PL429476A1 - Nowe zastosowanie kompleksów metali posiadających ligandy organiczne do aktywacji rutenowych (pre)katalizatorów metatezy olefin - Google Patents

Nowe zastosowanie kompleksów metali posiadających ligandy organiczne do aktywacji rutenowych (pre)katalizatorów metatezy olefin

Info

Publication number
PL429476A1
PL429476A1 PL429476A PL42947619A PL429476A1 PL 429476 A1 PL429476 A1 PL 429476A1 PL 429476 A PL429476 A PL 429476A PL 42947619 A PL42947619 A PL 42947619A PL 429476 A1 PL429476 A1 PL 429476A1
Authority
PL
Poland
Prior art keywords
catalysts
activating
olefin metathesis
metal complexes
new application
Prior art date
Application number
PL429476A
Other languages
English (en)
Inventor
Michał CHWALBA
Konrad KURCBACH
Krzysztof Gręda
Rafał GAWIN
Krzysztof Skowerski
Original Assignee
Apeiron Synthesis Spółka Akcyjna
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Apeiron Synthesis Spółka Akcyjna filed Critical Apeiron Synthesis Spółka Akcyjna
Priority to PL429476A priority Critical patent/PL429476A1/pl
Priority to PCT/EP2020/059181 priority patent/WO2020201314A1/en
Priority to US17/600,832 priority patent/US12338310B2/en
Priority to EP20716456.7A priority patent/EP3947515B1/en
Publication of PL429476A1 publication Critical patent/PL429476A1/pl

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/50—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/13—Morphological aspects
    • C08G2261/135—Cross-linked structures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3325—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from other polycyclic systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/418—Ring opening metathesis polymerisation [ROMP]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/70—Post-treatment
    • C08G2261/76—Post-treatment crosslinking

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Przedmiotem zgłoszenia jest zastosowanie związków wybranych spośród kompleksów miedzi, posiadających przynajmniej jeden ligand organiczny, lub kompleksów rutenu, posiadających przynajmniej jeden ligand organiczny do aktywacji rutenowych (pre)katalizatorów metatezy olefin w reakcji metatezy, w szczególności w reakcji polimeryzacji metatetycznej z otwarciem pierścienia (ROMP).
PL429476A 2019-04-02 2019-04-02 Nowe zastosowanie kompleksów metali posiadających ligandy organiczne do aktywacji rutenowych (pre)katalizatorów metatezy olefin PL429476A1 (pl)

Priority Applications (4)

Application Number Priority Date Filing Date Title
PL429476A PL429476A1 (pl) 2019-04-02 2019-04-02 Nowe zastosowanie kompleksów metali posiadających ligandy organiczne do aktywacji rutenowych (pre)katalizatorów metatezy olefin
PCT/EP2020/059181 WO2020201314A1 (en) 2019-04-02 2020-03-31 New use of metal complexes having organic ligands for activating olefin metathesis ruthenium (pre)catalysts
US17/600,832 US12338310B2 (en) 2019-04-02 2020-03-31 Use of metal complexes having organic ligands for activating olefin metathesis ruthenium (pre)catalysts
EP20716456.7A EP3947515B1 (en) 2019-04-02 2020-03-31 New use of metal complexes having organic ligands for activating olefin metathesis ruthenium (pre)catalysts

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL429476A PL429476A1 (pl) 2019-04-02 2019-04-02 Nowe zastosowanie kompleksów metali posiadających ligandy organiczne do aktywacji rutenowych (pre)katalizatorów metatezy olefin

Publications (1)

Publication Number Publication Date
PL429476A1 true PL429476A1 (pl) 2020-10-05

Family

ID=72666141

Family Applications (1)

Application Number Title Priority Date Filing Date
PL429476A PL429476A1 (pl) 2019-04-02 2019-04-02 Nowe zastosowanie kompleksów metali posiadających ligandy organiczne do aktywacji rutenowych (pre)katalizatorów metatezy olefin

Country Status (4)

Country Link
US (1) US12338310B2 (pl)
EP (1) EP3947515B1 (pl)
PL (1) PL429476A1 (pl)
WO (1) WO2020201314A1 (pl)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2025041082A1 (en) * 2023-08-23 2025-02-27 Inkbit, LLC Materials and methods for transmetallation-activated ring-opening metathesis polymerization (romp)

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6284852B1 (en) 1997-10-30 2001-09-04 California Institute Of Technology Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water
US6107420A (en) 1998-07-31 2000-08-22 California Institute Of Technology Thermally initiated polymerization of olefins using Ruthenium or osmium vinylidene complexes
AU2005228434A1 (en) 2004-03-29 2005-10-13 California Institute Of Technology Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand
PL1757613T3 (pl) 2005-08-22 2011-06-30 Rimtec Corp Wielokoordynacyjne kompleksy metalu do zastosowania w reakcjach metatezy
TW200950884A (en) 2008-06-11 2009-12-16 Henkel Corp (N-heterocyclic carbene) copper salt complex as latent click catalyst
PL216649B1 (pl) * 2011-06-06 2014-04-30 Univ Warszawski Nowe kompleksy rutenu, sposób ich wytwarzania oraz zastosowanie w reakcji metatezy olefin
DE102013201997A1 (de) 2013-02-07 2014-08-07 Robert Bosch Gmbh Verfahren und Vorrichtung zum Betrieb einer Kraftstoffeinspritzeinrichtung insbesondere eines Kraftfahrzeuges
EP2774674A1 (en) 2013-03-06 2014-09-10 Sonja Jost Water-insoluble Ruthenium catalyst composition for use in aqueous hydrogenation reactions
JP6342985B2 (ja) * 2013-03-15 2018-06-13 マテリア, インコーポレイテッド Rompポリマーのインモールドコーティング
RU2674471C2 (ru) 2014-07-03 2018-12-11 Гуан Мин Инновейшн Компани (Ухань) Катализаторы на основе переходного металла 8 группы, способ их получения и способ их применения в реакции метатезиса
WO2016100101A1 (en) 2014-12-15 2016-06-23 Merck Sharp & Dohme Corp. Ruthenium-based metathesis pre-catalyst compounds
WO2016130743A1 (en) * 2015-02-12 2016-08-18 Materia, Inc. Cyclic olefin resin compositions comprising functional elastomers
EP3448661B1 (en) * 2016-04-26 2024-03-27 Stratasys Ltd. Three-dimensional inkjet printing using ring-opening metathesis polymerization
PL421462A1 (pl) * 2017-04-28 2018-11-05 Uniwersytet Warszawski Sposób wytwarzania cyklicznych związków w reakcji metatezy olefin oraz zastosowanie katalizatorów rutenowych do wytwarzania cyklicznych olefin w reakcjach metatezy olefin
US11939410B2 (en) * 2018-06-29 2024-03-26 Apeiron Synthesis S.A. Organoruthenium complexes as precatalysts for olefin metathesis

Also Published As

Publication number Publication date
WO2020201314A1 (en) 2020-10-08
EP3947515A1 (en) 2022-02-09
US12338310B2 (en) 2025-06-24
US20220177612A1 (en) 2022-06-09
EP3947515B1 (en) 2023-03-01

Similar Documents

Publication Publication Date Title
Pugh et al. Metal complexes with ‘pincer’-type ligands incorporating N-heterocyclic carbene functionalities
Crespo et al. Kinetico-mechanistic studies on CX (X= H, F, Cl, Br, I) bond activation reactions on organoplatinum (II) complexes
MX2022001290A (es) Complejos de peptido biciclico en heterotandem.
EP4431180A3 (en) Olefin metathesis catalysts
PL1757613T3 (pl) Wielokoordynacyjne kompleksy metalu do zastosowania w reakcjach metatezy
Hirano et al. Oxidative coupling reactions at ruthenium (0) and their applications to catalytic homo-and cross-dimerizations¶
PL425935A1 (pl) Kompozycja katalityczna zawierająca nikiel, ligand typu fosfinowego oraz zasadę Lewisa oraz jej zastosowanie w sposobie oligomeryzacji olefin
WO2018236863A8 (en) Biaryl phenoxy group iv transition metal catalysts for olefin polymerization
AR078212A1 (es) Catalizador para isomerizacion y metatesis de olefinas
PL414234A1 (pl) Sposób wytwarzania kompleksów rutenu i związków pośrednich oraz ich zastosowanie w metatezie olefin
ATE485311T1 (de) Katalysatoren für die olefinpolymerisation
PL419421A1 (pl) Zastosowanie kompleksów rutenu w reakcji metatezy olefin
MX2021005690A (es) Metodo para la metatesis de olefinas utilizando un catalizador en la presencia de un activador y un agente retardante.
PL421462A1 (pl) Sposób wytwarzania cyklicznych związków w reakcji metatezy olefin oraz zastosowanie katalizatorów rutenowych do wytwarzania cyklicznych olefin w reakcjach metatezy olefin
RU2015143202A (ru) Бис(2-инденил)металлоценовый комплекс
ATE346853T1 (de) Lösliche spätübergangsmetallkatalysatoren für olefinpolymerisation
WO2019067274A8 (en) Bis-phenyl-phenoxy polyolefin catalysts having two methylenetrialkylsilicon ligands on the metal for improved solubility
CO2019003127A2 (es) Sistema catalizador usado en la oligomerización de olefinas y método para la oligomerización de olefinas
EA202091281A1 (ru) Способ полимеризации циклоолефинов с помощью метатезиса с раскрытием кольца
WO2010096445A3 (en) Thermally switchable ruthenium initiators
SA519401840B1 (ar) طريقة لتحضير محلول محفز لإنتاج 1-هكسين انتقائي
PL400397A1 (pl) Nowe kompleksy metali, zwlaszcza rutenu oraz ich zastosowanie
FR3039431B1 (fr) Nouvelle composition catalytique a base de nickel et d'un ligand de type phosphine complexe au nickel et son utilisation dans un procede d'oligomerisation des olefines
PL419637A1 (pl) Nowy kompleks rutenu, sposób jego otrzymywania oraz zastosowanie w reakcji metatezy olefin
PL434983A1 (pl) Nowe kompleksy rutenu, sposoby ich wytwarzania i ich zastosowanie w reakcji krzyżowej metatezy olefin