PL5927B3 - The method of obtaining sulfur from calcareous sulphates. - Google Patents
The method of obtaining sulfur from calcareous sulphates. Download PDFInfo
- Publication number
- PL5927B3 PL5927B3 PL5927A PL592726A PL5927B3 PL 5927 B3 PL5927 B3 PL 5927B3 PL 5927 A PL5927 A PL 5927A PL 592726 A PL592726 A PL 592726A PL 5927 B3 PL5927 B3 PL 5927B3
- Authority
- PL
- Poland
- Prior art keywords
- alkali
- sulphates
- chlorides
- sulfur
- alloy
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 4
- 239000011593 sulfur Substances 0.000 title claims description 4
- 229910052717 sulfur Inorganic materials 0.000 title claims description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 title claims description 4
- 239000003513 alkali Substances 0.000 claims description 12
- 239000000956 alloy Substances 0.000 claims description 9
- 229910045601 alloy Inorganic materials 0.000 claims description 9
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 7
- 150000001805 chlorine compounds Chemical class 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 4
- 239000000571 coke Substances 0.000 claims description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000000155 melt Substances 0.000 claims 1
- 150000003464 sulfur compounds Chemical class 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 4
- 239000001110 calcium chloride Substances 0.000 description 4
- 229910001628 calcium chloride Inorganic materials 0.000 description 4
- AGVJBLHVMNHENQ-UHFFFAOYSA-N Calcium sulfide Chemical class [S-2].[Ca+2] AGVJBLHVMNHENQ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000723353 Chrysanthemum Species 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- ATYBXAXBLUWREP-UHFFFAOYSA-N calcium oxygen(2-) hydrochloride Chemical class [O--].Cl.[Ca++] ATYBXAXBLUWREP-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Description
Najdluzszy czas trwania patentu do 24 wrzesnia 1941 r.Wynalazek dotyczy dalszego rozwi¬ niecia opisanego w patencie Nr 5 926 spo¬ sobu otrzymywania siarki z siarczanów wapiniowców, przyozem produkt surowy rozpuszcza sie w stopionym chlorku sodo¬ wym i pr-zeiz dodanie koksu otrzymuje sie siarczek wapniowca.Wedlug niniejszego wynalazku do sto¬ pu chlorku alkalicznego i siarczanu wap¬ niowca, przed albo po redukcji koksem, do¬ daje sie chlorku magneziu dla ulatwienia przemiany siarczków waJpniowców na chlor¬ ki alkaliczne.Chlorek magnezu stosowano dotychczas do otrzymywania ^siarkowodoru na drodze mokrej'1,. Jednakze ten ispoisób jesit koiszitloW- ny i prowadzi dio zanieczyszczenia wód od¬ plywowych, Wedlug niniejszego wynalaz¬ ku dodaje sie prawie odwodnionego chlor¬ ku magnezu do zawierajacego zredukowa¬ ne siarczany stopu alkalicznego, Wydziela¬ ja sie wtedy duze ilosci isiarkowodoru, jed-lioozesnie odlacza sie tlenek magnezu, przy- czem z nierozpuszczalnych w stopie siarcz¬ ków wapniowców tworza sie chlorki wap¬ niowców latwo roz|pulszc;zialne w stopionych chlorkach alkaljów, Wywiazytwainie sie siar¬ kowodoru mozna zwieikszyc i ulatwic przez wprioiwaidlzanie) ten sposób otrzymuje sie bardzo szybko wolry od siarczków wapniowców stop lek^ ko plynny, skladajacy sie z chlorków alkal- jów i wapniowtówu W stopie tyim tlenek magnezu szybko sie osadtea tak, ze Latwo go mozna usunac.Jezeli stop chlorków alka!j ów i wap¬ niowców uwolniony od magnezji i zawiera¬ jacy jeszcze w nadmiarze koks, zastosowac do ponownego rozpuszczania i redukcji siatnczanów wiajpniowiców, to: l-o mozna prowadzic prace w sposób ciagly, 2-o usu¬ nac wady zwiazane z praca ma drodze mo¬ krej, a mianolwicie: koszitowne otrzymywa¬ nie ichilorków alkalicznych przez odparowy¬ wanie i zanieczyszczanie stopu przez lugi pokrystaliczne.Skutkiem tego, ze magnezje stale od¬ dziela sie przez osadzanie ia tworzacy isie chlorek wapniowca stale wprowadza sie w obieg kolowy,, otrzymiuje sie ostatedzniie czysty zawierajacy tylko chlorki alkaliczi- ne stop chlorków wapniowców, którego o- trzymiywanie jest bardzo proste i nie pozwa¬ la na powstawaniie lugów pokrystaliicznych zanieczysizczajacych stop. PLThe longest term of the patent until September 24, 1941. The invention relates to a further development of the method of obtaining sulfur from calcareous sulphates described in the patent No. 5,926, with the addition of the raw product dissolved in molten sodium chloride and the addition of coke is obtained According to the present invention, magnesium chloride is added to the concentration of alkali chloride and calcium sulfate before or after reduction with coke to facilitate the conversion of alkaline sulfides to alkali chlorides. Magnesium chloride has heretofore been used to obtain hydrogen sulfide on wet road'1. However, this is a kind of siliticide and leads to the contamination of wastewater. According to the present invention, almost dehydrated magnesium chloride is added to the alkali alloy containing reduced sulfate. Large amounts of hydrogen sulphide are then released, the magnesium oxide is detached, and the calcium chloride is easily formed from the non-soluble calcium sulphides; it is easy to dissolve in the molten alkali chlorides, the formation of hydrogen sulphide can be increased and facilitated by injection) this method is obtained very quickly volatile from calcium sulphides, a slightly liquid alloy, consisting of alkali and calcium oxide chlorides In this alloy, the magnesium oxide is quickly deposited so that it can be easily removed. If the alloy of alkali and calcium chloride is free from magnesia and containing coke in excess, to be used to redissolve and reduce the retinates of chrysanthemums, then: work can be carried out continuously, 2-o remove the disadvantages related to the work in a wet way, namely: expensive preparation of alkali silides by evaporation and contamination of the alloy by post-crystalline liquors. As a result, the magnesia is constantly separated by sedimentation, and the calcium chloride which forms and forms are continuously circulated, and a pure calcium chloride alloy containing only alkali chlorides is obtained, which is very easy to clean and does not allow the formation of post-crystalline loams contaminating the alloys. PL
Claims (2)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL5927B3 true PL5927B3 (en) | 1926-10-30 |
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