PL442176A1 - Estry kwasu trimelitowego i izoprenolu oraz sposób ich otrzymywania i zastosowanie estrów kwasu trimelitowego i izoprenolu - Google Patents
Estry kwasu trimelitowego i izoprenolu oraz sposób ich otrzymywania i zastosowanie estrów kwasu trimelitowego i izoprenoluInfo
- Publication number
- PL442176A1 PL442176A1 PL442176A PL44217622A PL442176A1 PL 442176 A1 PL442176 A1 PL 442176A1 PL 442176 A PL442176 A PL 442176A PL 44217622 A PL44217622 A PL 44217622A PL 442176 A1 PL442176 A1 PL 442176A1
- Authority
- PL
- Poland
- Prior art keywords
- isoprenol
- esters
- trimellitic acid
- preparation
- weight
- Prior art date
Links
- 150000002148 esters Chemical class 0.000 title abstract 6
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 title abstract 6
- CPJRRXSHAYUTGL-UHFFFAOYSA-N isopentenyl alcohol Chemical compound CC(=C)CCO CPJRRXSHAYUTGL-UHFFFAOYSA-N 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- KRADHMIOFJQKEZ-UHFFFAOYSA-N Tri-2-ethylhexyl trimellitate Chemical compound CCCCC(CC)COC(=O)C1=CC=C(C(=O)OCC(CC)CCCC)C(C(=O)OCC(CC)CCCC)=C1 KRADHMIOFJQKEZ-UHFFFAOYSA-N 0.000 abstract 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 abstract 1
- 239000012975 dibutyltin dilaurate Substances 0.000 abstract 1
- LQRUPWUPINJLMU-UHFFFAOYSA-N dioctyl(oxo)tin Chemical compound CCCCCCCC[Sn](=O)CCCCCCCC LQRUPWUPINJLMU-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 238000005809 transesterification reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Przedmiotem zgłoszenia są estry kwasu trimelitowego i izoprenolu oraz sposób ich otrzymywania na drodze reakcji transestryfikacji trimelitanu tris(2-etyloheksylu) z izoprenolem przy użyciu jednego z trzech katalizatorów: tlenku dibutylocyny, tlenku dioktylocyny albo dilaurynianu dibutylocyny. Reakcja może być prowadzona na dwa sposoby: aby otrzymać zawartość estrów podstawionych na poziomie min. 88% wag. albo, aby otrzymać zawartość estrów monopodstawionych na poziomie min. 67% wag. Po oddestylowaniu pozostałości alkoholi mieszanina estrów może zostać zastosowana do plastyfikacji polichlorku winylu.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL442176A PL442176A1 (pl) | 2022-09-01 | 2022-09-01 | Estry kwasu trimelitowego i izoprenolu oraz sposób ich otrzymywania i zastosowanie estrów kwasu trimelitowego i izoprenolu |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL442176A PL442176A1 (pl) | 2022-09-01 | 2022-09-01 | Estry kwasu trimelitowego i izoprenolu oraz sposób ich otrzymywania i zastosowanie estrów kwasu trimelitowego i izoprenolu |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL442176A1 true PL442176A1 (pl) | 2024-03-04 |
Family
ID=90106972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL442176A PL442176A1 (pl) | 2022-09-01 | 2022-09-01 | Estry kwasu trimelitowego i izoprenolu oraz sposób ich otrzymywania i zastosowanie estrów kwasu trimelitowego i izoprenolu |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL442176A1 (pl) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1136688A (en) * | 1966-04-28 | 1968-12-11 | Fmc Corp | Polyallyl esters |
| US4473702A (en) * | 1979-11-15 | 1984-09-25 | Kureha Kagaku Kogyo Kabushiki Kaisha | Method for producing diallyl ester of aromatic dicarboxylic acid |
| US20170088691A1 (en) * | 2015-09-28 | 2017-03-30 | Evonik Degussa Gmbh | Tripentyl esters of trimellitic acid |
-
2022
- 2022-09-01 PL PL442176A patent/PL442176A1/pl unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1136688A (en) * | 1966-04-28 | 1968-12-11 | Fmc Corp | Polyallyl esters |
| US4473702A (en) * | 1979-11-15 | 1984-09-25 | Kureha Kagaku Kogyo Kabushiki Kaisha | Method for producing diallyl ester of aromatic dicarboxylic acid |
| US20170088691A1 (en) * | 2015-09-28 | 2017-03-30 | Evonik Degussa Gmbh | Tripentyl esters of trimellitic acid |
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