PL450047A1 - Sposób utleniania toluenu wobec metaloorganicznych cieczy jonowych - Google Patents

Sposób utleniania toluenu wobec metaloorganicznych cieczy jonowych

Info

Publication number
PL450047A1
PL450047A1 PL450047A PL45004724A PL450047A1 PL 450047 A1 PL450047 A1 PL 450047A1 PL 450047 A PL450047 A PL 450047A PL 45004724 A PL45004724 A PL 45004724A PL 450047 A1 PL450047 A1 PL 450047A1
Authority
PL
Poland
Prior art keywords
ionic liquids
organometallic
toluene oxidation
organometallic ionic
mpa
Prior art date
Application number
PL450047A
Other languages
English (en)
Inventor
Dawid Lisicki
Beata Orlińska
Piotr Wikliński
Original Assignee
Politechnika Śląska W Gliwicach
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Politechnika Śląska W Gliwicach filed Critical Politechnika Śląska W Gliwicach
Priority to PL450047A priority Critical patent/PL450047A1/pl
Publication of PL450047A1 publication Critical patent/PL450047A1/pl

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/04—Monocyclic monocarboxylic acids
    • C07C63/06—Benzoic acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Przedmiotem zgłoszenia jest sposób utleniania toluenu wobec metaloorganicznych cieczy jonowych, który polega na tym, że utlenianie prowadzi się w obecności od 0,1% do 1,0% molowych metaloorganicznej cieczy jonowej w przeliczeniu na surowiec, w kwasie octowym w stosunku objętościowym do surowca 1:10 do 1:2, proces prowadzi się w obecności gazu zawierającego tlen, w temperaturze od 110°C do 180°C, pod ciśnieniem 0,2 MPa do 2,0 MPa, w czasie od 0,5 h do 4 h.
PL450047A 2024-10-16 2024-10-16 Sposób utleniania toluenu wobec metaloorganicznych cieczy jonowych PL450047A1 (pl)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL450047A PL450047A1 (pl) 2024-10-16 2024-10-16 Sposób utleniania toluenu wobec metaloorganicznych cieczy jonowych

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL450047A PL450047A1 (pl) 2024-10-16 2024-10-16 Sposób utleniania toluenu wobec metaloorganicznych cieczy jonowych

Publications (1)

Publication Number Publication Date
PL450047A1 true PL450047A1 (pl) 2026-04-20

Family

ID=99477177

Family Applications (1)

Application Number Title Priority Date Filing Date
PL450047A PL450047A1 (pl) 2024-10-16 2024-10-16 Sposób utleniania toluenu wobec metaloorganicznych cieczy jonowych

Country Status (1)

Country Link
PL (1) PL450047A1 (pl)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107626349A (zh) * 2017-09-27 2018-01-26 三峡大学 一种制备苯甲醇、苯甲醛和苯甲酸的催化剂及制备苯甲醇、苯甲醛和苯甲酸的方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107626349A (zh) * 2017-09-27 2018-01-26 三峡大学 一种制备苯甲醇、苯甲醛和苯甲酸的催化剂及制备苯甲醇、苯甲醛和苯甲酸的方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
BIN LU ET AL: "Chemical Engineering Journal, vol. 225, 01.06.2012, p. 266-272 https://www.sciencedirect.com/science/article/abs/pii/S1385894713004129", SOLVENT-FREE OXIDATION OF TOLUENE IN AN IONIC LIQUID WITH H2O2 AS OXIDANT *
DAWID LISICKI ET AL.,: "Ind. Enf. Chem. Res., vol.60/issue 30, 11579-11589, 20.07.2021 https://pubs.acs.org/doi/epdf/10.1021/acs.iecr.1c00927?ref=article_openPDF", SELECTIVE AEROBIC OXIDATION OF TOLUENE IN THE PRESENCE OF CO2+ AND TASK-SPECIFIC ORGANIC SALTS, INCLUDING IONIC LIQUIDS *

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