PL4742B1 - Oil-splitting agent. - Google Patents
Oil-splitting agent. Download PDFInfo
- Publication number
- PL4742B1 PL4742B1 PL4742A PL474224A PL4742B1 PL 4742 B1 PL4742 B1 PL 4742B1 PL 4742 A PL4742 A PL 4742A PL 474224 A PL474224 A PL 474224A PL 4742 B1 PL4742 B1 PL 4742B1
- Authority
- PL
- Poland
- Prior art keywords
- fats
- splitting
- oil
- acids
- splitting agent
- Prior art date
Links
- 239000003925 fat Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000011148 porous material Substances 0.000 claims description 2
- 241001303601 Rosacea Species 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 201000004700 rosacea Diseases 0.000 claims 1
- 150000003460 sulfonic acids Chemical class 0.000 description 7
- 239000002253 acid Substances 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000012505 colouration Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
Description
Do rozszczepiania tluszczów stosowano znane organiczne, naogól ciezko plynna, smoliste kwasy sulfonowe. Wytwarzanie tych kwasów w stanie czystym zarówno jak ich dawkowanie nasuwa jednak znacz¬ ne trudnosci. Dlatego próbowano stosowac do rozszczepiania tluszczów sole tych kwa¬ sów, lecz pomimo pewnych dodatnich stron nie jest to takze korzystne, poniewaz zdol¬ nosc rozszczepiania kwasów sulfonowych zmniejsza sie silnie z powodu obecnosci so¬ li nieorganicznych.Tymczasem stwierdzono, ze mozna przez mieszanine ciezkorplynnych kwasów sulfo¬ nowych z materialami porowatemi nip. z ziemia okrzemkowa, weglem zwierzecym I tym podobnemi otrzymac produkty w po¬ staci proszków, które w dzialaniu sa o wie¬ le lepsze, niz sole kwasów sulfonowych, u- zywane do rozszczepiania tluszczów, a na¬ wet niekiedy znacznie przewyzszaja kwasy sulfonowe, stosowana bez [przytoczonych powyzej materialów.Okazalo sie równiez,, ze nowe te srodki rozszczepiaja tluszcze na kwasy tluszczowe i gliceryne prawie calkowicie bez ciemnego zabarwienia, jakie powstaje zwykle przy rozszczepianiu tluszczów znanym sposcu bem.Wobec tego przy zastosowaniu nowych srodków do rozszczepiania tluszczów, osia¬ gnieto skutek dodatni.Oczywiscie mozna takze niekrystaliez- ne sole oraz pochodne kwasów sulfonowychprzerobic na wiecej wartosciowe produkty przez zmieszanie z matenj atami porowa¬ temu Przyklad. 1000 kg loju wolowego pó u- pr ze dniem oczyszczeniu1 przez dodanie od¬ powiedniej ilosci wody i kwasu siatkowego, gotuje sie po zmieszaniu z 15 kg srodka, u- zyskanego przez zmieszanie 1 czesci od¬ czynnika Twitchella i 1,5 czesci ziemi o- krzemkowej. Juz po uplywie 12 godzin roz¬ szczepienie ' dochodzi do 90% i moze byc doprowadzone do 100% przez odlanie war¬ stwy wodnej i przedluzenie gotowania o kilka godzin. Otrzymane kwasy tluszczowe wyfcazujja wybitnie jasne zabarwienie.Zamiast podanego srodka mozna z tym samym skutkiem stoisowac inne aromatycz]- no-tluszczowe kwasy sulfonowe, kwasy sul¬ fonowe z olejów mineralnych lulb tez kwasy sulfonowe, nadajace sie do rozszczepiania tluszczów wedlug patentów niemieckich Sch. 65987 IV 23d, R. 58507 IV 23d i R. 59740 IV 23d, Ziemie okrzemkowa mozna tez zastapic ziemia bielaca, weglem aktyw¬ nym lub tym podobnem cialem. PLKnown organic, generally liquid, tar sulphonic acids were used to split fats. However, the production of these acids in a pure state, as well as their dosing, presents considerable difficulties. Therefore, attempts have been made to use salts of these acids for splitting fats, but despite some positive sides it is also not advantageous, because the ability to split sulfonic acids is greatly reduced due to the presence of inorganic salts. It has now been found that it can be caused by a mixture of liquid acids. sulfonates with porous nip materials. with diatomaceous earth, animal carbon and the like to obtain products in the form of powders, which in action are much better than the salts of sulfonic acids, used for splitting fats, and even sometimes significantly exceed sulfonic acids, It also turned out that these new agents break down fats into fatty acids and glycerin almost completely without the dark colouration that is usually formed when splitting fats in a known way. Therefore, when using new means for splitting fats, the axis There was a positive effect. Of course, it is also possible to convert non-crystalline salts and derivatives of sulfonic acids into more valuable products by mixing with porous materials. Example. 1000 kg of a half-hive beef sack with the day of cleaning1 by adding an appropriate amount of water and reticulate acid, is boiled after mixing with 15 kg of the agent, obtained by mixing 1 part of Twitchell's reagent and 1.5 parts of soil silicon. As soon as 12 hours have elapsed, the splitting has reached 90% and can be brought to 100% by pouring off the water layer and extending cooking for several hours. The obtained fatty acids have an extremely light color. Instead of the agent given, other aromatic-fatty sulfonic acids, sulfonic acids from mineral oils or sulfonic acids, suitable for splitting fats according to German patents, can be used with the same effect. 65987 IV 23d, R. 58507 IV 23d and R. 59740 IV 23d, Diatomaceous earth can also be replaced by bleach earth, activated carbon or the like. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL4742B1 true PL4742B1 (en) | 1926-06-30 |
Family
ID=
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| PL4742B1 (en) | Oil-splitting agent. | |
| GB490285A (en) | Manufacture of washing agents | |
| GB315205A (en) | Improvements in the manufacture and production of light bricks | |
| DE494507C (en) | Process for the preparation of carbazole-N-sulfonic acid and pure carbazole | |
| PL7449B1 (en) | A method of sulfonating fatty acids and their esters. | |
| SU61318A1 (en) | Fat Splitting Method | |
| PL13855B3 (en) | Method of obtaining condensation products of aldehydes and phenols | |
| PL4336B1 (en) | Method for obtaining o-oxyase dyes. | |
| SU1614913A1 (en) | Lubricant for metal moulds | |
| PL14743B1 (en) | The method obtained double-substituted tetrazoles. | |
| PL26907B1 (en) | Method for the preparation of oil-soluble bismuth salts. | |
| DE657724C (en) | Process for the nucleus alkylation of polyhydric phenols | |
| AT87715B (en) | Process for tanning animal hides. | |
| PL15588B1 (en) | Method for the preparation of 2, 2, 5, 5-tetramethyl-3-pyrroline-carbon N-diethyl amide. | |
| DE601896C (en) | Process for the sulfonation of N-substituted 2-pyridones | |
| PL19027B1 (en) | Method for the production of organic sulfuric acid derivatives. | |
| CH139067A (en) | Process for the preparation of a sulfur-containing compound. | |
| PL125289B2 (en) | Method of manufacture of soap from fat waste,especially refining residues from manufacture of margarine | |
| PL14164B3 (en) | A method of obtaining an anthracene series vat dye, stable to the action of chlorine. | |
| CH180581A (en) | Process for the preparation of a new sulfonic acid. | |
| PL27239B3 (en) | A method of separating valuable ingredients from tobacco ground. | |
| CH162735A (en) | Process for the preparation of a sulfonic chloride. | |
| CH164730A (en) | Process for the preparation of a new sulfonic acid. | |
| CH185532A (en) | Process for preparing an aromatic compound containing selenium, nitrogen and sulfur. | |
| CH128995A (en) | Process for the preparation of 2-oxynaphthalene-3-sulfo-6-carboxylic acid. |