PL444177A1 - Sposób otrzymywania estru kwasu tereftalowego i alkoholu alifatycznego C8 z odpadowego poli(tereftalanu etylenu) - Google Patents
Sposób otrzymywania estru kwasu tereftalowego i alkoholu alifatycznego C8 z odpadowego poli(tereftalanu etylenu)Info
- Publication number
- PL444177A1 PL444177A1 PL444177A PL44417723A PL444177A1 PL 444177 A1 PL444177 A1 PL 444177A1 PL 444177 A PL444177 A PL 444177A PL 44417723 A PL44417723 A PL 44417723A PL 444177 A1 PL444177 A1 PL 444177A1
- Authority
- PL
- Poland
- Prior art keywords
- ethylene terephthalate
- poly
- alcohol
- reaction
- reaction mixture
- Prior art date
Links
- -1 terephthalic acid ester Chemical class 0.000 title abstract 11
- 229920000139 polyethylene terephthalate Polymers 0.000 title abstract 5
- 239000005020 polyethylene terephthalate Substances 0.000 title abstract 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 title abstract 3
- 239000002699 waste material Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 title 1
- 239000012451 post-reaction mixture Substances 0.000 abstract 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- GVKORIDPEBYOFR-UHFFFAOYSA-K [butyl-bis(2-ethylhexanoyloxy)stannyl] 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)O[Sn](CCCC)(OC(=O)C(CC)CCCC)OC(=O)C(CC)CCCC GVKORIDPEBYOFR-UHFFFAOYSA-K 0.000 abstract 1
- 239000000908 ammonium hydroxide Substances 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- BVFSYZFXJYAPQJ-UHFFFAOYSA-N butyl(oxo)tin Chemical compound CCCC[Sn]=O BVFSYZFXJYAPQJ-UHFFFAOYSA-N 0.000 abstract 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 abstract 1
- LQRUPWUPINJLMU-UHFFFAOYSA-N dioctyl(oxo)tin Chemical compound CCCCCCCC[Sn](=O)CCCCCCCC LQRUPWUPINJLMU-UHFFFAOYSA-N 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 239000012153 distilled water Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Substances [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Substances [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 abstract 1
- 238000005809 transesterification reaction Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
- C08J11/22—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
- C08J11/24—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/02—Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/80—Phthalic acid esters
- C07C69/82—Terephthalic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Przedmiotem zgłoszenia jest sposób otrzymywania estru kwasu tereftalowego i alkoholu alifatycznego C8, z odpadowego poli(tereftalanu etyienu), który polega na tym, że mieszaninę odpadowego poli(tereftalanu etylenu) i alifatycznego alkoholu C8 poddaje się transestryfikacji wobec katalizatora z grupy obejmującej butylo tris(2-etyloheksanian) cyny, bis(2-etyloheksanian) cyny, tlenek monobutylocyny, tlenek dibutylocyny oraz tlenek dioktylocyny. Reakcja przebiega w reaktorze okresowym, w temperaturze od 120 do 280°C, w czasie od 1 do 10 godzin, pod ciśnieniem od 500 do 1000 mBar. Udział katalizatora wynosi od 0,1 do 10% m/m w odniesieniu do masy poli(tereftalanu etylenu), zaś stosunek masowy alkoholu do poli (tereftalanu etylenu) wynosi od 1,2:1 do 8:1. Glikol polietylenowy, który powstaje w reakcji jest w sposób ciągły usuwany ze środowiska reakcji przez destylację. Uzyskaną mieszaninę poreakcyjną przesącza się i przemywa się wodnym roztworem wodorotlenku sodu, potasu albo amonu, o stężeniu od 1 do 15% m/m, w ilości od 1 do 50% m/m, w odniesieniu do masy przesączonej mieszaniny poreakcyjnej i przemywa się wodą destylowaną. Z oczyszczonej mieszaniny poreakcyjnej oddestylowuje się nadmiar alkoholu i otrzymuje surowy produkt, który można bezpośrednio zastosować jako plastyfikator, albo wcześniej poddać dalszemu oczyszczeniu.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL444177A PL444177A1 (pl) | 2023-03-21 | 2023-03-21 | Sposób otrzymywania estru kwasu tereftalowego i alkoholu alifatycznego C8 z odpadowego poli(tereftalanu etylenu) |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL444177A PL444177A1 (pl) | 2023-03-21 | 2023-03-21 | Sposób otrzymywania estru kwasu tereftalowego i alkoholu alifatycznego C8 z odpadowego poli(tereftalanu etylenu) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL444177A1 true PL444177A1 (pl) | 2024-09-23 |
Family
ID=92843887
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL444177A PL444177A1 (pl) | 2023-03-21 | 2023-03-21 | Sposób otrzymywania estru kwasu tereftalowego i alkoholu alifatycznego C8 z odpadowego poli(tereftalanu etylenu) |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL444177A1 (pl) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200938570A (en) * | 2008-03-10 | 2009-09-16 | Chang Chun Plastics Co Ltd | Method for producing high purity terephthalate from recycled polyester waste material |
| PL213868B1 (pl) * | 2006-10-06 | 2013-05-31 | Inst Inzynierii Materialow Polimerowych I Barwnikow | Sposób wytwarzania estrów i oligoestrów tereftalowych |
-
2023
- 2023-03-21 PL PL444177A patent/PL444177A1/pl unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL213868B1 (pl) * | 2006-10-06 | 2013-05-31 | Inst Inzynierii Materialow Polimerowych I Barwnikow | Sposób wytwarzania estrów i oligoestrów tereftalowych |
| TW200938570A (en) * | 2008-03-10 | 2009-09-16 | Chang Chun Plastics Co Ltd | Method for producing high purity terephthalate from recycled polyester waste material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB2153351A (en) | A process for the production of mixtures containing c6-c10-fatty acids | |
| US20170204045A1 (en) | Novel lactic acid recovery process | |
| US3594414A (en) | Process for the preparation of fiber-grade terephthalic acid | |
| CN111960943A (zh) | 一种半连续法生产对苯二甲酸二辛酯的工艺 | |
| EP0488467A2 (en) | Preparation of alkoxyalkanoic acids | |
| KR102313565B1 (ko) | 폴리올 에스테르의 후처리 방법 | |
| JP2015525074A (ja) | 乳酸エステルの製造方法 | |
| US20080183004A1 (en) | Method of preparing cyclohexanepolycarboxylic acid ester without phthalatic and plasticizer prepared by the same | |
| PL444177A1 (pl) | Sposób otrzymywania estru kwasu tereftalowego i alkoholu alifatycznego C8 z odpadowego poli(tereftalanu etylenu) | |
| GB1468388A (en) | Process for the hydrolysis of decidous wood | |
| EP2042588A1 (en) | Process for the esterification and transesterification of fats | |
| CN101914022A (zh) | 二步法生产高含量和高光学纯度乳酸甲酯的方法 | |
| PL444963A1 (pl) | Sposób otrzymywania estru kwasu tereftalowego i alkoholu alifatycznego C9 z odpadowego poli(tereftalanu etylenu) | |
| EP0206230A2 (en) | Methyl methacrylate production | |
| CN114989012A (zh) | 一种十六碳丁酯的连续化生产工艺 | |
| US7820859B2 (en) | Process for preparing L- (+) -lactic acid | |
| EP1953135A1 (en) | Method of preparing cyclohexanepolycarobxylic acid ester without phthalatic and plasticizer prepared by the same | |
| PL441925A1 (pl) | Sposób otrzymywania estru kwasu tereftalowego i alkoholu alifatycznego C8 z wykorzystaniem odpadowego poli(tereftalanu etylenu) | |
| CN110713439A (zh) | 一种环己烷-1，2-二甲酸酯类环保增塑剂的制备方法 | |
| US2993913A (en) | Preparation of 2, 2-bis (hydroxymethyl) tetrahydrofuran | |
| US2352253A (en) | Purification of aliphatic acids and anhydrides | |
| CN113754536A (zh) | 一种三乙二醇二正辛酸酯的制备方法 | |
| US2487610A (en) | Process of refining glycerin | |
| US2294346A (en) | Purification of fusel oil and amyl alcohol | |
| US3150165A (en) | Non-catalytic hydrolysis of diesters of dicarboxylic acids to the monoesters |