PL443105A1 - Sposób otrzymywania kwasów karboksylowych z biomasy lignocelulozowej z wykorzystaniem frakcji hemicelulozowej - Google Patents
Sposób otrzymywania kwasów karboksylowych z biomasy lignocelulozowej z wykorzystaniem frakcji hemicelulozowejInfo
- Publication number
- PL443105A1 PL443105A1 PL443105A PL44310522A PL443105A1 PL 443105 A1 PL443105 A1 PL 443105A1 PL 443105 A PL443105 A PL 443105A PL 44310522 A PL44310522 A PL 44310522A PL 443105 A1 PL443105 A1 PL 443105A1
- Authority
- PL
- Poland
- Prior art keywords
- amount
- carboxylic acids
- hemicellulose fraction
- lignocellulosic biomass
- temperature
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 6
- 229920002488 Hemicellulose Polymers 0.000 title abstract 4
- 150000001735 carboxylic acids Chemical class 0.000 title abstract 3
- 239000002029 lignocellulosic biomass Substances 0.000 title abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 4
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 abstract 3
- AEMOLEFTQBMNLQ-YMDCURPLSA-N D-galactopyranuronic acid Chemical compound OC1O[C@H](C(O)=O)[C@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-YMDCURPLSA-N 0.000 abstract 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000001720 carbohydrates Chemical class 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 239000002638 heterogeneous catalyst Substances 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- YZUPZGFPHUVJKC-UHFFFAOYSA-N 1-bromo-2-methoxyethane Chemical compound COCCBr YZUPZGFPHUVJKC-UHFFFAOYSA-N 0.000 abstract 1
- 239000002028 Biomass Substances 0.000 abstract 1
- AEMOLEFTQBMNLQ-AQKNRBDQSA-N D-glucopyranuronic acid Chemical compound OC1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-AQKNRBDQSA-N 0.000 abstract 1
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 abstract 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 abstract 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 abstract 1
- SHZGCJCMOBCMKK-JFNONXLTSA-N L-rhamnopyranose Chemical compound C[C@@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O SHZGCJCMOBCMKK-JFNONXLTSA-N 0.000 abstract 1
- PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000007900 aqueous suspension Substances 0.000 abstract 1
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 abstract 1
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 229930182830 galactose Natural products 0.000 abstract 1
- 239000008103 glucose Substances 0.000 abstract 1
- 229940097043 glucuronic acid Drugs 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000005580 one pot reaction Methods 0.000 abstract 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
- C12P7/54—Acetic acid
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
- C12P7/56—Lactic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Biotechnology (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Przedmiotem zgłoszenia jest sposób otrzymywania kwasów karboksylowych z biomasy lignocelulozowej w procesie katalitycznym typu one-pot w reaktorze ciśnieniowym, który charakteryzuje się tym, że wodną zawiesinę biomasy lignocelulozowej zawierającą węglowodanową frakcję hemicelulozową w której znajdują się kwasy uronowe, korzystnie kwas galakturonowy i/lub kwas glukuronowy w ilości do 39% kwasu galakturonowego i do 1,2% kwasu glukoronowego frakcji hemicelulozowej biomasy miesza się z katalizatorem heterogenicznym w stosunku masowym 1:4 katalizatora do roztworu węglowodanów frakcji hemicelulozowej, umieszcza się w autoklawie, a następnie dokładnie miesza, szczelnie zamyka izolując układ reakcyjny od otoczenia, podgrzewa do temperatury 100 - 250°C utrzymując układ reakcyjny w podwyższonej temperaturze przez 1 - 5 h, następnie obniża się temperaturę układu reakcyjnego do wartości 20 - 25°C (temperatura pokojowa), a potem układ reakcyjny rozdziela się w procesie filtracji uzyskując fazę ciekłą, która zawiera mieszaninę kwasów karboksylowych C1 - C3, przy czym frakcja hemicelulozowa kierowana do procesu zawiera ksylozę w ilości 55 - 69%, mannozę w ilości 1 - 5%, galaktozę w ilości 1 - 12%, glukozę w ilości 2 - 9%, ramnozę w ilości 1 - 3%, a jako katalizator heterogeniczny stosuje się zeolit typu BEA modyfikowany w procesie suszenia i kalcynacji, zeolit typu Na-BEA, żywice jonowymienne, korzystnie żywice AMBERLYST 15(H) lub DOWEX DRG8(H).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL443105A PL247009B1 (pl) | 2022-12-09 | 2022-12-09 | Sposób otrzymywania kwasów karboksylowych z biomasy lignocelulozowej z wykorzystaniem frakcji hemicelulozowej |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL443105A PL247009B1 (pl) | 2022-12-09 | 2022-12-09 | Sposób otrzymywania kwasów karboksylowych z biomasy lignocelulozowej z wykorzystaniem frakcji hemicelulozowej |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL443105A1 true PL443105A1 (pl) | 2024-06-10 |
| PL247009B1 PL247009B1 (pl) | 2025-04-22 |
Family
ID=91432134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL443105A PL247009B1 (pl) | 2022-12-09 | 2022-12-09 | Sposób otrzymywania kwasów karboksylowych z biomasy lignocelulozowej z wykorzystaniem frakcji hemicelulozowej |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL247009B1 (pl) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103313955A (zh) * | 2010-12-30 | 2013-09-18 | 维仁特公司 | 还原性生物质液化 |
| US20170002387A1 (en) * | 2013-05-28 | 2017-01-05 | Api Intellectual Property Holdings, Llc | Processes for fermentation of lignocellulosic glucose to aliphatic alcohols or acids |
| US10214474B2 (en) * | 2014-10-06 | 2019-02-26 | Cooperatie Koninklijke Cosun U.A. | Oxidation of uronic acids to aldaric acids |
| US20200056213A1 (en) * | 2015-07-08 | 2020-02-20 | GranBio Intellectual Property Holdings, LLC | Processes for fermentation of lignocellulosic glucose to aliphatic alcohols or acids |
-
2022
- 2022-12-09 PL PL443105A patent/PL247009B1/pl unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103313955A (zh) * | 2010-12-30 | 2013-09-18 | 维仁特公司 | 还原性生物质液化 |
| US20170002387A1 (en) * | 2013-05-28 | 2017-01-05 | Api Intellectual Property Holdings, Llc | Processes for fermentation of lignocellulosic glucose to aliphatic alcohols or acids |
| US10214474B2 (en) * | 2014-10-06 | 2019-02-26 | Cooperatie Koninklijke Cosun U.A. | Oxidation of uronic acids to aldaric acids |
| US20200056213A1 (en) * | 2015-07-08 | 2020-02-20 | GranBio Intellectual Property Holdings, LLC | Processes for fermentation of lignocellulosic glucose to aliphatic alcohols or acids |
Also Published As
| Publication number | Publication date |
|---|---|
| PL247009B1 (pl) | 2025-04-22 |
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