PL443773A1 - Method of separating a mixture of lithium, cobalt and nickel cations in lithium-ion battery solutions - Google Patents

Method of separating a mixture of lithium, cobalt and nickel cations in lithium-ion battery solutions

Info

Publication number
PL443773A1
PL443773A1 PL443773A PL44377323A PL443773A1 PL 443773 A1 PL443773 A1 PL 443773A1 PL 443773 A PL443773 A PL 443773A PL 44377323 A PL44377323 A PL 44377323A PL 443773 A1 PL443773 A1 PL 443773A1
Authority
PL
Poland
Prior art keywords
lithium
cobalt
cations
exchange membrane
solutions
Prior art date
Application number
PL443773A
Other languages
Polish (pl)
Other versions
PL248450B1 (en
Inventor
Anna Siekierka
Original Assignee
Politechnika Wrocławska
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Politechnika Wrocławska filed Critical Politechnika Wrocławska
Priority to PL443773A priority Critical patent/PL248450B1/en
Publication of PL443773A1 publication Critical patent/PL443773A1/en
Publication of PL248450B1 publication Critical patent/PL248450B1/en

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/54—Reclaiming serviceable parts of waste accumulators
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/52—Reclaiming serviceable parts of waste cells or batteries, e.g. recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/84—Recycling of batteries or fuel cells

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Urology & Nephrology (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Development (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

Przedmiotem zgłoszenia jest sposób rozdziału roztworów mieszanin kationów metali litu (Li), niklu (Ni) i kobaltu (Co) w roztworach baterii litowo-jonowych, który charakteryzuje się tym, że wykorzystuje się elektromembranową separację jonów metali w połączeniu z selektywnym wytrącaniem soli do frakcjonowania jonów metali lekkich (Li) oraz przejściowych (Co, Ni), przy czym w pierwszym etapie przeprowadza się proces elektrodializy z wykorzystaniem znanej membrany anionowymiennej i przy zastosowaniu selektywnej membrany kationowymiennej w kierunku transportu kationów kobaltu, korzystnie sfunkcjonalizowanej 5-chloro-8-hydroksycholiną. Proces elektrodializy w co najmniej 5 V do czasu uzyskania stanu równowagi wymiany jonowej pomiędzy ewaluowaną membraną kationowymienną lub do momentu zahamowania wymiany jonowej z wykorzystaniem membrany anionowymiennej w wyniku czego wyselekcjonowany kation kobaltu przechodzi z komory nadawy do komory permeatu i uzyskuje się w komorze permeatu kationy kobaltu, a w komorze retentatu mieszaninę kationów litu oraz niklu. Następnie te roztwory poddaje się precypitacji, przy użyciu co najmniej jednego środka strącającego kationy metali przejściowych poddaje się co najmniej, korzystnie wodorotlenek lub siarczek lub siarczan (IV) lub fosforan lub węglan lub krzemian lub chromian.The subject of the application is a method for separating solutions of mixtures of lithium (Li), nickel (Ni) and cobalt (Co) metal cations in lithium-ion battery solutions, which is characterized in that electromembrane separation of metal ions is used in combination with selective precipitation of salts for fractionation of light metal ions (Li) and transition metal ions (Co, Ni), wherein in the first stage an electrodialysis process is carried out using a known anion exchange membrane and using a selective cation exchange membrane in the direction of transport of cobalt cations, preferably functionalized with 5-chloro-8-hydroxycholine. The electrodialysis process at at least 5 V until the equilibrium state of ion exchange is achieved between the evaluated cation exchange membrane or until the ion exchange using the anion exchange membrane is inhibited as a result of which the selected cobalt cation passes from the feed chamber to the permeate chamber and cobalt cations are obtained in the permeate chamber and a mixture of lithium and nickel cations in the retentate chamber. Then these solutions are subjected to precipitation, using at least one precipitating agent for transition metal cations, at least, preferably hydroxide or sulphide or sulphate (IV) or phosphate or carbonate or silicate or chromate.

PL443773A 2023-02-10 2023-02-10 Method for separating a mixture of lithium, cobalt and nickel cations in lithium-ion battery solutions PL248450B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL443773A PL248450B1 (en) 2023-02-10 2023-02-10 Method for separating a mixture of lithium, cobalt and nickel cations in lithium-ion battery solutions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL443773A PL248450B1 (en) 2023-02-10 2023-02-10 Method for separating a mixture of lithium, cobalt and nickel cations in lithium-ion battery solutions

Publications (2)

Publication Number Publication Date
PL443773A1 true PL443773A1 (en) 2024-08-12
PL248450B1 PL248450B1 (en) 2025-12-15

Family

ID=92264353

Family Applications (1)

Application Number Title Priority Date Filing Date
PL443773A PL248450B1 (en) 2023-02-10 2023-02-10 Method for separating a mixture of lithium, cobalt and nickel cations in lithium-ion battery solutions

Country Status (1)

Country Link
PL (1) PL248450B1 (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014056609A1 (en) * 2012-10-10 2014-04-17 Rockwood Lithium GmbH Method for the hydrometallurgical recovery of lithium, nickel and cobalt from the lithium transition metal oxide-containing fraction of used galvanic cells

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014056609A1 (en) * 2012-10-10 2014-04-17 Rockwood Lithium GmbH Method for the hydrometallurgical recovery of lithium, nickel and cobalt from the lithium transition metal oxide-containing fraction of used galvanic cells

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ANNA SIEKIERKA, FATMA YALCINKAYA: "Separation and Purification Technology; 2022, 299, 121695", SELECTIVE COBALT-EXCHANGE MEMBRANES FOR ELECTRODIALYSIS DEDICATED FOR COBALT RECOVERY FROM LITHIUM, COBALT AND NICKEL SOLUTIONS *
KA HO CHAN, MONU MALIK, GISELE AZIMI: "Resources, Conservation and Recycling, 2022, 178, 106076", SEPARATION OF LITHIUM, NICKEL, MANGANESE, AND COBALT FROM WASTE LITHIUM-ION BATTERIES USING ELECTRODIALYSIS *

Also Published As

Publication number Publication date
PL248450B1 (en) 2025-12-15

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