PL441676A1 - Sposób katalitycznej konwersji palnej materii węglonośnej do gazu syntezowego i urządzenie do katalitycznej konwersji palnej materii węglonośnej do gazu syntezowego - Google Patents

Sposób katalitycznej konwersji palnej materii węglonośnej do gazu syntezowego i urządzenie do katalitycznej konwersji palnej materii węglonośnej do gazu syntezowego

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Publication number
PL441676A1
PL441676A1 PL441676A PL44167622A PL441676A1 PL 441676 A1 PL441676 A1 PL 441676A1 PL 441676 A PL441676 A PL 441676A PL 44167622 A PL44167622 A PL 44167622A PL 441676 A1 PL441676 A1 PL 441676A1
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PL
Poland
Prior art keywords
synthesis gas
carbon
bearing matter
layer
matter
Prior art date
Application number
PL441676A
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English (en)
Inventor
Albin Czernichowski
Marek Tyksiński
Janusz Przeorek
Original Assignee
Albin Czernichowski
Marek Tyksiński
Janusz Przeorek
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Albin Czernichowski, Marek Tyksiński, Janusz Przeorek filed Critical Albin Czernichowski
Priority to PL441676A priority Critical patent/PL441676A1/pl
Priority to EP23765580.8A priority patent/EP4551505A2/en
Priority to CA3261264A priority patent/CA3261264A1/en
Priority to PCT/PL2023/000035 priority patent/WO2024010472A2/en
Publication of PL441676A1 publication Critical patent/PL441676A1/pl

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/0005—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes
    • C01B3/001—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes characterised by the uptaking media; Treatment thereof
    • C01B3/0018—Inorganic elements or compounds, e.g. oxides, nitrides, borohydrides or zeolites; Solutions thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys
    • C01B3/0047—Intermetallic compounds; Metal alloys containing a rare earth metal
    • C01B3/0057—Intermetallic compounds; Metal alloys containing a rare earth metal and nickel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
    • B01J8/0453—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being superimposed one above the other
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/40—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/00044—Temperature measurement
    • B01J2208/00061—Temperature measurement of the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00628—Controlling the composition of the reactive mixture
    • B01J2208/00646—Means for starting up the reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00716—Means for reactor start-up
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0855—Methods of heating the process for making hydrogen or synthesis gas by electromagnetic heating
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1023—Catalysts in the form of a monolith or honeycomb
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
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    • C01—INORGANIC CHEMISTRY
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    • C01B2203/14—Details of the flowsheet
    • C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
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    • C01B2203/1614—Controlling the temperature
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    • C01—INORGANIC CHEMISTRY
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    • C01B2203/1628—Controlling the pressure
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/169—Controlling the feed

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)

Abstract

Przedmiotem zgłoszenia jest sposób katalityczno-dotleniającej konwersji palnej materii węglonośnej do gazu syntezowego metodą półspalania (POX), który charakteryzuje się tym, że tę materię węglonośną będącą w postaci gazowej, parowej lub ciekłej bezpopiołowej dotlenia się za pomocą czynnika dotleniającego w obecności dwóch kolejnych katalizatorów POX osadzonych na nośnikach ułożonych warstwowo, przy czym katalizatorem w pierwszej warstwie jest mieszanina tlenków niklu i ceru w stosunku wagowym Ni/Ce od 0,5 do 1 i o właściwościach utleniających tę materię w temperaturze od 1200°C do 800°C, a katalizatorem w drugiej warstwie jest nikiel metaliczny albo mieszanina tlenków niklu i ceru w stosunku wagowym Ni/Ce od 2 do 10 i o właściwościach redukcyjno-rekombinacyjnych w temperaturze od 800°C do 300°C. Temperatury wewnątrz warstw tych katalizatorów zmieniają się stopniowo wzdłuż kierunku przepływającej materii wejściowej od maksimum 1200°C przy kontakcie reagentów z pierwszą warstwą aż do minimum 300°C na wylocie gazu syntezowego, będącego produktem tej konwersji, a temperaturę pierwszej, początkowo zimnej warstwy katalizatora w operacji zimnego startu, doprowadza się do co najmniej 750°C za pomocą ślizgającego się wyładowania elektrycznego GlidArc, po czym wyładowanie zatrzymuje się. Wynalazek obejmuje także reaktor do katalityczno-dotleniającej konwersji palnej materii węglonośnej.
PL441676A 2022-07-08 2022-07-08 Sposób katalitycznej konwersji palnej materii węglonośnej do gazu syntezowego i urządzenie do katalitycznej konwersji palnej materii węglonośnej do gazu syntezowego PL441676A1 (pl)

Priority Applications (4)

Application Number Priority Date Filing Date Title
PL441676A PL441676A1 (pl) 2022-07-08 2022-07-08 Sposób katalitycznej konwersji palnej materii węglonośnej do gazu syntezowego i urządzenie do katalitycznej konwersji palnej materii węglonośnej do gazu syntezowego
EP23765580.8A EP4551505A2 (en) 2022-07-08 2023-07-08 Method for the catalytic conversion of carbonaceous fuel into synthesis gas and apparatus for the catalytic conversion of carbonaceous fuel into synthesis gas
CA3261264A CA3261264A1 (en) 2022-07-08 2023-07-08 Catalytic conversion method of carbonaceous fuel into synthesis gas and apparatus for the catalytic conversion of carbonaceous fuel into synthesis gas
PCT/PL2023/000035 WO2024010472A2 (en) 2022-07-08 2023-07-08 Catalytic conversion method of carbonaceous fuel into synthesis gas and apparatus for catalytic conversion of carbonaceous fuel into synthesis gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL441676A PL441676A1 (pl) 2022-07-08 2022-07-08 Sposób katalitycznej konwersji palnej materii węglonośnej do gazu syntezowego i urządzenie do katalitycznej konwersji palnej materii węglonośnej do gazu syntezowego

Publications (1)

Publication Number Publication Date
PL441676A1 true PL441676A1 (pl) 2024-01-15

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ID=87971958

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Application Number Title Priority Date Filing Date
PL441676A PL441676A1 (pl) 2022-07-08 2022-07-08 Sposób katalitycznej konwersji palnej materii węglonośnej do gazu syntezowego i urządzenie do katalitycznej konwersji palnej materii węglonośnej do gazu syntezowego

Country Status (4)

Country Link
EP (1) EP4551505A2 (pl)
CA (1) CA3261264A1 (pl)
PL (1) PL441676A1 (pl)
WO (1) WO2024010472A2 (pl)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6887456B2 (en) * 2001-10-05 2005-05-03 Conocophillips Company Catalyst system for enhanced flow syngas production
FR2872149B1 (fr) * 2004-06-28 2007-10-19 Physiques Sarl Et Chimiques Conversion plasma-catalytique de matieres carbonees
CA2612320C (en) * 2005-06-27 2012-04-17 Ceramatec, Inc. Plasma-catalytic conversion of carbonaceous matters

Also Published As

Publication number Publication date
WO2024010472A2 (en) 2024-01-11
EP4551505A2 (en) 2025-05-14
CA3261264A1 (en) 2024-01-11
WO2024010472A3 (en) 2024-02-15

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