PL96614B1 - LIQUID WASH - Google Patents
LIQUID WASH Download PDFInfo
- Publication number
- PL96614B1 PL96614B1 PL17076174A PL17076174A PL96614B1 PL 96614 B1 PL96614 B1 PL 96614B1 PL 17076174 A PL17076174 A PL 17076174A PL 17076174 A PL17076174 A PL 17076174A PL 96614 B1 PL96614 B1 PL 96614B1
- Authority
- PL
- Poland
- Prior art keywords
- sodium
- urea
- weight
- polyphosphates
- water glass
- Prior art date
Links
- 239000007788 liquid Substances 0.000 title claims description 9
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 16
- 239000004202 carbamide Substances 0.000 claims description 16
- 229920000388 Polyphosphate Polymers 0.000 claims description 13
- 239000001205 polyphosphate Substances 0.000 claims description 13
- 235000011176 polyphosphates Nutrition 0.000 claims description 13
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 10
- 235000019353 potassium silicate Nutrition 0.000 claims description 9
- 239000003599 detergent Substances 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 230000000087 stabilizing effect Effects 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 239000000271 synthetic detergent Substances 0.000 claims description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 3
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 3
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 3
- 229940005740 hexametaphosphate Drugs 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 239000004615 ingredient Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- -1 sodium alkylarylsulfonate Chemical class 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Description
Przedmiotem wynalazku jest ciekly srodek myja¬ cy przeznaczony przede wszystkim do mycia reczne¬ go urzadzen i sprzetu w przemysle mleczarskim i w innych galeziach przemyslu spozywczego.The present invention relates to a liquid detergent Mainly intended for washing by hand it devices and equipment in the dairy industry and in other branches of the food industry.
Znane dotychczas ciekle srodki myjace maja postac dyspersja lub roztworów detergentów syntetycznych wywodzie i zawieraja przewaznie dodatkowo inne zwiazki chemicznie wykazujace wlasciwosci myjace.The liquid cleaning agents known so far have the form of dispersion or solutions of synthetic detergents arguments and usually also contain others chemicals with cleaning properties.
Srodki te zawieraja równiez dodatek substancji sta¬ bilizujacych, które zwiekszaja wzajemna rozpu¬ szczalnosc detergentów syntetycznych i skladników nieorganicznych.These agents also contain an addition of solids bilizing, which increase mutual dissolution leakage of synthetic detergents and ingredients inorganic.
Substancje stabilizujace przeciwdzialaja metnieniu srodków i wytracaniu sie ich skladnlików w czasie produkcji lub magazynowania, zapobiegajac jedno¬ czesnie ich rozwarstwianiu sie.Stabilizing substances prevent shading resources and the loss of their ingredients over time production or storage, preventing one¬ together with their delamination.
Trudnosci wystepujace przy produkcji tego typu srodków polegaja na wlasciwym doborze substancji stabilizujacej oraz na okresleniu optymalnego pro¬ centowego udzialu jej w stosunku do pozostalych skladników srodka myjacego.Difficulties in the production of this type of measures rely on the correct selection of substances stabilizing and determining the optimal pro ¬ percentage share of it in relation to the others detergent ingredients.
Jako substancje stabilizujace stosowane sa: glice¬ ryna, alkohole, mocznik, sulfoniany, alkilofosforany oraz inne.The following are used as stabilizing substances: glycerin rine, alcohols, urea, sulfonates, alkylphosphates and other.
Zalecane bywa równiez stosowanie polifosforanów jako zwiazków dzialajacych peptyzujaco i klarujaco na substancje powierzchniowo czynne w roztworach wodnych. Stwierdzono jednaka ze polifosforany nie wykazuja takiego dzialania w cieklych srodkach my¬ jacych, zawierajacych duze ilosci szkla wodnego so- dowego. W srodkach zawierajacych na przyklad 45% szkla wodnego i alkiloarylosulfonian sodowy w ilo¬ sci okolo 3%, w przeliczeniu na substancje aktywna, nastepuje rozwarstwienie natychmiast, albo w kró¬ tkim czasie po wytworzeniu srodków, mlimo obecno¬ sci polifosforanów w granicach stezen wyznaczonych przez rozpuszczalnosc tych zwiazków.The use of polyphosphates is also recommended as compounds with a peptizing and clarifying effect on surfactants in solutions aquatic. However, it has been found that polyphosphates do not show this effect in liquid detergents jugs, containing large amounts of water glass day. In measures containing, for example, 45% of water glass and sodium alkylarylsulfonate in amounts about 3%, based on the active substance, stratification occurs immediately or shortly time after the preparation of the agents, although not present polyphosphate content within the determined concentration limits by the solubility of these compounds.
Ze wzgledów ekonomicznych szczególnie korzystne jest stosowanie mocznika jako substancji stabilizuja¬ cej. Zwiazek ten jednak rozklada sie w srodowisku alkalicznym, tracac stopniowo swe wlasciwosci star"" bilizujace. Stwierdzono przykladowo, ze przy zawar¬ tosci w cieklym srodku myjacym szkla wodnego so¬ dowego okolo 45% i alkilobenzenosulfónianu sodo¬ wego okolo 3,5%, w przeliczeniu na substancje akty¬ wna, nastepuje utrata jednorodnosci preparatu po obnizeniu sie zawartosci mocznika do okolo 3%. Wa¬ dy te powoduja obnizenlie wartosci uzytkowej i han¬ dlowej cieklych preparatów myjacych.Particularly advantageous for economic reasons is the use of urea as a stabilizing substance more. This relationship, however, breaks down in the environment alkaline, gradually losing its star properties "" bilizing. For example, it has been found that when the in a liquid detergent of water glass soy of about 45% and sodium alkylbenzenesulfonate 3.5%, based on the active substances wna, there is a loss of homogeneity of the preparation after lowering the urea content to about 3%. Wa¬ these causes a reduction in value in use and a tradeoff for liquid cleansing preparations.
Ciekly srodek myjacy wedlug wynalazku stanowi roztwór anionoaktywnych detergentów syntety¬ cznych, korzystnie alMloarylosulfonianów sodowych w ilosci od 1 do 8% wagowych w przeliczeniu na substancje aktywna, w srodowisku alkalicznym za¬ wierajacym od 35 do 50% wagowych szkla wodnego oraz dodatek stabilizatorów zlozony z mocznika i heksametafosforanu, trójpolifosforanu lub tetrapo- lifosforanu sodowego, albo z mocznika i mieszaniny . tych fosforanów. Stosunek wagowy mocznika do wy- mlienionych fosforanów powinien wynosic od 1 :1 96 61496 614 3 do 10 :1, najkorzystniej od 2 :1 do 6 :1, przy czym ilosc fosforanów wyraza sie w jednostkach wago¬ wych P205, natomiast laczna ilosc mocznika i poli¬ fosforanu wzglednie polifosforanów w stosunku do produktu zawierajacego 35 do 50 procent wagowych szkla wodnego wynosH 6 do 15% wagowych. Srodek tein moze ponadto zawierac inne substancje posaada- jaoe wlasciwosci myjace, szczególnie ortofosforany sodowe.A liquid detergent according to the invention is synthetic anionic detergent solution active, preferably sodium alkylarylsulfonates in an amount of 1 to 8% by weight based on active substance, in an alkaline environment containing from 35 to 50% by weight of water glass and the addition of stabilizers consisting of urea and hexametaphosphate, tripolyphosphate or tetrapo- sodium phosphate, either from urea and a mixture. these phosphates. The urea weight ratio to the milled phosphates should be 1: 1 96 61 496 614 3 to 10: 1, most preferably from 2: 1 to 6: 1, with the amount of phosphate is expressed in units of weight P205, while the total amount of urea and poly phosphate or polyphosphate relative to of a product containing 35 to 50 weight percent The water glass is 6 to 15% by weight. Center tein may also contain other substances that good washing properties, especially orthophosphates sodium.
Wprowadzenie do skladu srodka myjacego z duza zawartoscia szkla wodnego polifosforanów, zwlaszcza heksametafosforanu sodowego, obok mocznika, po¬ woduje zahamowanie rozkladu moczniika i utrwale¬ nie jego dzialania stabilizujacego wobec mieszaniny szkla wodnego, substancji powierzchniowo czynnej i wody. Todzialanie polifosforanów, szczególnie hek¬ sametafosforanu, wobec mocznika, zapewniajace trwaly efekt stabilizujacy i klarownosc produktu wy¬ stepuje tylko w wymienionych stosunkach iloscio¬ wych miedzy polifosforanem z jednej strony oraz mo¬ cznikiem i szklem wodnym z drugiej strony.Introduction to the composition of the large detergent polyphosphate water glass content, especially sodium hexametaphosphate, in addition to urea, po inhibits the decomposition of urea and fixes it not its stabilizing effect on the mixture water glass, surfactant and water. The working life of polyphosphates, especially hex self-metaphosphate, against urea, providing permanent stabilizing effect and product clarity it taps only in the mentioned ratios of quantity between polyphosphate on one side and mo¬ teapot and water glass on the other side.
Przez stosowanie okreslonej kombinacji polifosfo¬ ranu i mocznika mozna zatem — w przypadku cie¬ klych srodków myjacych o duzej zawartosci szkla wodnego — uzyskac klarowny, jednorodny preparat nie rozdzielajacy sie i nie metniejacy nawet w ciagu wielomiesiecznego przechowywania, co nie udaje sie przy uzyciu wylacznie polifosforanu lub wylacznie mocznika.By using a specific combination of polyphosphate the wound and urea can therefore - in the case of shadow - clumped cleaning agents with a high glass content water - obtain a clear, homogeneous preparation not separating and not shrinking even in continuation months of storage, which fails using polyphosphate only or exclusively urea.
Zaletami tak otrzymanego srodka sa równiez do¬ bre wlasciwosci myjace, wysoka zdolnosc utrzymy¬ wania usunietych zanieczyszczen w roztworze, la¬ twosc dozowania i latwosc rozpuszczania w wodzie. 29 Srodek ten jest stosunkowo lagodny w dzialaniu za¬ równo w stosunku do metali, jak i do skóry ludzkiej.The advantages of the measure thus obtained are also quite great washing properties, high maintenance capacity cleaning the removed impurities in a solution, la easy dosing and easy to dissolve in water. 29 This agent is relatively mild in its action equally to metals and to human skin.
Przyklad. 6 kg keiylobenzenosulfonianu sodo¬ wego o zawartosci substancji aktywnej 50% rozpu¬ szcza sie w 38 1 wody, dodaje 8 kg mocznliika i 5 kg heksametafosforanu sodowego. Po rozpuszczeniu wszystkich skladników wprowadza sie 43 kg szkla wodnego sodowego i miesza az do calkowitego roz¬ puszczenia Po kilku do kilkunastu godzinach odsta- wania, w czasie których na dnie zbiornika moze ze¬ brac sie niewielka losc osadu rozlewa slie klarowna ciecz do opakowan. iExample. 6 kg of sodium keylbenzenesulfonate with an active substance content of 50% of the dissolving Pept in 38 liters of water, add 8 kg of urea and 5 kg sodium hexametaphosphate. After dissolving of all ingredients are introduced 43 kg of glass of aqueous sodium and stirred until completely dissolved releasing After a few to several hours, the during which the bottom of the tank may bite a small amount of sediment spills out clear liquid for packaging. and
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL17076174A PL96614B1 (en) | 1974-04-30 | 1974-04-30 | LIQUID WASH |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL17076174A PL96614B1 (en) | 1974-04-30 | 1974-04-30 | LIQUID WASH |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL96614B1 true PL96614B1 (en) | 1978-01-31 |
Family
ID=19967143
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL17076174A PL96614B1 (en) | 1974-04-30 | 1974-04-30 | LIQUID WASH |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL96614B1 (en) |
-
1974
- 1974-04-30 PL PL17076174A patent/PL96614B1/en unknown
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