application, new intermediate compounds for producing new derivatives of naphthalene, new photosensitizers for the processes of photoinitiated cationic polymerization and new photoinitiating systems
PL412067A1 (en) * 2015-04-20 2016-10-24 Politechnika Krakowska im. Tadeusza Kościuszki New derivatives of 1-aminonaphthaleno-2-carbonitrile, methods for producing them and application, new photosensitizers for the processes of photoinitiated cationic, radical and hybrid polymerization and new photoinitiating systems for the processes of cationic, radical and hybrid photopolymerization

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
CHOI, SANG HOON SEO, SEOK-JUN ZHAO, DAN PARK, KYOUNG-TAE KIM, ENHANCED LUMINESCENCE CHARACTERISTICS OF MESOPHASE SILICA THIN FILMS DOPED WITH IN-SITU-FORMED RARE EARTH COMPLEXES, 31 January 2016 (2016-01-31) *
S.P. SINHA H.M.N.H. IRVING, THE SYNERGIC EXTRACTION OF THE EUROPIUM III -BIS-PHENANTHROLINE-TRIS-SALICYLATE COMPLEX AND THE PREPARATION AND PROPERTIES OF ANALOGOUS TERNARY RARE EARTH COMPLEXES, November 1970 (1970-11-01) *
SATO, SAKI ISHII, AYUMI YAMADA, CHISAKI KIM, JUNGUEN HO SONG, CHUL, LUMINESCENCE OF FUSION MATERIALS OF POLYMERIC CHAIN-STRUCTURED LANTHANIDE COMPLEXES, 28 February 2015 (2015-02-28) *
YUE BIN SUN HUI-JUAN CHEN YING-NAN KONG KAI CHU HAI-BIN, DNA BINDING AND ANTIBACTERIAL PROPERTIES OF TERNARY LANTHANIDE COMPLEXES WITH SALICYLIC ACID AND PHENANTHROLINE, 2014 *

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