PL77084B1 - - Google Patents

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Publication number
PL77084B1
PL77084B1 PL1971152212A PL15221271A PL77084B1 PL 77084 B1 PL77084 B1 PL 77084B1 PL 1971152212 A PL1971152212 A PL 1971152212A PL 15221271 A PL15221271 A PL 15221271A PL 77084 B1 PL77084 B1 PL 77084B1
Authority
PL
Poland
Prior art keywords
piston
channel
slide
end position
channels
Prior art date
Application number
PL1971152212A
Other languages
Polish (pl)
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Publication date
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Publication of PL77084B1 publication Critical patent/PL77084B1/pl

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Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01FMEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
    • G01F11/00Apparatus requiring external operation adapted at each repeated and identical operation to measure and separate a predetermined volume of fluid or fluent solid material from a supply or container, without regard to weight, and to deliver it
    • G01F11/10Apparatus requiring external operation adapted at each repeated and identical operation to measure and separate a predetermined volume of fluid or fluent solid material from a supply or container, without regard to weight, and to deliver it with measuring chambers moved during operation
    • G01F11/12Apparatus requiring external operation adapted at each repeated and identical operation to measure and separate a predetermined volume of fluid or fluent solid material from a supply or container, without regard to weight, and to deliver it with measuring chambers moved during operation of the valve type, i.e. the separating being effected by fluid-tight or powder-tight movements
    • G01F11/14Apparatus requiring external operation adapted at each repeated and identical operation to measure and separate a predetermined volume of fluid or fluent solid material from a supply or container, without regard to weight, and to deliver it with measuring chambers moved during operation of the valve type, i.e. the separating being effected by fluid-tight or powder-tight movements wherein the measuring chamber reciprocates
    • G01F11/18Apparatus requiring external operation adapted at each repeated and identical operation to measure and separate a predetermined volume of fluid or fluent solid material from a supply or container, without regard to weight, and to deliver it with measuring chambers moved during operation of the valve type, i.e. the separating being effected by fluid-tight or powder-tight movements wherein the measuring chamber reciprocates for fluent solid material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/002Feeding of the particles in the reactor; Evacuation of the particles out of the reactor with a moving instrument
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B1/00Packaging fluent solid material, e.g. powders, granular or loose fibrous material, loose masses of small articles, in individual containers or receptacles, e.g. bags, sacks, boxes, cartons, cans, or jars
    • B65B1/30Devices or methods for controlling or determining the quantity or quality or the material fed or filled
    • B65B1/36Devices or methods for controlling or determining the quantity or quality or the material fed or filled by volumetric devices or methods
    • B65B1/38Devices or methods for controlling or determining the quantity or quality or the material fed or filled by volumetric devices or methods by pistons co-operating with measuring chambers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65GTRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G53/00Conveying materials in bulk through troughs, pipes or tubes by floating the materials or by flow of gas, liquid or foam
    • B65G53/34Details
    • B65G53/40Feeding or discharging devices
    • B65G53/46Gates or sluices, e.g. rotary wheels
    • B65G53/4683Gates or sluices, e.g. rotary wheels with a reciprocating mover acting directly on material

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • General Physics & Mathematics (AREA)
  • Quality & Reliability (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
  • Basic Packing Technique (AREA)
  • Filling Or Emptying Of Bunkers, Hoppers, And Tanks (AREA)

Description

Uprawniony z patentu: Farbwerke Hoechst Aktiengesellschaft vormals Meister Lucius & Bruning, Frankfurt/Main (Re¬ publika Federalna Niemiec) Dozownik do proszków Przedmiotem wynalazku jest dozownik z poje¬ mnikiem dozowanego materialu, podajnikiem i oprózniaczem, przeznaczony do wolumetrycznego dozowania w malych dawkach zachowujacych sie jak plyn proszków, podawanych do przestrzeni ga¬ zowej, wykazujacej nadcisnienie w stosunku do atmosfery.Znane jest urzadzenie do wolumetrycznego do¬ zowania w malych dawkach sproszkowanych cial stalych, któremu przyporzadkowany jest zbiornik dla dozowanego materialu oraz podajnik. Zbiornik taki jest przewaznie otwarty od góry, zas podajni¬ kiem jest slimak, talerzyk lub walec z komórkami.Dawki podawanego materialu okreslane sa za po¬ moca podajnika lub podlaczonego naczynia mierni¬ czego. Przy kilku znanych dozownikach, na przy¬ klad przy wagach ze zbiornikiem bebnowym obro¬ towym,, do dozowania kleistych materialów stoso¬ wano równiez mechaniczne oprózniacze do oczy¬ szczania cylindrycznych naczyn mierniczych.Znane najczesciej urzadzenia moga byc uszczel¬ nione od zapylania za pomoca odpowiednich okap- turzen. Wada tych znanych urzadzen jest to, ze nawet w urzadzeniach okapturzonych trudne jest przeprowadzac dozowanie do przestrzeni bedacej pod cisnieniem, poniewaz juz nieznaczne cisnienie gazu przebija sie przez urzadzenia podajace i mier- - nicze, w wyniku czego jeszcze bardziej utrudnione jest wolumetryczne dozowanie zachowujacych sie 10 15 25 80 2 jak plyn proszków, które jest obarczone i tak wieksza tolerancja bledów.Znane urzadzenia zawodza zupelnie, gdy maja pracowac przeciw znacznym cisnieniom gazu, a mianowicie nadcisnieniem wynoszacym 5—50 atn.Zadaniem wynalazku jest wyeliminowanie tych wad, a zwlaszcza opracowanie takiego dozownika, przy którym unikie sie przebicia cisnienia gazu do podajnika i zbiornika z dozowanym materialem.W celu rozwiazania tego zadania zastosowano do¬ zownik z pojemnikiem dozowanego materialu, po¬ dajnikiem i oprózniaczem charakteryzujacy sie tym, ze podajnik stanowi przewezenie pionowego suwa¬ ka tloczkowego, które przy górnym krancowym po¬ lozeniu suwaka wchodzi do pojemnika dozowane¬ go materialu, a przy dolnym krancowym polozeniu suwaka do zbiornika zderzakowego, oraz tym, ze dolny koniec suwaka tloczkowego prowadzony jest szczelnie w kanale, który polaczony jest z kanalem prowadzacym tloczka oprózniajacego oraz tym, ze tloczek oprózniajacy w swym krancowym poloze¬ niu wypelnia przynalezny do niego kanal prowa¬ dzacy, a w drugim swym krancowym polozeniu tworzy polaczenie z przestrzenia gazowa, laczy ze soba obydwa kanaly prowadzace i odslania przy¬ lacze swojego kanalu prowadzacego do urzadzenia wydmuchowego.Przedmiot wynalazku uwidoczniony jest w przy¬ kladzie wykonania na rysunku, na którym fig. 1 77 0843 przedstawia przekrój wzdluzny dozownika, a fig. 2 — jego przekrój czesciowy.Podajnik znajduje sie w przewezeniu 1 pionowe¬ go suwaka tloczkowego 2. Na fig. 1 przedstawiono suwak tloczkowy 2 w jego dolnym krancowym po- 5 lozeniu, przy czym w polozeniu tym przewezenie 1 wchodzi do zderzakowego zbiornika 4. W górnym krancowym polozeniu suwaka tloczkowego przewe¬ zenie wchodzi do pojemnika 3 dozowanego mate¬ rialu. Dolny koniec suwaka tloczkowego 2 prowa- 10 dzony jest szczelnie w kanale 5. Czesc tego kanalu jest widoczna na fig. 2, a na fig. 1 kanal ten jest zakryty dolnym koncem tloczka 2. Kanal 5 jest polaczony z prowadzacym kanalem 6 oprózniajace¬ go tloczka 7, wedlug fig. 2. W dolnym krancowym 15 polozeniu oprózniajacego tloczka 7, kanal 6 jest tym tloczkiem wypelniony, co uwidocznione jest na fig. 1. W drugim krancowym polozeniu opróz¬ niajacego tloczka 7 prowadzacy kanal 6 otwiera sie przez przylacze 8 w kierunku przestrzeni ga- 20 zowej w wyniku czego odslania sie wlot prowa¬ dzacego kanalu 5 do kanalu 6, oraz przylacza 9 do urzadzenia wydmuchowego, które nie jest uwi¬ docznione na rysunku. Urzadzenie wydmuchowe stanowi zbiornik sprezonego gazu lub system ru- 25 rek, polaczony przez zawór 15 z przylaczem 9.Sterowanie tloczków moze sie odbywac w znany ogólnie sposób za pomoca ukladu dzwigni i tarczy programowej, lub korzystniej za pomoca urzadzen pneumatycznych. Na fig. 1 widoczne sa pneuma- 30 tyczne sterujace cylindry 10 i 11, które polaczone sa za pomoca trójdrogowych zaworów 16 z nie- uwidocznionym na rysunku zródlem sprezonego gazu. Otwieranie i zamykanie zaworów odbywa sie w znany sposób za pomoca elektrycznych urza- 35 dzen pomocniczych, jak na przyklad wlacznika programowego.W celu poprawienia uszczelnienia przesuwnych tloczków w kanalach 5 i 6 umieszczone sa dlawni- ce 12 z przewidzianymi przy nich kanalami od- 40 sysajacymi. Korzystnym przypadkiem szczególnie jest to, gdy dozowany proszek jest katalizatorem, który w przestrzeni gazowej podlaczonego reakto¬ ra ma uproscic lub przyspieszyc reakcje. W tym przypadku nawet bardzo male ilosci gazu, które 45 przedostaja sie do zbiornika zderzakowego wsku¬ tek nieszczelnosci prowadzenia tloczka lub dlawnic, moglyby prowadzic do zlej pracy urzadzenia. Dzie¬ ki kanalom odciagajacym, które przez zawory 17 i 18 podlaczone sa do znanego urzadzenia próznio- 50 wego, zapobiega sie prostym sposobem przenika¬ niu gazowych skladników reakcji do zderzakowego zbiornika 4 i pojemnika 3 dozowanego materialu.Przylacze 9 w prowadzacym kanale 6 w zaleznosci od polozenia przyporzadkowanych zaworów 15 i 18 55 moze równiez spelniac funkcje kanalu odsysaja¬ cego.Dla wyjasnienia sposobu dzialania punktem wyj¬ scia jest przedstawione na fig. 1 polozenie tloczko¬ wego suwaka 2 i oprózniajacego tloczka 7. W fa- «o zie tej zawór 18 jest otwarty, a zawory 15 i 17 sa zamkniete. W zderzakowym zbiorniku 4 znajdu¬ je sie sproszkowany katalizator w ilosci, która od¬ powiada pojemnosci przewezenia 1 tloczkowego su¬ waka 2. Pojemnik 3 dozowanego materialu jest co *5 4 najmniej czesciowo napelniony sproszkowanym ka¬ talizatorem oraz azotem z przewodu 19.Podczas pracy dozownika, utrzymywane jest wspóldzialanie tloczków i zaworów, w sposób taki tloczkowy suwak 2 zostaje cofniety do górnego krancowego polozenia. Dzieki temu zostaje osiag¬ niete przewezenie 1 tak dalece, ze wejdzie do po¬ jemnika 3 dozowanego materialu,, zeby moglo na¬ pelniac sie proszkiem. W polozeniu tym zderzako¬ wy zbiornik 4 wydala swa zawartosc do kanalu prowadzacego 5 suwaka tloczkowego 2. Teraz tlo¬ czek cofa sie w kierunku polozenia podstawowego, zatrzymuje sie jednak w pokazanym na fig. 2 polozeniu posrednim, zeby nie sprasowac w kanale 5 proszku. Zabrany przewezeniem proszek nie mo¬ ze teraz wpadac do zbiornika zderzakowego.W fazie nastepnej otwieraja sie zawory 17 i 15, zawór 18 zamyka sie i tloczek oprózniajacy 7 wra¬ ca do polozenia widocznego na fig. 2. Pod cisnie¬ niem, które jest o kilka atmosfer wyzsze w sto¬ sunku do cisnienia w przestrzeni gazowej, gazowy skladnik reakcji lub obojetny dla reakcji gaz prze¬ chodzi przez otwarty zawór 15 do zwolnionej cze¬ sci prowadzacych kanalów 6 i 5, przy czym podany tu i znajdujacy sie w kanalach proszek zostaje przez przylacze 8 wdmuchniety do przestrzeni ga¬ zowej. Cofajac sie kolejno do polozenia poczatko¬ wego tloczkowy suwak 2 i oprózniajacy tloczek 7 wypieraja z kanalów znajdujace sie tam ewentual¬ nie resztki proszku. Nastepnie zamyka sie zawór 15, a otwiera zawór 18.W ten sposób osiagniete zostaje ponownie polo¬ zenie wyjsciowe. Wspóldzialanie tloczków i zawo¬ rów jest w sposób regulowany powtarzane. Z przedstawionego sposobu dzialania mozna zauwa¬ zyc, ze tloczek oprózniajacy 7 poza funkcja opróz¬ niania, spelnia równiez role elementu zamykajace¬ go. W przypadku,, gdy nie ma obaw co do zacho¬ dzacych reakcji proszku lub inicjowania reakcji przez proszek, mozna zrezygnowac z odsysania za dlawnicami. PL PLThe right holder of the patent: Farbwerke Hoechst Aktiengesellschaft vormals Meister Lucius & Bruning, Frankfurt / Main (Federal Republic of Germany) Powder dispenser The subject of the invention is a dispenser with a container for dosed material, a feeder and an emptying device, intended for volumetric dosing in small doses that maintain A device for volumetric dosing in small doses of powdered solids, which is assigned to a container for the dosed material and a feeder, is known as a liquid of powders fed into a gas space, showing an overpressure in relation to the atmosphere. Such a tank is usually open at the top, and the feeder is a screw, plate or roller with cells. The material feed rates are determined by the feeder or connected measuring vessel. In several known dispensers, for example scales with a rotary drum, for dispensing sticky materials, mechanical drainers were also used to clean cylindrical measuring vessels. The most common devices can be sealed against pollination with appropriate hood. The disadvantage of these known devices is that even in hooded devices it is difficult to carry out the dosing into the pressurized space, since a slight gas pressure already penetrates the feeding and measuring devices, with the result that volumetric dosing of the behaving behaves even more difficult. 15 25 80 2 as a liquid of powders, which is burdened with a greater tolerance of errors. Known devices fail completely when they are supposed to work against significant gas pressures, namely an overpressure of 5-50 atm. The task of the invention is to eliminate these drawbacks, and in particular to develop such a dispenser, which avoids gas pressure breakthrough to the feeder and the container with the dosed material. In order to solve this task, a dispenser with a dosed material container, a feeder and an emptying device was used, characterized by the fact that the feeder is a passage of the vertical piston slide which at the upper end position of the slider w it goes to the dispensing material container, and at the lower end position of the slider to the buffer tank, and that the lower end of the piston slide is guided tightly in a channel which is connected to the guide channel of the discharge piston and with the discharge piston in its terminal position. It fills the associated guide channel, and in its second end position it forms a connection with the gas space, connects both guide channels with each other and exposes the connection of its guide channel to the exhaust device. The subject of the invention is illustrated in the example of the embodiment in Fig. 1 77 0843 shows a longitudinal section of the dispenser, and Fig. 2 shows a partial section. 5 folded, where in this position the passage 1 enters the buffer tank 4. In the upper end position at the piston slide, the passage enters the container 3 of the material to be dispensed. The lower end of the piston slide 2 is guided tightly in the channel 5. A part of this channel is shown in Fig. 2, and in Fig. 1 this channel is covered by the lower end of the piston 2. The channel 5 is connected to the leading emptying channel 6. of the piston 7, according to Fig. 2. In the lower end position 15 of the emptying piston 7, the channel 6 is filled with this piston, as shown in Fig. 1. In the second end position of the emptying piston 7, the guiding channel 6 opens through the connection 8 in towards the gas space 20, thereby exposing the inlet of the lead channel 5 to the channel 6, and the connection 9 to the exhaust device, which is not shown in the drawing. The blowing device is a compressed gas tank or pipe system connected via a valve 15 to a connection 9. The pistons can be controlled in a generally known manner by means of a lever arrangement and a program dial, or more preferably by means of pneumatic devices. 1 shows the pneumatic control cylinders 10 and 11 which are connected by means of three-way valves 16 to a source of compressed gas not shown. The valves are opened and closed in a known manner by means of electric auxiliaries, such as, for example, a software switch. In order to improve the sealing of the sliding pistons in the channels 5 and 6, glands 12 with suction channels are provided alongside them. . A preferred case is, in particular, when the powder to be dosed is a catalyst which is intended to simplify or accelerate the reactions in the gas space of the connected reactor. In this case, even very small amounts of gas which enter the buffer tank as a result of leakage of the piston guide or gland, could lead to poor operation of the device. Due to the extraction channels, which are connected via valves 17 and 18 to the known vacuum device, the penetration of gaseous reaction components into the buffer tank 4 and the dosing material container 3 is prevented in a simple manner. Connection 9 in the lead channel 6, depending on from the position of the assigned valves 15 and 18 55, it can also perform the function of a suction channel. For explanation of the mode of operation, the starting point is shown in Fig. 1 the position of the piston slide 2 and the emptying piston 7. In this case, the valve 18 is open and valves 15 and 17 are closed. The buffer tank 4 contains the powdered catalyst in an amount that corresponds to the passage capacity of 1 piston slider 2. The dosing material container 3 is at least partially filled with the powdered catalyst and the nitrogen from the line 19. of the dispenser, the interaction of the pistons and valves is maintained, in such a way the piston slide 2 is retracted to the upper end position. Thereby, the reduction 1 is achieved so far that it enters the container 3 of the material to be dispensed so that it can be filled with powder. In this position, the buffer tank 4 discharges its contents into the guide channel 5 of the piston slide 2. The piston now retracts towards the home position, but stops in the intermediate position shown in FIG. 2, so as not to compress the powder in the channel 5. The transported powder cannot now fall into the buffer tank. In the next phase, valves 17 and 15 open, valve 18 closes and the discharge piston 7 returns to the position shown in Fig. 2. Under a pressure which is about several atmospheres higher with respect to the pressure in the gas space, the gaseous reaction component or the reaction inert gas passes through the open valve 15 into the released portion of the leading channels 6 and 5, the powder specified here and present in through connection 8, blown into the gas space. By returning successively to the initial position, the piston slide 2 and the emptying piston 7 displace any residual powder from the channels. Valve 15 then closes and valve 18 opens. The home position is thus re-attained. The interaction of pistons and valves is controlled repeatedly. It can be seen from the presented mode of operation that the discharge piston 7, apart from the emptying function, also has the role of a closing element. Suction downstream of the stuffing boxes can be dispensed with when there is no concern about the powder reactions taking place or the powder initiating the reaction. PL PL

Claims (3)

1. Zastrzezenia patentowe 1. Dozownik z pojemnikiem dozowanego mate¬ rialu, podajnikiem i oprózniaczem, sluzacy do wo- lumetrycznego dozowania w malych dawkach za- , chowujacych sie jak plyn proszków, podawanych do przestrzeni gazowej wykazujacej nadcisnienie, znamienny tym, ze podajnik stanowi przewezenie 1 pionowego suwaka tloczkowego (2), które przy górnym krancowym polozeniu suwaka tloczkowego wchodzi do pojemnika (3) dozowanego materialu, a przy dolnym krancowym polozeniu suwaka (2) do zbiornika zderzakowego (4), przy czym dolny koniec suwaka tloczkowego (2) prowadzony jest szczelnie w kanale (5), który polaczony jest z ka¬ nalem prowadzacym (6) tloczka oprózniajacego (7) oraz tym, ze tloczek oprózniajacy w swym kran¬ cowym polozeniu wypelnia przynalezny do niego kanal prowadzacy (6), a w drugim swym kranco¬ wym polozeniu stwarza polaczenie (8) z przestrze¬ nia gazowa, laczy ze soba obydwa kanaly prowa¬ dzace i odslania przylacze (9) swojego kanalu pro¬ wadzacego (6) do urzadzenia wydmuchowego.77 0841. Claims 1. A dispenser with a dosed material container, a feeder and an emptying device for volumetric dosing in small doses of powders that behave like a liquid, fed into a gas space showing overpressure, characterized by the fact that the feeder is a conduit 1 vertical piston slide (2), which, at the upper end position of the piston slide, enters the container (3) for dosed material, and at the lower end position of the slide (2) into the buffer tank (4), with the lower end of the piston slide (2) guided is sealed in the channel (5), which is connected to the guide channel (6) of the discharge piston (7) and that the discharge piston fills the associated guide channel (6) at its end position, and the other at its end stop In its position, it creates a connection (8) with the gas space, connects both leading channels and exposes the connection (9) of its lead channel (6) to the device outlet 77 084 2. Dozownik wedlug zastrz. 1, znamienny tym, ze suwak tloczkowy (2) i tloczek oprózniajacy (7) polaczone sa z cylindrami sterujacymi (10, 11).2. The dispenser according to claim Device according to claim 1, characterized in that the piston slide (2) and the discharge piston (7) are connected to the control cylinders (10, 11). 3. Dozownik wedlug zastrz. 1 albo 2, znamienny tym, ze kanaly prowadzace maja dlawnice (12) z podlaczonymi do nich kanalami odsysajacymi (13). PL PL3. The dispenser according to claim A method as claimed in claim 1 or 2, characterized in that the lead channels have glands (12) with suction channels (13) connected thereto. PL PL
PL1971152212A 1970-12-18 1971-12-16 PL77084B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2062513A DE2062513B2 (en) 1970-12-18 1970-12-18 Dosing device for dosing powders

Publications (1)

Publication Number Publication Date
PL77084B1 true PL77084B1 (en) 1975-02-28

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Family Applications (1)

Application Number Title Priority Date Filing Date
PL1971152212A PL77084B1 (en) 1970-12-18 1971-12-16

Country Status (16)

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US (1) US3750911A (en)
JP (1) JPS5423591B1 (en)
AT (1) AT333525B (en)
AU (1) AU452588B2 (en)
BE (1) BE776959A (en)
BR (1) BR7108372D0 (en)
CA (1) CA956280A (en)
DE (1) DE2062513B2 (en)
ES (1) ES397869A1 (en)
FR (1) FR2118159B1 (en)
GB (1) GB1370492A (en)
IT (1) IT944040B (en)
NL (1) NL7117071A (en)
PL (1) PL77084B1 (en)
RO (1) RO60595A (en)
ZA (1) ZA718476B (en)

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AT333525B (en) 1976-11-25
RO60595A (en) 1976-08-15
DE2062513B2 (en) 1979-02-15
ZA718476B (en) 1972-09-27
BE776959A (en) 1972-06-20
IT944040B (en) 1973-04-20
FR2118159B1 (en) 1976-02-13
ATA1080371A (en) 1976-03-15
FR2118159A1 (en) 1972-07-28
DE2062513A1 (en) 1972-07-13
AU3693671A (en) 1973-06-21
ES397869A1 (en) 1975-04-16
US3750911A (en) 1973-08-07
JPS5423591B1 (en) 1979-08-15
BR7108372D0 (en) 1973-05-03
GB1370492A (en) 1974-10-16
NL7117071A (en) 1972-06-20
CA956280A (en) 1974-10-15
AU452588B2 (en) 1974-09-05

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