PL423032A1 - System with the reference electrode with liquid connection, intended for electroanalytical subsurface and abyssal measurements - Google Patents

System with the reference electrode with liquid connection, intended for electroanalytical subsurface and abyssal measurements

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Publication number
PL423032A1
PL423032A1 PL423032A PL42303217A PL423032A1 PL 423032 A1 PL423032 A1 PL 423032A1 PL 423032 A PL423032 A PL 423032A PL 42303217 A PL42303217 A PL 42303217A PL 423032 A1 PL423032 A1 PL 423032A1
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PL
Poland
Prior art keywords
reference electrode
liquid
expansion vessel
liquid connection
measurements
Prior art date
Application number
PL423032A
Other languages
Polish (pl)
Other versions
PL234798B1 (en
Inventor
Józef Wiora
Alicja Wiora
Original Assignee
Politechnika Śląska
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Politechnika Śląska filed Critical Politechnika Śląska
Priority to PL423032A priority Critical patent/PL234798B1/en
Publication of PL423032A1 publication Critical patent/PL423032A1/en
Publication of PL234798B1 publication Critical patent/PL234798B1/en

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  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Abstract

Układ z elektrodą odniesienia z połączeniem ciekłym do pomiarów elektroanalitycznych, zwłaszcza potencjometrycznych, mający zastosowanie w warunkach głębokiego zanurzenia w badanej próbce, zwłaszcza w warunkach podwodnych, wyposażony w elektrodę odniesienia (1) z połączeniem ciekłym, która składa się z elektrody wewnętrznej (2), korzystnie chlorosrebrowej, zanurzonej w roztworze wewnętrznym (3), korzystnie nasyconym chlorku sodu, i posiada połączenie ciekłe elektrody odniesienia (4), łącznik (5) i naczynie wyrównawcze (6), w którym korzystnie znajduje się ciecz (8) o właściwościach pozwalających na mieszanie się z próbką (10) charakteryzuje się tym, że elektroda odniesienia (1) połączona jest z naczyniem wyrównawczym (6), zawierającym połączenie ciekłe naczynia wyrównawczego (9), za pomocą łącznika (5) w sposób rozłączny lub nierozłączny, przy czym w naczyniu wyrównawczym (6) znajduje się płyn (7), o gęstości mniejszej, niż gęstość roztworu wewnętrznego (3) i cieczy (8), korzystnie powietrze lub olej transformatorowy, a elektroda odniesienia (1) i naczynie wyrównawcze (6) zanurzone są w próbce (10), natomiast połączenie ciekłe elektrody odniesienia (4) znajduje się powyżej połączenia ciekłego naczynia wyrównawczego (9).A system with a reference electrode with a liquid connection for electroanalytical measurements, especially potentiometric measurements, applicable in deep immersion in a tested sample, especially under underwater conditions, equipped with a reference electrode (1) with a liquid connection, which consists of an internal electrode (2), preferably silver-chloride, immersed in an internal solution (3), preferably saturated sodium chloride, and has a liquid connection of the reference electrode (4), a junction (5) and an expansion vessel (6) in which the liquid (8) with properties allowing mixing with the sample (10) is characterized in that the reference electrode (1) is connected to the expansion vessel (6), containing the liquid connection of the expansion vessel (9), by means of a connector (5) in a detachable or inseparable manner, in which the expansion vessel (6) contains fluid (7), with a density less than g the density of the internal solution (3) and liquid (8), preferably air or transformer oil, and the reference electrode (1) and expansion vessel (6) are immersed in the sample (10), while the liquid connection of the reference electrode (4) is above the connection a liquid expansion vessel (9).

PL423032A 2017-10-02 2017-10-02 System with the reference electrode with liquid connection, intended for electroanalytical subsurface and abyssal measurements PL234798B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL423032A PL234798B1 (en) 2017-10-02 2017-10-02 System with the reference electrode with liquid connection, intended for electroanalytical subsurface and abyssal measurements

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL423032A PL234798B1 (en) 2017-10-02 2017-10-02 System with the reference electrode with liquid connection, intended for electroanalytical subsurface and abyssal measurements

Publications (2)

Publication Number Publication Date
PL423032A1 true PL423032A1 (en) 2019-04-08
PL234798B1 PL234798B1 (en) 2020-04-30

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Family Applications (1)

Application Number Title Priority Date Filing Date
PL423032A PL234798B1 (en) 2017-10-02 2017-10-02 System with the reference electrode with liquid connection, intended for electroanalytical subsurface and abyssal measurements

Country Status (1)

Country Link
PL (1) PL234798B1 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL316056A1 (en) * 1995-11-03 1997-05-12 Ciba Corning Diagnostics Corp Reference electrode assembly
EP1338892B1 (en) * 2002-02-22 2005-10-26 Mettler-Toledo GmbH Pressure-resistant reference electrode for electrochemical measurements
US7459066B2 (en) * 1999-06-08 2008-12-02 Broadley Technologies, Corporation Reference electrode having a microfluidic flowing liquid junction
WO2010072509A1 (en) * 2008-12-22 2010-07-01 Endress+Hauser Conducta Gesellschaft Für Mess- Und Regeltechnik Mbh+Co. Kg Reference electrode
CN102967639A (en) * 2012-07-11 2013-03-13 哈尔滨工程大学 Long-life reference electrode suitable for deep-sea high hydrostatic pressure environment

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL316056A1 (en) * 1995-11-03 1997-05-12 Ciba Corning Diagnostics Corp Reference electrode assembly
US7459066B2 (en) * 1999-06-08 2008-12-02 Broadley Technologies, Corporation Reference electrode having a microfluidic flowing liquid junction
EP1192455B1 (en) * 1999-06-08 2014-07-02 Broadley Technologies Corporation Reference electrode having a microfluidic flowing liquid junction
EP1338892B1 (en) * 2002-02-22 2005-10-26 Mettler-Toledo GmbH Pressure-resistant reference electrode for electrochemical measurements
WO2010072509A1 (en) * 2008-12-22 2010-07-01 Endress+Hauser Conducta Gesellschaft Für Mess- Und Regeltechnik Mbh+Co. Kg Reference electrode
CN102967639A (en) * 2012-07-11 2013-03-13 哈尔滨工程大学 Long-life reference electrode suitable for deep-sea high hydrostatic pressure environment

Also Published As

Publication number Publication date
PL234798B1 (en) 2020-04-30

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