PL424902A1 - Two-dimensional crystalline surface-modified titanium carbide Ti<sub>3</sub>C<sub>2</sub> and method for obtaining two-dimensional crystalline surface-modified titanium carbide Ti<sub>3</sub>C<sub>2</sub> - Google Patents
Two-dimensional crystalline surface-modified titanium carbide Ti<sub>3</sub>C<sub>2</sub> and method for obtaining two-dimensional crystalline surface-modified titanium carbide Ti<sub>3</sub>C<sub>2</sub>Info
- Publication number
- PL424902A1 PL424902A1 PL424902A PL42490218A PL424902A1 PL 424902 A1 PL424902 A1 PL 424902A1 PL 424902 A PL424902 A PL 424902A PL 42490218 A PL42490218 A PL 42490218A PL 424902 A1 PL424902 A1 PL 424902A1
- Authority
- PL
- Poland
- Prior art keywords
- sub
- titanium carbide
- modified titanium
- modified
- crystalline surface
- Prior art date
Links
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical class C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 title abstract 8
- 239000010936 titanium Substances 0.000 title 2
- 150000002902 organometallic compounds Chemical class 0.000 abstract 3
- 230000000737 periodic effect Effects 0.000 abstract 3
- 229910009819 Ti3C2 Inorganic materials 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 229910044991 metal oxide Inorganic materials 0.000 abstract 2
- 150000004706 metal oxides Chemical group 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- 239000012300 argon atmosphere Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000012299 nitrogen atmosphere Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000013557 residual solvent Substances 0.000 abstract 1
- 239000013049 sediment Substances 0.000 abstract 1
- 239000010802 sludge Substances 0.000 abstract 1
Landscapes
- Carbon And Carbon Compounds (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
Abstract
Przedmiotem zgłoszenia jest krystaliczny dwuwymiarowy węglik tytanu Ti3C2 modyfikowany powierzchniowo tlenkami metali grupy 13 układu okresowego. Zgłoszenie obejmuje też sposób otrzymywania krystalicznego dwuwymiarowego węglika tytanu Ti3C2 modyfikowanego powierzchniowo tlenkami metali grupy 13 układu okresowego, który polega na tym, że w atmosferze azotu lub argonu do rozpuszczalnika organicznego dodaje się węglik tytanu i związek metaloorganiczny R3M, gdzie R oznacza podstawnik alkilowy i/lub aromatyczny o ilości atomów węgla od 1 do 15 a M oznacza metal grupy 13 układu okresowego, ogrzewa się przez kilka godzin a następnie usuwa się rozpuszczalnik z nieprzereagowanym związkiem metaloorganicznym i zmodyfikowany węglik tytanu w postaci osadu poddaje się działaniu powietrza o wilgotności względnej do 100% lub tlenu. Otrzymany zmodyfikowany węglik tytanu poddaje się obróbce termicznej i następnie węglik tytanu z roztworem związku metaloorganicznego ogrzewa się w temperaturze 20-200°C w ciągu 0,5-24 godzin i po reakcji rozpuszczalnik usuwa się. Z osadu usuwa się resztę rozpuszczalnika w próżni i wystawia się na działanie powietrza lub tlenu a tak otrzymany materiał poddaje się obróbce termicznej w suszarce lub piecu.The subject of the application is a crystalline two-dimensional titanium carbide Ti3C2 surface modified with metal oxides of group 13 of the periodic table. The application also covers a method of obtaining crystalline two-dimensional titanium carbide Ti3C2 surface-modified with metal oxides of group 13 of the periodic table, which consists in adding titanium carbide and an organometallic compound R3M to an organic solvent under nitrogen or argon atmosphere, where R is an alkyl substituent and / or aromatic with a number of carbon atoms from 1 to 15 and M is a metal of Group 13 of the periodic table, heated for several hours and then the solvent with unreacted organometallic compound is removed and the modified titanium carbide sediment is exposed to air with a relative humidity of up to 100%, or oxygen. The obtained modified titanium carbide is heat treated and then the titanium carbide with the organometallic compound solution is heated at 20-200 ° C for 0.5-24 hours and after the reaction the solvent is removed. The residual solvent is removed from the sludge in vacuo and exposed to air or oxygen, and the material thus obtained is heat treated in an oven or oven.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL424902A PL239048B1 (en) | 2018-03-07 | 2018-03-07 | Two-dimensional crystalline surface-modified titanium carbide Ti<sub>3</sub>C<sub>2</sub> and method for obtaining two-dimensional crystalline surface-modified titanium carbide Ti<sub>3</sub>C<sub>2</sub> |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL424902A PL239048B1 (en) | 2018-03-07 | 2018-03-07 | Two-dimensional crystalline surface-modified titanium carbide Ti<sub>3</sub>C<sub>2</sub> and method for obtaining two-dimensional crystalline surface-modified titanium carbide Ti<sub>3</sub>C<sub>2</sub> |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL424902A1 true PL424902A1 (en) | 2019-09-09 |
| PL239048B1 PL239048B1 (en) | 2021-11-02 |
Family
ID=67844614
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL424902A PL239048B1 (en) | 2018-03-07 | 2018-03-07 | Two-dimensional crystalline surface-modified titanium carbide Ti<sub>3</sub>C<sub>2</sub> and method for obtaining two-dimensional crystalline surface-modified titanium carbide Ti<sub>3</sub>C<sub>2</sub> |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL239048B1 (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL411404A1 (en) * | 2015-02-26 | 2016-08-29 | Politechnika Warszawska | Method for obtaining modified graphene flakes and the surface-modified graphene flakes |
-
2018
- 2018-03-07 PL PL424902A patent/PL239048B1/en unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL411404A1 (en) * | 2015-02-26 | 2016-08-29 | Politechnika Warszawska | Method for obtaining modified graphene flakes and the surface-modified graphene flakes |
Non-Patent Citations (2)
| Title |
|---|
| FEN WANG, FACILE SYNTHESIS SNO2 NANOPARTICLE-MODIFIED TI3C2 MXENE NANOCOMPOSITES FOR ENHANCED LITHIUM STORAGE APPLICATION, 2017 * |
| HUANG ZHANG, CU2O HYBRIDIZED TITANIUM CARBIDE WITH OPEN CONDUCTIVE FRAMEWORKS FOR LITHIUM-ION BATTERIES, 2016 * |
Also Published As
| Publication number | Publication date |
|---|---|
| PL239048B1 (en) | 2021-11-02 |
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