PL443012A1 - New iodonium salts, method of producing new iodonium salts, application of new iodonium salts, new photocurable composites intended for dental fillings, method of producing new photocurable composites intended for dental fillings and the use of biphenyl derivatives - Google Patents

New iodonium salts, method of producing new iodonium salts, application of new iodonium salts, new photocurable composites intended for dental fillings, method of producing new photocurable composites intended for dental fillings and the use of biphenyl derivatives

Info

Publication number
PL443012A1
PL443012A1 PL443012A PL44301222A PL443012A1 PL 443012 A1 PL443012 A1 PL 443012A1 PL 443012 A PL443012 A PL 443012A PL 44301222 A PL44301222 A PL 44301222A PL 443012 A1 PL443012 A1 PL 443012A1
Authority
PL
Poland
Prior art keywords
new
iodonium salts
sub
biphenyl
phenyliodonium
Prior art date
Application number
PL443012A
Other languages
Polish (pl)
Other versions
PL248381B1 (en
Inventor
Monika Topa-Skwarczyńska
Joanna Ortyl
Mariusz Galek
Original Assignee
Photo Hitech Spółka Z Ograniczoną Odpowiedzialnością
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Photo Hitech Spółka Z Ograniczoną Odpowiedzialnością filed Critical Photo Hitech Spółka Z Ograniczoną Odpowiedzialnością
Priority to PL443012A priority Critical patent/PL248381B1/en
Publication of PL443012A1 publication Critical patent/PL443012A1/en
Publication of PL248381B1 publication Critical patent/PL248381B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/06—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to carbon atoms of six-membered aromatic rings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/60—Preparations for dentistry comprising organic or organo-metallic additives
    • A61K6/62—Photochemical radical initiators
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/27—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups
    • C07C205/35—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/18—Polycyclic aromatic halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Biophysics (AREA)
  • Dental Preparations (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Zgłoszenie dotyczy nowych soli jodoniowych o wzorze ogólnym (1), w którym E<sup>ϴ</sup> oznacza anion heksafluorofosforanowy lub tosylowy, a X oznacza podstawnik o wzorze ogólnym (2A),związany z atomem jodu poprzez atom węgla w pozycji 2 lub 5, odpowiadającej położeniu podstawnika R<sub>1</sub> lub R<sub>4</sub>, odpowiednio, w którym to wzorze (2A) podstawniki R<sub>1</sub> - R<sub>4</sub>, o ile odpowiadający podstawnikowi R<sub>1</sub> lub R<sub>4</sub> atom węgla w pozycji 2 lub 5 nie tworzy wiązania z atomem jodu, niezależnie od siebie oznaczają atom wodoru lub grupę metoksylową, które to nowe sole jodoniowe wybrane są z grupy obejmującej: tosylan (2,4-dimetoksy-4'-nitro[1,1'-bifenyl]-5 -yl)fenylojodoniowy, tosylan (2-metoksy-4'-nitro[1,1'-bifenyl]-5-yl)fenylojodoniowy, tosylan (4-metoksy-4'-nitro[1,1'-bifenyl]-3-yl)fenylojodoniowy, tosylan (3,5-dimetoksy-4'-nitro[1,1'-bifenyl]-2-yl)fenylojodoniowy, heksafluorofosforan (2,4-dimetoksy-4'-nitrol[1,1'-bifenyl]-5-yl)fenylojodoniowy, heksafluorofosforan (2-metoksy-4'-nitro[1,1'-bifenyl]-5-yl)fenylojodoniowy, heksafluorofosforan (4-metoksy-4'-nitro[1,1'-bifenyl]-3-yl)fenylojodoniowy, heksafluorofosforan (3,5-dimetoksy-4'-nitro[1,1'-bifenyl]-2-yl)fenylojodoniowy. Zgłoszenie dotyczy także sposobu wytwarzania nowych soli jodoniowych, zastosowania nowych soli jodoniowych, nowych kompozytów fotoutwardzalnych przeznaczonych na wypełnienia stomatologiczne, sposobu wytwarzania nowych kompozytów fotoutwardzalnych przeznaczonych na wypełnienia stomatologiczne i zastosowania pochodnych bifenylu.The application concerns new iodonium salts of the general formula (1), in which E<sup>ϴ</sup> is a hexafluorophosphate or tosyl anion, and X is a substituent of the general formula (2A), bonded to the iodine atom through the carbon atom in position 2 or 5, corresponding to the position of the substituent R<sub>1</sub> or R<sub>4</sub>, respectively, in which formula (2A) substituents R<sub>1</sub> - R<sub> 4</sub>, unless the carbon atom in position 2 or 5 corresponding to the substituent R<sub>1</sub> or R<sub>4</sub> does not form a bond with the iodine atom, independently of each other represent a hydrogen atom or a methoxy group, which new iodonium salts are selected from the group consisting of: (2,4-dimethoxy-4'-nitro[1,1'-biphenyl]-5-yl)phenyliodonium tosylate, (2-methoxy-4'- nitro[1,1'-biphenyl]-5-yl)phenyliodonium, (4-methoxy-4'-nitro[1,1'-biphenyl]-3-yl)phenyliodonium tosylate, (3,5-dimethoxy-4) tosylate '-nitro[1,1'-biphenyl]-2-yl)phenyliodonium, (2,4-dimethoxy-4'-nitrol[1,1'-biphenyl]-5-yl)phenyliodonium hexafluorophosphate, (2-methoxy -4'-nitro[1,1'-biphenyl]-5-yl)phenyliodonium, (4-methoxy-4'-nitro[1,1'-biphenyl]-3-yl)phenyliodonium hexafluorophosphate, (3,5 -dimethoxy-4'-nitro[1,1'-biphenyl]-2-yl)phenyliodonium. The application also concerns the method of producing new iodonium salts, the use of new iodonium salts, new photocurable composites intended for dental fillings, the method of producing new photocurable composites intended for dental fillings and the use of biphenyl derivatives.

PL443012A 2022-11-30 2022-11-30 New iodonium salts, method of producing new iodonium salts, application of new iodonium salts, new photocurable composites intended for dental fillings, method of producing new photocurable composites intended for dental fillings and the use of biphenyl derivatives PL248381B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL443012A PL248381B1 (en) 2022-11-30 2022-11-30 New iodonium salts, method of producing new iodonium salts, application of new iodonium salts, new photocurable composites intended for dental fillings, method of producing new photocurable composites intended for dental fillings and the use of biphenyl derivatives

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL443012A PL248381B1 (en) 2022-11-30 2022-11-30 New iodonium salts, method of producing new iodonium salts, application of new iodonium salts, new photocurable composites intended for dental fillings, method of producing new photocurable composites intended for dental fillings and the use of biphenyl derivatives

Publications (2)

Publication Number Publication Date
PL443012A1 true PL443012A1 (en) 2024-06-03
PL248381B1 PL248381B1 (en) 2025-12-08

Family

ID=91333079

Family Applications (1)

Application Number Title Priority Date Filing Date
PL443012A PL248381B1 (en) 2022-11-30 2022-11-30 New iodonium salts, method of producing new iodonium salts, application of new iodonium salts, new photocurable composites intended for dental fillings, method of producing new photocurable composites intended for dental fillings and the use of biphenyl derivatives

Country Status (1)

Country Link
PL (1) PL248381B1 (en)

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
BALCERAK, A., & KABATC, J., THE PHOTOOXIDATIVE SENSITIZATION OF BIS(P-SUBSTITUTED DIPHENYL)IODONIUM SALTS IN THE RADICAL POLYMERIZATION OF ACRYLATES. RSC ADVANCES, (2019) 9, 28490 - 28499. *
KABATC, J., ORTYL, J., & KOSTRZEWSKA, K., NEW KINETIC AND MECHANISTIC ASPECTS OF PHOTOSENSITIZATION OF IODONIUM SALTS IN PHOTOPOLYMERIZATION OF ACRYLATES. RSC ADVANCES, (2017) 7, 41619-41629. DOI:10.1039/C7RA05978G *
VILLOTTE, S.; GIGMES, D.; DUMUR, F.; LALEVÉE, J., DESIGN OF IODONIUM SALTS FOR UV OR NEAR-UV LEDS FOR PHOTOACID GENERATOR AND POLYMERIZATION PURPOSES. MOLECULES 2020, 25, 149. HTTPS://DOI.ORG/10.3390/MOLECULES25010149 *

Also Published As

Publication number Publication date
PL248381B1 (en) 2025-12-08

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