PL429454A1 - Sposób otrzymywania jodków organicznych, kompozycja perowskitotwórcza z jodkiem organicznym otrzymanym tym sposobem oraz ogniwo fotowoltaiczne z warstwą perowskitową wytworzoną z tej kompozycji - Google Patents

Sposób otrzymywania jodków organicznych, kompozycja perowskitotwórcza z jodkiem organicznym otrzymanym tym sposobem oraz ogniwo fotowoltaiczne z warstwą perowskitową wytworzoną z tej kompozycji

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PL429454A1
PL429454A1 PL429454A PL42945419A PL429454A1 PL 429454 A1 PL429454 A1 PL 429454A1 PL 429454 A PL429454 A PL 429454A PL 42945419 A PL42945419 A PL 42945419A PL 429454 A1 PL429454 A1 PL 429454A1
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iodide
salt
rxni
rxn
perovskite
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PL429454A
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English (en)
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Kasjan Misztal
Konrad WOJCIECHOWSKI
Olga Malinkiewicz
Zbigniew Miara
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Saule Spółka Z Ograniczoną Odpowiedzialnością
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Priority to PL429454A priority Critical patent/PL429454A1/pl
Priority to EP20177469.2A priority patent/EP3719001B1/en
Priority to PL20177469.2T priority patent/PL3719001T3/pl
Priority to ES20177469T priority patent/ES2966640T3/es
Priority to KR1020217035679A priority patent/KR102815316B1/ko
Priority to CN202080026905.XA priority patent/CN114096511B/zh
Priority to PCT/IB2020/055167 priority patent/WO2020202131A1/en
Priority to JP2021556704A priority patent/JP7634148B2/ja
Priority to US17/601,065 priority patent/US12202783B2/en
Publication of PL429454A1 publication Critical patent/PL429454A1/pl

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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  • Pyridine Compounds (AREA)

Abstract

Przedmiotem zgłoszenia jest sposób otrzymywania soli o wzorze ogólnym: RxNI, gdzie: RxN stanowi kation organiczny (RxN+), R oznacza podstawnik (R-), wybrany z grupy składającej się z podstawników organicznych: R1-, R2-, R3- oraz wodoru (H-), x oznacza liczbę podstawników R- bezpośrednio połączonych z atomem azotu (N) w kationie organicznym RxN+, przy czym x wynosi 3 lub 4, I stanowi anion jodkowy (I?). W sposobie tym sporządza się mieszaninę reakcyjną w taki sposób, że: w środowisku rozpuszczalnika wytwarza się in situ jodowodór (HI) poprzez wymieszanie jodu cząsteczkowego (I2) z kwasem mrówkowym (COOH) w stosunku molowym jod cząsteczkowy (I2): kwas mrówkowy (COOH) nie mniejszym niż 1,01:1, do tego środowiska rozpuszczalnika wprowadza się ponadto związek będący donorem kationu organicznego RxN+, w ilości niezbędnej do zachowania stosunku molowego donor kationu organicznego RxN+: jod cząsteczkowy (I2) nie mniejszego niż 1,01:1, przy czym sporządzoną mieszaninę reakcyjną utrzymuje się w temperaturze nie niżej niż 20°C przez czas niezbędny do wytworzenia produktu reakcji będącego solą o wzorze ogólnym RxNI. Przedmiotem zgłoszenia jest także zastosowanie soli o wzorze ogólnym: RxNI. Otrzymany ww.sposobem, produkt reakcji stanowi substrat do syntezy perowskitów. Ponadto zgłoszenie obejmuje też kompozycje perowskitotwórczą, zawierająca w swym składzie co najmniej jedną sól o wzorze og.: RxNI, wybraną z grupy, składającej się z: jodku metyloamoniowego (MAI), jodku etyloamoniowego, jodku propyloamoniowego, jodku butyloamoniowego, jodku pentyloamoniowego, jodku heksyloamoniowego, jodku heptyloamoniowego, jodku oktyloamoniowego (OAI) oraz jodku formamidyniowego (FAI). Przedmiotem zgłoszenia jest również ogniwo fotowoltaiczne, które zawiera warstwę perowskitową wytworzoną z udziałem soli o wzorze ogólnym: RxNI, która to sól jest otrzymana sposobem według dowolnego z zastrzeżeń od 1 do 15.
PL429454A 2019-04-02 2019-04-02 Sposób otrzymywania jodków organicznych, kompozycja perowskitotwórcza z jodkiem organicznym otrzymanym tym sposobem oraz ogniwo fotowoltaiczne z warstwą perowskitową wytworzoną z tej kompozycji PL429454A1 (pl)

Priority Applications (9)

Application Number Priority Date Filing Date Title
PL429454A PL429454A1 (pl) 2019-04-02 2019-04-02 Sposób otrzymywania jodków organicznych, kompozycja perowskitotwórcza z jodkiem organicznym otrzymanym tym sposobem oraz ogniwo fotowoltaiczne z warstwą perowskitową wytworzoną z tej kompozycji
EP20177469.2A EP3719001B1 (en) 2019-04-02 2020-05-29 A method for synthesis of organic iodides
PL20177469.2T PL3719001T3 (pl) 2019-04-02 2020-05-29 Sposób syntezy jodków organicznych
ES20177469T ES2966640T3 (es) 2019-04-02 2020-05-29 Un método para la síntesis de yoduros orgánicos
KR1020217035679A KR102815316B1 (ko) 2019-04-02 2020-06-01 유기 요오드화물의 합성 방법, 유기 요오드화물을 포함하는 페로브스카이트 형성 조성물, 및 이로부터 수득된 페로브스카이트 층을 갖는 광전지
CN202080026905.XA CN114096511B (zh) 2019-04-02 2020-06-01 有机碘化物的合成方法、包含有机碘化物的钙钛矿形成用组合物和具有由此获得的钙钛矿层的光伏电池
PCT/IB2020/055167 WO2020202131A1 (en) 2019-04-02 2020-06-01 A method for synthesis of organic iodides, a perovskite-forming composition comprising an organic iodide and a photovoltaic cell with a perovskite layer obtained therefrom
JP2021556704A JP7634148B2 (ja) 2019-04-02 2020-06-01 有機ヨウ化物の合成のための方法、有機ヨウ化物を含むペロブスカイト形成組成物、およびそれから得られるペロブスカイト層を有する光電池
US17/601,065 US12202783B2 (en) 2019-04-02 2020-06-01 Method for synthesis of organic iodides, a perovskite-forming composition comprising an organic iodide and a photovoltaic cell with a perovskite layer obtained therefrom

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PL429454A PL429454A1 (pl) 2019-04-02 2019-04-02 Sposób otrzymywania jodków organicznych, kompozycja perowskitotwórcza z jodkiem organicznym otrzymanym tym sposobem oraz ogniwo fotowoltaiczne z warstwą perowskitową wytworzoną z tej kompozycji

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EP4249468B1 (en) 2022-03-21 2025-05-07 Solaveni GmbH A method for synthesis of halide salts
CN115872902A (zh) * 2022-12-09 2023-03-31 湖南铱太科技有限公司 一种甲脒氢碘酸盐的绿色提纯方法
CN118684584A (zh) * 2023-03-22 2024-09-24 宁德时代新能源科技股份有限公司 有机化合物、钙钛矿前驱体溶液、钙钛矿薄膜、钙钛矿电池和用电装置
CN116986992B (zh) * 2023-08-01 2025-07-04 西湖大学 二维锡基钙钛矿的可控制备方法及其在光泵浦中的应用
KR20250116468A (ko) * 2024-01-25 2025-08-01 한화솔루션 주식회사 페로브스카이트 용액 및 이를 이용하는 페로브스카이트 박막 형성 방법

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US20120318357A1 (en) 2011-06-17 2012-12-20 Precursor Energetics, Inc. Deposition processes for photovoltaics
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EP3719001B1 (en) 2023-11-15
EP3719001A3 (en) 2020-10-14
US20220185765A1 (en) 2022-06-16
CN114096511B (zh) 2025-01-14
US12202783B2 (en) 2025-01-21
EP3719001A2 (en) 2020-10-07
KR102815316B1 (ko) 2025-05-29
JP7634148B2 (ja) 2025-02-21
CN114096511A (zh) 2022-02-25
ES2966640T3 (es) 2024-04-23
PL3719001T3 (pl) 2024-03-18
KR20220008813A (ko) 2022-01-21
WO2020202131A1 (en) 2020-10-08
EP3719001C0 (en) 2023-11-15

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