PL6046B1 - The method of cleaning crude earth oils and other products. - Google Patents

The method of cleaning crude earth oils and other products. Download PDF

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PL6046B1
PL6046B1 PL6046A PL604624A PL6046B1 PL 6046 B1 PL6046 B1 PL 6046B1 PL 6046 A PL6046 A PL 6046A PL 604624 A PL604624 A PL 604624A PL 6046 B1 PL6046 B1 PL 6046B1
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soap
oil
oils
salt
products
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PL6046A
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Polish (pl)
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Sposób' ocizyisizicizianiiiiai olejów ltiitnenail- nych i tym padiolbnych produktów iziaipomo- ca kwiaistu isnairikotweglo, jak wiiadbma. ma mla celu mozliwe usiumliieoie simloliisityich ciilail oriaiz btajr^wlilacycih (zaniieczyisiziazeii Puzy pioddb- nem oczyszczaniu znaczne ilosci wysoko- iwiaintosctiioiwtych skladniików dlejóiw ulegaja izimiilanioim chemiilczinym ii istamioiwiia odpadlek (tak iziwame smloily kwtaisne). Oddiaiwina wi^c sitailajnla sile znalezc sposób, który mstuwaiby (Wiskaziawe! iZ|aJrrieczysizic!z,eniial ibelz wyiwioly- wiajmia izmaiaziiuych. zmiiani chemiiiaziniyoh aleij nu.Zdlatwlallo siie Uip,, ze ullejpszenie osiaga sie, piodldlajaic aleje u|pnze|dlnii!einu oazysKcizieiniu lugllemii, oelemi odicliajg-njiieciia iz niilcli peiwiniych sulbstainicyj (ikwiaisów nlaftemiowyich i t. dl) i ullatwliieinflia dalsizego praaeisai tfafiWawiajriflla kjwiasem isiialrkawyim. Sposób ten jedtók nie przyjal isffie, plomilewalz asfiaglamy efekt iw istocie okalzyiwtall .sie iSitoJSiumkoiwlo nnewulelitói* Pmzytem wlsizieilkiie lugiowtanne i mycie anilme- nailn&go aleiju czy tb suirofwego, czy oczy- siziazanegp kwtalsieim siarkowymi, jest utrud¬ nione z powodu tworzenia sile emiuilsyj, jak wiiadbmo, przeiszkadizajacyioh w robldcie, a z drujgiej istmony ;z powodu hydlnolliilzy my- dtf.Nilruiejisizy wynalazek uisuiwia wlskaiziairie truidhlasdi lugowalnlija i ipmziefmyiwtaruila ¦ pnztez zabasowanie zasadowych sulbstaiucyij iz db- dlatkilem isidlii, iomaiz zwiazków w irodizlalju soli (Salzantige Subsitata) ewentualnie noiztwo- irów tych isdbistanicyj, prszyclzeim wymienio- nie srodki lotczyszczajace dlziiallaija ma aleje iw tlakiieim stezeniu, ze ztelniieczysizczeniia wydlztiiellaja sie \i osilajcHalja.Paizy tym spasidblile nastejpujie baftidzo iStpiraiwne oczyisizczianfe, porialefwiaz apendiaklaczlkcjfwaity, aiz dlo sizlaimiisitego, z duza za- "* watloscia my^ilta^pslaid, w którymi sa zebrane v catóino ^b^Hviiioirte obojetne sybsitamicje, zaiwairte w oleju. Usunleciie mydel wedlug obecnych sposobów (pirizefnfyiwattiiie woda) jest czesto zmudne, niezupelnie i' polaczbnle ¦z duiemi stnaitamli oleju, tymazalsjetm wedlug nowej metody oczyszczania, podczas, jedine- gó zafoilegu wydziela sie ptraiwiie calai ilosc mtydla. Olej iponiad isizlaimfetym osiadem Ba¬ wienia jesizcze dlriobine ilosci sriodków ioazy- sizezajacycih i pewiilen madlmiiar wolnych al¬ kalj ów, któme usuwa sie latwo woda, pnzy- czem móe ziauiwiazono tiworizieriila sie emulsji!, co dciwodziil, ze w itietn sipiasób traktowany olej wdailie albo iprdiwiie wicalie niile z-awiera mydla. Ponadto przemywalnie jest woigóle zbyteczne, wyistatfczia Siiltrowialnlie lub odsitan nie sie w spokoju.Olej, izaiwaJrty w, sizlialmilsitym icnaadlzole, mozna atiizymiaic prziez odlwiitfoiwlanie lub w inny sposóH Równiez osiadle zaniecizy- sizicizenia mjotznia zaipomiolca 'odwirowania od¬ dzielic idd calej ilosci oleju. Srodki che- milczne anpga byc dodajwlane w kolejnosci dowolniej. Mozna np/tfafiinoiwac lugiem, tuai- sitepniie dodlaiwac roztwory soli albo tez sole uzyc ralzem z alkaljlaimlii, lub sitnajaoine pirzfeiz sole prodiukty rafinowac alkaljami." Tego jfadteiajiii] ocizysKcizenliie cisiaga sie prizefz dzialanlie róznego rrodziaiju solami ewentualnie izjwiiazkanii w rodzaju soli, j cuikmzjamiajmi lub fenoliami,. SizcizeigóMie na¬ dlacja istie isiolle kwiaisóiw iccgainicznych, j.ak nip. kwiasu benizioesiofwegio; prócz tego iwisikaiziac ^mbzna, dlla przykladu sole kwasu octowego, etyjlo-sdarkowego, kwasu ftalowego, sulfani- lowego, nieta-anilowego, niaftailAnoisulfono- wlegja, naftiiomowego i t, dv Mozna równiez zialsitosoiwac sole mieorgiai- nitame, np. chlorek sodowy, siarczan sodo- wy, fosforan sodowy lub odipowiledlnlie sole potasioiwe i miaglneizowe.Jezeli stracenie produkty wlcale nie raa- wiienaja, lub tziawiiejriaja niewielkie ilosci substancyj, tworzacych mydla), dodaje sie odpowiednie kwasy: nafitiioniowy lub inne suibsitajncje, tworzace iz iziasiadamii mydlla, jiak tluiste oleje albo mydla goboiwe np. monio- polowie- Dziala sie prizytem naprziemfiian mydlem al sola.Ilosc i stezenie noztworóiw istoto.1 reguluje sie wedlug wlasnosci uzytej substancji, któne daja sie okreslic przez wjstepne ipró- by.Stosujac dió oazysizctzaniia mydla, ejwen- tuailnie sufesltiainicje (tworzace mydla, mozna oibyc -slie bez isoli, jezeli uzyje siile alkailjów w takiej ilosci ii stezeniu, zie (prtzy wisjpól- dzliialanjiu mydel) tnasitepaje wydztólenJile eWentuailniiei sitracenie osadiu zamieczy- szicfzen. Otrzymuje siie prizyteim olej, pcizba- wiiiony ciemnych substancyj.W ipnaktyoe uzywa siie wiieklsizjyich ilosci alkaljciw isiillnile ^tezicinycli. Alkaljia dodaje sie po traktowaniu myldllem, leicz cala ilosc lub czesc ich mozinJa sitoisiowac tlez riazem z mydlem. iPir,zykla|d I, 1 kg dtesitylaitu suncwego oleju minieirialnego (oleju tuiiibiimoiwegoi) w;sitrz|ajsia siie siillniie pnzy 25—30°C :z 40 cm3 25% ^go wiodbego roztworu fcienzoesanu so- doweigo', nasiteipnie, stale mieszajac, dodaje isde sitqpliuio|wo w mialyoh dalwkach 20 cm3 wodlnJego kugu sodowegio (38 Be), miesza sie jeisizcze w ciagu lOdiu minut ii w ciagu dnia zositaiwiiia w sipekoju. Brumatny oisiad sciaga siie, a clleij pozbawiony alkaljów przemywia i klaruje.Przyklad II. 1 kjg destylatu surowego oleju mlinerialnego (olej tirlansformiatorów) rafinuje sie w temperaturze pokojowej w zwykly siposób piecio ipriccentowa ilioiscia kwaisu siarkowego o cilezianze wlasciwym 1,84. Olej odldlzielony od uzytego do oczy- azezjania kwasu, traktuje sie najprzód 10 cm3 wodnego lugu sodowego (38Be) nasteipniie miesiza sie dobmze z 60 cm3 25%-ego roz¬ tworu wiodlneigd benzioesianu siodowegio, wresizcie, sitale miesizajac, dodiaje mialiemii porcjami 60 cm3 wodnego lugu sodowego ^38 Be) i: wsitnzasa w ciagu 10 mitiui Mie- — Z —szainimie pozostawila sile iw! cSagiu dlnliai w spo¬ koju, odciaga pozloistaly sizlaJm, prizemywia olej i klaruje- Paizryitóiajd! IIL 1 k|g destylatu mineral¬ nego surowego oleiju (turbitaolwtego) mileszai sie pnziy 25°—30°C z 10 g lewiasu n^Ltiionio^ wqgo, dodaje, sillmiie wstrzasajjac, 10 cm3 25%-ego wodnego irozitworu benlzoesianu so¬ dowego, nafsitepnie, wisitazasajac dtaJleij, w malych porcjach 10 om3 wtodhego lugu isio- dow^go (38 Be), miiesizainiitae wistanzasia sie kolo 10 minut i pozostawila! W ciagli 1 dlnliiaj w spokoju. Bnuiriattiny 'Olsiatd usuwa isiiie, a uwolniony od ailkaljów oliej przemywia i klaruje* Przyklad IV. Do 100 kg destylatu de¬ ju mineralnego diodaje sie iw teimipieriaturze pokojowej 10 kg 10%-ego sliilnlie alkafcz- nego roztworu mydfoi monopolowego i, mie- Sizajac istale, dodalje sie 10,1 on3 widnego lugu sodowego (39 Be)i( Dla wyraznego od- dzifeileniia warstw, wllewa sie 5—10 1 wody i po zimliiesizamiu pozostawila w sipokioju, pnzyczem ma spodzie izibiieral sile czysty lug, w srodku ziainieczysizczeniia, a w górnej wlajrstwte oczyszczony olej, który przemy¬ wa sie dla usuniecia wolnych alkaljów i mydel. Uzyte odtazynmilkr znainym spplsiolbem moiga ibyc jzire^emiettioiwiajne. Dq itWcmziemGa mydel nadlaja sie wszellkiie suhstanclje, któ¬ re w ziaizmaczonych warunkach wytwarzaja mydla, np. oleje tluste* Wytnialiaizek mozmia na)tuinalnlile zasftoso- wac i do takich produktów, które byly uprzednio olazysizczone linnemii sposobami, np- byly traktowialne ziemia bielaca- Jalko materjialy isuriowe wchodza 'takze w zakres wynailaiztku przetwory olejów izSlenuuych — wegla bruttuatnegoUi ptizemyislu parajfómiowie- go. PLThe method of "ocizyisizicizianiiiiai" fatty oils, and including the dry products and the aid of flowering isnairikotweglo, such as wiiadbma. It was aimed at possible usiumliieoie simloliisityich ciilail oriaiz btajr ^ wlilacycih (wandering the poisons with the purification of considerable amounts of high-iiaintoscti-oivic components of the dleja and succumbing to and weakening the chemiilchinous cords, Wiskaziawe! IZ | aJrrieczysizic! Z, eniial ibelz wywieoly- wiajmia izmaiaziiuych.changing chemiiiaziniyoh aleij nu.Zdlatwlallo si Uip ,, that it is getting better, that you get better, piodlajic aleje u | asnamiinichiislugiiiislugia! (ikwiaisów nlaftemiowyich and t. dL) and ullatwliieinflia dalsizego praaeisai tfafiWawiajriflla kjwiasem isiialrkawyim. this method did not accept jedtók isffie, plomilewalz asfiaglamy effect and indeed okalzyiwtall .sie iSitoJSiumkoiwlo nnewulelitói * Pmzytem wlsizieilkiie lugiowtanne and washing it anilme- nailn & aleiju tb suirofwego or whether it goes without siziazanegp kwtals with sulfur substances, it is difficult due to the formation of the strength of emuils, such as wiiadbmo, transformations in the robldt, and from the second istmony; because of the hydlnolliilzy of my- dtf. iomaiz compounds in irodizlalju salt (Salzantige Subsitata) optionally noiztwo- isdbistanicyj the spin cycle, prszyclzeim wymienio- no measures have lotczyszczajace dlziiallaija alleys and tlakiieim concentration of ztelniieczysizczeniia wydlztiiellaja August \ osilajcHalja.Paizy and the spasidblile nastejpujie baftidzo iStpiraiwne oczyisizczianfe, porialefwiaz apendiaklaczlkcjfwaity, and z dlo sizlaimiisitego, with a great deal of "* doubt my ^ ilta ^ pslaid, in which are collected v catóino ^ b ^ Hviiioirte indifferent sybsitamicje, zaiwairte in oil. Removing the soap according to the current methods (pirizefnfyiwattiiie water) is often tedious, incomplete and combined with a large amount of oil, then I use the new method of cleansing, during the course of the infiltration, the whole amount of breath is released. Oil and oil and faint sediment Fairy still dlriobine the amount of oasis and sizajacych and a certain amount of free alalia, which can be easily removed by water, so that I was aaaaaaaaaaaaaaaaaa user tied up with the emulsion, and that I drank the oil in it! I am already full of soap. In addition, washing facilities are completely redundant, there is no need to drain the filter or sift in peace. Olej, izaiwaJrty in, sizlialmilsitym icnaadlzole, it is possible to atimize with a de-lightening or in some other way. Anpga chemicals should be added in order as desired. You can, for example, tfafiinoinat with lye, tuai-sitepniie add salt solutions or also use salt with alkaline salt, or sitnajaoine pirzfeiz salt prodiucts refined with alkali. " SizcizeigóMie, for example, the salts of acetic acid, ethylalic acid, phthalic acid, sulphanilic acid, non-tartarilic acid, non-tartarilic acid, non-tartaric acid, and other Naphthylomic it, dv You can also whitenize meorginitame salts, e.g. sodium chloride, sodium sulphate, sodium phosphate or deipovilated potassium and muscle salts. If the loss of the products does not brighten up or thawed small amounts of soap substances), the appropriate acids are added: naphthionic or other suibilitants, forming and with the adjuncts amii soaps, jiak greasy oils or gobo soaps, e.g. monio - half - It works with prite, with alcohol al salt. The number and concentration of substances and essence1 are adjusted according to the properties of the substance used, which can be defined by interim and intertwined interactions. soaps, ejven- tailly suffesltiainitje (creating soaps, you can be silky without salt, if you use the strength of alkailjs in such quantity and concentration, the green (more than a half- split the soap) cuts the severity of exhaustion. Jile swells and swells swells. A prizyteim oil is obtained, tanned by dark substances. In the ipnaktyoe, greater amounts of alkali are used and there is an innumerable ^ tezicinycli. Alkaljia are added after the treatment with soap, pour all or part of them, sieve the background with a rose with soap. iPir, zykla | d I, 1 kg of dtesitylaite of minirial oil (thuiiibiimitei oil) w; sieve sifted 25-30 ° C: with 40 cm3 of a 25% sodium phytochemical master solution, stirring constantly, stirring , adds isde sitqpliuio | the water in the small halves of 20 cm3 of water of the sodium kugio (38 Be), still stirred for an ice-cream for two minutes, and during the day it burns in a piss. Brumatny oisiad pulls down, and the alkaline-free clue was washed and clarified. Example II. 1 kilogram of distillate of crude mlinerial oil (oil of tirlessformers) is refined in the usual manner at room temperature with a five percent amount of sulfuric acid with a specific calcium content of 1.84. The oil is separated from the acid used for purification, it is treated first with 10 cm3 of aqueous sodium liquor (38Be). Next month it is good with 60 cm3 of a 25% leading solution, aside from the saddle benzoate, resume, sepals by mixing, add 60 cm3 of water lugu sodowego ^ 38 Be) and: in the course of 10 mitiui Mie- - Z-szainim left strength and in! cSagiu dlnliai at ease, pulls away the golden sizlaJm, prizemywia oil and clarifies- Paizryitóiajd! IIL 1 kg of crude oil (turbitaollin) mineral distillate is rising at 25 ° -30 ° C with 10 g of N-L-thionium leviasis, adding, shaking, 10 cm3 of a 25% aqueous solution of sodium benlzoate , in a great way, hanging down for 10 minutes, in small portions of 10 om3 of the second crude oil (38 Be), the meat started about 10 minutes and left! Stay in peace for 1 longer. Bnuiriattiny 'Olsiatd removes isiiie, and the oil freed from ailkalias washes and clarified * Example IV. To 100 kg of mineral de-sate distillate, 10 kg of a 10% sililinally alkaline solution of monopoly mydfand are diode at room temperature and, while still stirring, 10.1 kg of light sodium liquor (39 Be) and (For clear The layers are removed, 5-10 liters of water are poured and after the wintering is left in the waterhole, the bottom of the lanyard is washed with clean lug, in the middle of whitishness, and in the upper layer, purified oil, which is washed to remove free alkali and soap. The decanitic of a well-known spplsiolb can make and be an emetitic jzire ^. , for example, there were treatable soil of bielac - Jalko materjialy isuriowe are also included in the scope of invented products of izSlenuuych oils - brutal coal Ui ptizem parajfómiowie yislu. PL

Claims (4)

Zastrzezenia patentowe. 1. Sposób oczyszazajniiai tfopy i innych olejów iod sulhsitancyj ciiemino izalhartwfiionych, zttiiamffeniny tlem, ze malterjia/l wyjiscilowy zia- diaje sie mydlem i nadaniaineim ailkjaljów, pirzyozeim mydlo wchlania zabarwione sub¬ stancje ziais nadmllair alkaljów straicia -mydlo wraiz .z izanilecizyszcizetnliiaiml'.Patent claims. 1. The method of cleansing tfopy and other oils and from sulfite and tarnishing, zttiiamffenin with the background that malterjia / l is exiting with soap and giving them ailkjaljs, taking the soap, absorbing the dyed alkalis and hyperglycaemic substances. 2. Odmiana ispoisobu wedlug izias-triz,. 1, w iraziie, ,gdy ropa izawiiiera dlostlajteazma ilosc suibstamcyj, ulegaljacych zmydlltamiu, zinia- mlieinlna temu, ze stosuje sie tylko nadimiar alkaljów, pnzyczem czesc ailkaljów izmydla siuibsitlaincje, ullegajape izmydllfeuniiki, a uitwio- rzdme mydilo irioizp,usziaziai zainfielazysizKazeiniia, zas nadmiilar alkaljów dlzialla ,jak ojpiiisainlo w zaiste 1.2. Variation of ispoisobu according to izias-triz ,. 1, in irritation, when the oil contains long lasting oil, there is a number of suibstones, succumb to saponification, unlike the fact that only an excess of alkalis is used, I shed some of the ailkaljas and the soap for siuibsitlings, the relaxation of the ailments, inflammation of the ailments it continued, as it was indeed in 1. 3. Sipoisób wedlug zastazi. 1, znamien¬ ny tem, ze ziaftnilast gotowych mydel stosu¬ je isie matlerjaly dajace sie zimydllac, np. kwasy nlaftemlowe, tworzace mydla z czesdia alikafljów, pmzyazem resizita, t. j. nadblilar ailkallljów, diziiiaila jak opisano w zastirizi. 1.3. Sipoisób according to the substitutes. According to claim 1, characterized in that the refined soaps are used and they are matlerials that can be dimpled, e.g. 1. 4. - Sposób wedlug izaistlnz- 1, 2 l 3, /zna¬ mienny tetai, ze dla spotegowania cczy- szczanila stosuje sie dddaltek soli1 lub sub- staincyj w rodizaju sioli. Fritz Schwarz. Zastepca: I. Myszczynslki, rzecznik patentowy Dl-ak L. Boguslawskiego, Warszawa. PL4. - The method according to the present-1, 2 l 3, / the characteristic tetai that in order to intensify the cysteine salt 1 or a substance in a kind of salt is used. Fritz Schwarz. Deputy: I. Myszczynslki, patent attorney Dl-ak L. Boguslawski, Warsaw. PL
PL6046A 1924-05-10 The method of cleaning crude earth oils and other products. PL6046B1 (en)

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