PL426896A1 - New 2-amino-4-phenyl-6-methylbenzene-1,3-dicarbonitrile derivatives, methods of their preparation, new photoinitiation systems for photoinitiated cationic, radical, thiol-ene and hybrid polymerization processes and use of new 2-amino-4-phenyl-6-methylbenzene-1,3-dicarbonitrile derivatives - Google Patents
New 2-amino-4-phenyl-6-methylbenzene-1,3-dicarbonitrile derivatives, methods of their preparation, new photoinitiation systems for photoinitiated cationic, radical, thiol-ene and hybrid polymerization processes and use of new 2-amino-4-phenyl-6-methylbenzene-1,3-dicarbonitrile derivativesInfo
- Publication number
- PL426896A1 PL426896A1 PL426896A PL42689618A PL426896A1 PL 426896 A1 PL426896 A1 PL 426896A1 PL 426896 A PL426896 A PL 426896A PL 42689618 A PL42689618 A PL 42689618A PL 426896 A1 PL426896 A1 PL 426896A1
- Authority
- PL
- Poland
- Prior art keywords
- new
- phenyl
- methylbenzene
- amino
- group
- Prior art date
Links
- WYDZPJKNTNMEFR-UHFFFAOYSA-N 2-amino-4-methyl-6-phenylbenzene-1,3-dicarbonitrile Chemical class NC1=C(C#N)C(C)=CC(C=2C=CC=CC=2)=C1C#N WYDZPJKNTNMEFR-UHFFFAOYSA-N 0.000 title abstract 4
- 125000002091 cationic group Chemical group 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- OXBLVCZKDOZZOJ-UHFFFAOYSA-N 2,3-Dihydrothiophene Chemical compound C1CC=CS1 OXBLVCZKDOZZOJ-UHFFFAOYSA-N 0.000 title 1
- 150000003254 radicals Chemical class 0.000 title 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Przedmiotem zgłoszenia są nowe pochodne 2-amino-4-fenylo-6-metylobenzeno-1,3-dikarbonitrylu o wzorze ogólnym (1), w którym R1 oznacza atom wodoru -H, atom bromu -Br, grupę fenylową -C6H5, grupę metylosulfanylową -SCH3, -podstawioną grupę fenylową z podstawnikiem -CH3, -OCH3, -N(CH3)2, -CN, -SCH3, -SO2CH3, R1 może też oznaczać wybraną grupę określoną wzorami wskazanymi na rysunku (2), R2 oznacza atom wodoru -H, grupę fenylową -C6H5, grupę -CnH2n+1, w której n oznacza liczbę całkowitą od 1 do 12, taką jak grupa -CH3, -C2H5; R3 oznacza atom wodoru -H, grupę fenylową -C6H5, grupę -CnH2n+1, w której n oznacza liczbę całkowitą od 1 do 12, taką jak grupa -CH3,-C2H5, przy czym gdy R1 oznacza atom wodoru -H lub atom bromu -Br, to co najmniej jeden spośród R2 i R3 jest różny od atomu wodoru -H. Zgłoszenie niniejsze dotyczy także sposobów wytwarzania nowych pochodnych 2-amino-4-fenylo-6-metylobenzeno-1,3-dikarbonitrylu o wzorze ogólnym (1) oraz ich zastosowań, a także nowych systemów fotoinicjujących do procesów fotoinicjowanej polimeryzacji kationowej, rodnikowej, tiol-en i hybrydowej.The subject of the application are new 2-amino-4-phenyl-6-methylbenzene-1,3-dicarbonitrile derivatives of the general formula (1), in which R1 is a hydrogen atom -H, a bromine atom -Br, a phenyl group -C6H5, a methylsulfanyl group -SCH3, -substituted phenyl group with a substituent -CH3, -OCH3, -N (CH3) 2, -CN, -SCH3, -SO2CH3, R1 can also be a selected group defined by the formulas shown in figure (2), R2 is a hydrogen atom -H, a phenyl group -C6H5, a group -CnH2n + 1 in which n is an integer from 1 to 12, such as a group -CH3, -C2H5; R3 represents a hydrogen atom -H, a phenyl group -C6H5, a group -CnH2n + 1 where n is an integer from 1 to 12, such as a group -CH3, -C2H5, with the proviso that when R1 is hydrogen -H or bromine -Br, then at least one of R2 and R3 is different from hydrogen -H. The present application also relates to methods for the preparation of new 2-amino-4-phenyl-6-methylbenzene-1,3-dicarbonitrile derivatives of general formula (1) and their applications, as well as new photoinitiating systems for cationic, radical, thiol-photoinitiated polymerization processes. en and hybrid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL426896A PL238210B1 (en) | 2018-09-04 | 2018-09-04 | New 2-amino-4-phenyl-6-methylbenzene-1,3-dicarbonitrile derivatives, methods of their preparation, new photoinitiation systems for photoinitiated cationic, radical, thiol-ene and hybrid polymerization processes and use of new 2-amino-4-phenyl-6-methylbenzene-1,3-dicarbonitrile derivatives |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL426896A PL238210B1 (en) | 2018-09-04 | 2018-09-04 | New 2-amino-4-phenyl-6-methylbenzene-1,3-dicarbonitrile derivatives, methods of their preparation, new photoinitiation systems for photoinitiated cationic, radical, thiol-ene and hybrid polymerization processes and use of new 2-amino-4-phenyl-6-methylbenzene-1,3-dicarbonitrile derivatives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL426896A1 true PL426896A1 (en) | 2020-03-09 |
| PL238210B1 PL238210B1 (en) | 2021-07-26 |
Family
ID=69709526
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL426896A PL238210B1 (en) | 2018-09-04 | 2018-09-04 | New 2-amino-4-phenyl-6-methylbenzene-1,3-dicarbonitrile derivatives, methods of their preparation, new photoinitiation systems for photoinitiated cationic, radical, thiol-ene and hybrid polymerization processes and use of new 2-amino-4-phenyl-6-methylbenzene-1,3-dicarbonitrile derivatives |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL238210B1 (en) |
-
2018
- 2018-09-04 PL PL426896A patent/PL238210B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL238210B1 (en) | 2021-07-26 |
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