PL7060B1 - The method of obtaining ice paints. - Google Patents
The method of obtaining ice paints. Download PDFInfo
- Publication number
- PL7060B1 PL7060B1 PL7060A PL706026A PL7060B1 PL 7060 B1 PL7060 B1 PL 7060B1 PL 7060 A PL7060 A PL 7060A PL 706026 A PL706026 A PL 706026A PL 7060 B1 PL7060 B1 PL 7060B1
- Authority
- PL
- Poland
- Prior art keywords
- paints
- obtaining ice
- chlorine
- solution
- oxy
- Prior art date
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- 238000000034 method Methods 0.000 title claims description 4
- 239000003973 paint Substances 0.000 title claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims 1
- 241000219146 Gossypium Species 0.000 claims 1
- -1 sulfonate diazo compounds Chemical class 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000009835 boiling Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 3
- HKOOXMFOFWEVGF-UHFFFAOYSA-N phenylhydrazine Chemical compound NNC1=CC=CC=C1 HKOOXMFOFWEVGF-UHFFFAOYSA-N 0.000 description 3
- NIPDVSLAMPAWTP-UHFFFAOYSA-N 2-methoxy-5-nitroaniline Chemical compound COC1=CC=C([N+]([O-])=O)C=C1N NIPDVSLAMPAWTP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 229940067157 phenylhydrazine Drugs 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- XTTIQGSLJBWVIV-UHFFFAOYSA-N 2-methyl-4-nitroaniline Chemical compound CC1=CC([N+]([O-])=O)=CC=C1N XTTIQGSLJBWVIV-UHFFFAOYSA-N 0.000 description 1
- XJCVRTZCHMZPBD-UHFFFAOYSA-N 3-nitroaniline Chemical compound NC1=CC=CC([N+]([O-])=O)=C1 XJCVRTZCHMZPBD-UHFFFAOYSA-N 0.000 description 1
- IIAKWFQNRUWEME-UHFFFAOYSA-N 4-methoxy-1-nitrocyclohexa-2,4-dien-1-amine Chemical compound COC1=CCC(N)([N+]([O-])=O)C=C1 IIAKWFQNRUWEME-UHFFFAOYSA-N 0.000 description 1
- VVPHSMHEYVOVLH-UHFFFAOYSA-N 6-hydroxynaphthalene-2-sulfonic acid Chemical compound C1=C(S(O)(=O)=O)C=CC2=CC(O)=CC=C21 VVPHSMHEYVOVLH-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- 150000001716 carbazoles Chemical group 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- XFSXWFOXECTCPD-UHFFFAOYSA-N naphthalen-1-ylsulfamic acid Chemical compound C1=CC=C2C(NS(=O)(=O)O)=CC=CC2=C1 XFSXWFOXECTCPD-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- CSABAZBYIWDIDE-UHFFFAOYSA-N sulfino hydrogen sulfite Chemical compound OS(=O)OS(O)=O CSABAZBYIWDIDE-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
v. Wykryto, iz zapomoca oksynaitokarba- zoli i ich homologów na wlóknach udaje sie wytworzyc wedlug metod, stosowanych zwykle przy otrzymywaniu farb lodowych, barwniki trwale. Otrzymuje sie w ten spo¬ sób odcienie od ceglasto czerwonego przez brunatny do czarnego o znacznej odporno¬ sci na pranie, dzialanie chloru i lugu.Oksynaftokarbazole otrzymuje sie w spo¬ sób znany najkorzystniej zapomoca kon¬ densacji hydrazyny z kwasem naftolo-lub naftylosulfonowym w obecnosci dwusiar- czynu (Bucherer J, pr. Ch. t. 81 (1910) str. 25 ff.) i nastepnego stapiania z alkaljami zracemi.Przyklad I, Materjal przepaja sie roz¬ tworem 7-oksy-2./-rnaftokarbazolu otrzyma¬ nego zapomoca kondensacji fenylohydrazy¬ ny i kwasu 1-naftylaminosulfonowego i sta¬ piania, w sposób nastepujacy: OH 5 kg oksynaftokarbazolu, 7.5 kg oleju tureckiego i 7.5—10 kg lugu sodowego 340 Be zarabia sie na zimno i rozpuszcza w 500 1 wody gotowanej; po dodaniu 5 1 al-dehydu mrówkowego 40°/0-cgo zanurza sie w tej mieszaninie materjal.Materjal przepojony, ewentualnie po wysuszeniu, wywoluje sie dwuazowanym roztworem m-nitraniliny; otrzymuje sie czerwien brunatna o bardzo dobrej odpor¬ nosci na gotowanie, dzialanie chloru, swia¬ tla i lugu.Przyklad IL Materjal przepaja sie, jak w przykladzie I, roztworem 7-oksy-2.Jf- naftobromokarbazolu, otrzymanego za- pomoca bromowania, i wywoluje dwuazo- wana 4-nitro-2-anizydyna. Otrzymuje sie czern brunatna o bardzo dobrej odporno¬ sci na gotowanie, dzialanie chloru, swia¬ tla i lugu.Przyklad III. Materjal przepaja sie roztworem 6 - oksy - 12 - naftokarbazolu, otrzymanego z fenylohydrazyny i kwasu 2-naftolo-6 sulfonowego przez stapianie, i wywoluje dwuazowana 4-nitro-2-anizydy- na. Otrzymuje sie czern fioletowa odporna na gotowanie, dzialanie chloru, swiatla i lugu. /\_OH /\ __./\/ ¦ l ! I j Przyklad IV. Materjal przepaja sie roztworem 7-oksy-2,./-nafto-7' metylokar- bazolu. Po wywolaniu dwuazowana 4-ni- tro-2-toluidyna otrzymuje sie piekny kolor bordo, odporny na gotowanie, dzialanie chloru, swiatla i lugu./S /\ Cfl3/lNAraA|/N \/ i OH Przyklad V. Oksynaftokarbazole nada¬ ja sie równiez do druku naftolem, Materjal nasyca sie roztworem zawierajacym w 10 1 240 g 7-oksynaftokarbazolu, 300 g oleju tu¬ reckiego, 380 g lugu sodowego 36° Be, na¬ stepnie suszy i drukuje roztworem p-nitro- o-anizydyny, zageszczonym i zmieszanym z siarczanem glinu.Po wydrukowaniu materjal suszy sie, przemywa, mydli i pierze ostatecznie.Otrzymuje sie bardzo odporna na dziala¬ nie chloru, mydla i swiatla czern brunat¬ na.Zamiast przytoczonych w przykladach powyzszych oksykarbazoli mozna stosowac ich pochodne, które otrzymuje sie z kwasu 1 - naftolo .5-6-7 lub 2- naftolo - 5 - 6-7 sulfonowego lub tez mozna stosowac równiez oksydwunaftokarbazple jako pod¬ stawniki lub karbazole, podstawione w resz¬ cie fenylohydrazynowej. PL PLv. It has been found that with the help of oxynaitocarbazols and their homologs on fibers, it is possible to produce permanent dyes according to the methods usually used in the preparation of ice paints. In this way, shades from brick red through brown to black are obtained, with a high resistance to washing, chlorine and slurry. of disulphite (Bucherer J, pr. Ch. vol. 81 (1910) p. 25 ff.) and subsequent fusion with the alkali of the racially. By means of condensation of phenylhydrazine and 1-naphthylaminosulfonic acid and melting, as follows: OH 5 kg of oxynaphtocarbazole, 7.5 kg of Turkish oil and 7.5-10 kg of sodium liquor 340 Be is cold prepared and dissolved in 500 liters of boiled water; the material is immersed in this mixture after the addition of 5 l of 40 [deg.] al-formic aldehyde. The material is soaked, possibly after drying, with the diazotized m-nitraniline solution; brown red is obtained with very good resistance to boiling, the action of chlorine, light and slurry. Example IL Materjal is permeated, as in example I, with a solution of 7-oxy-2.Jf-naphthobromocarbazole obtained by bromination, and produces diazotized 4-nitro-2-anisidine. A brown black color is obtained with very good resistance to boiling, chlorine, light and slurry. Example III. The material is infiltrated with a solution of 6 - oxy - 12 - naphtocarbazole, obtained from phenylhydrazine and 2-naphthol-6 sulfonic acid by fusion, and produces diazotized 4-nitro-2-anisidine. A violet black is obtained, which is resistant to boiling, chlorine, light and slurry. / \ _ OH / \ __./\/ ¦ l! I j Example IV. The material is permeated with a solution of 7-oxy-2,2 / - naphtho-7 'methylcarbol. After the development of the diazotized 4-nitro-2-toluidine, a beautiful burgundy color is obtained, resistant to boiling, the action of chlorine, light and lug./S / \ Cfl3 / lNAraA | / N \ / and OH. Example V. Oxynaphtocarbazole gives can also be used for printing with naphthol, the material is saturated with a solution containing in 10 1 240 g of 7-oxynaphtocarbazole, 300 g of turkish oil, 380 g of sodium liquor 36 ° Be, then dried and printed with a solution of p-nitro-anisidine, after printing, the material is dried, washed, soaps and washed finally. It is very resistant to chlorine, soap and black light. it is obtained from 1- naphthol. 5-6-7 or 2-naphthol-5- 6-7 sulfonic acid, or it is also possible to use diaphthocarbazole as substituents or carbazoles substituted with a phenylhydrazine residue. PL PL
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Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL7060B1 true PL7060B1 (en) | 1927-04-30 |
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