PL99537B1 - METHOD OF PERIODIC POLYCONDENSATION IN APPLIANCES WITH STIRRERS - Google Patents

METHOD OF PERIODIC POLYCONDENSATION IN APPLIANCES WITH STIRRERS Download PDF

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Publication number
PL99537B1
PL99537B1 PL17957475A PL17957475A PL99537B1 PL 99537 B1 PL99537 B1 PL 99537B1 PL 17957475 A PL17957475 A PL 17957475A PL 17957475 A PL17957475 A PL 17957475A PL 99537 B1 PL99537 B1 PL 99537B1
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PL
Poland
Prior art keywords
temperature
mass
until
reacting
process temperature
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PL17957475A
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Polish (pl)
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Priority to PL17957475A priority Critical patent/PL99537B1/en
Publication of PL99537B1 publication Critical patent/PL99537B1/en

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Description

Przedmiotem wynalazku jest sposób prowadzenia periodycznej polikondensacji w aparatach z mie¬ szadlami, zwlaszcza do polikondensacji tereftalanu glikolu etylenowego.Znany jest sposób prowadzenia periodycznej po¬ likondensacji w reaktorach, których uklady grzejne zasila sie nosnikami ciepla o zmiennej, regulowa¬ nej temperaturze i regulowanej wielkosci przeply¬ wu. Po zaladowaniu do reaktora, monomer ogrzewa sie do odpowiedniej temperatury i miesza sie, przy czym obniza sie cisnienie wewnatrz reaktora. Po osiagnieciu przez mase reagujaca odpowiedniej tem¬ peratury, obniza sie temperature nosnika ciepla, chlodzac go w chlodnicach wodnych lub powietrz¬ nych i z jego pomoca odbiera sie cieplo mieszania.Proces prowadzi sie az do uzyskania odpowiedniej lepkosci masy reagujacej.Wadami tego sposobu sa: koniecznosc posiadania indywidualnego ukladu grzejnego dla kazdego reak¬ tora, brak mozliwosci utrzymania niezbednej jed¬ norodnosci rozkladu temperatury w masie reagu¬ jacej, co powoduje obnizenie jakosci polimeru, któ¬ ry zawiera duzo1 zanieczyszczen spowodowanych degradacja termiczna oraz tworzeniem sie oligome¬ rów produktów cyklicznych.Istote sposobu wedlug wynalazku stanowi zasto¬ sowanie ogrzewania reaktora z pomoca cieklego nosnika ciepla o stalej temperaturze i stalym prze¬ plywie i utrzymywanie temperatury masy reagu- jacej w dopuszczalnych granicach z pomoca regu¬ lacji intensywnosci mieszania.Sposób wedlug wynalazku polega na tym, ze reaktor, zawierajacy mase reagujaca, ogrzewa sie cieklym nosnikiem ciepla o stalym przeplywie i sta¬ lej temperaturze nie wyzszej od wymaganej konco¬ wej temperatury procesu, korzystnie równej opty¬ malnej temperaturze procesu, przy czym, przy ob¬ nizonym cisnieniu, miesza sie mase reagujaca az do osiagniecia optymalnej temperatury procesu, po czym zmniejsza sie intensywnosc mieszania, obniza¬ jac obroty mieszadla, dla ustalenia sie temperatury nie wyzszej od górnej granicznej temperatury pro¬ cesu, a nastepnie prowadzi sie proces, az do uzys¬ kania zalozonej lepkosci istotnej masy reagujacej.Zaletami tego sposobu sa: uzyskanie bardzo rów¬ nomiernego rozkladu temperatury w masie reagu¬ jacej, co prowadzi do obnizenia zawartosci zanie¬ czyszczen w polimerze spowodowanych degradacja termiczna i tworzeniem sie oligomerów produktów cyklicznych oraz mozliwosci ogrzewania kilku reak¬ torów z tego sarniego ukladu grzejnego.Sposób wedlug wynalazku przedstawiono na po¬ nizszym przykladzie: Do reaktora, którego budowa opisana jest w opisie patentowym nr 96(378 wprowa¬ dza sie tereftalan glikolu etylenowego o ciezarze czasteczkowym okolo 5000 i temperaturze okolo 278°C. Do plaszcza grzejnego tego reaktora dopro¬ wadza sie ciekly dowftherm A o stalej temperaturze 285°C i stalym przeplywie. Nastepnie dodaje sie 99 53T99 537 katalizator trójtlenek antymonu w ilosci 0,05 czesci wagowych i miesza mase reagujaca ustalajac obroty mieszadla na 40 obrotów/min., .przy czym wytwarza sie w reaktorze próznie rzedu 0,5-t-1 mm Hg. Po podniesieniu sie temperatury masy reagujacej do 285°C, obniza sie obroty mieszadla do 10 obro¬ tów/min. i prowadzi proces az do uzyskania tempe¬ ratury 289°C i lepkosci istotnej masy reagujacej 0,660 +0,0(15. PLThe subject of the invention is a method of conducting periodic polycondensation in apparatus with stirrers, especially for the polycondensation of ethylene glycol terephthalate. May wu. After charging into the reactor, the monomer is heated to the appropriate temperature and stirred while the pressure inside the reactor is lowered. After reaching the appropriate temperature by the reacting mass, the temperature of the heat carrier is lowered by cooling it in water or air coolers, and with its help the heat of mixing is recovered. The process leads to obtaining the appropriate viscosity of the reacting mass. The disadvantages of this method are: having an individual heating system for each reactor, the inability to maintain the necessary uniformity of temperature distribution in the reaction mass, which causes a reduction in the quality of the polymer, which contains a lot of impurities caused by thermal degradation and the formation of oligomers of cyclic products. The method according to the invention is the use of heating the reactor with a liquid heat carrier at a constant temperature and constant flow and keeping the temperature of the reaction mass within acceptable limits by regulating the intensity of the mixing. The method according to the invention consists in that the reactor, containing a reactive mass, it heats up that it is a liquid heat carrier with a constant flow and a constant temperature not higher than the required final process temperature, preferably equal to the optimal process temperature, and the reactant mass is mixed under reduced pressure until the optimal process temperature is reached, then the mixing intensity is reduced, the stirrer speed is lowered, in order to set the temperature not higher than the upper limit temperature of the process, and then the process is carried out until the assumed viscosity of the relevant reaction mass is obtained. The advantages of this method are: a very even temperature distribution in the reaction mass, which leads to a reduction in the content of impurities in the polymer caused by thermal degradation and the formation of oligomers of cyclic products, and the possibility of heating several reactors from this roe deer heating system. ¬ the following example: For a reactor whose structure is described in the description of p No. 96 (378) is introduced ethylene glycol terephthalate with a molecular weight of about 5000 and a temperature of about 278 ° C. A liquid downdum A with a constant temperature of 285 ° C. and a constant flow is fed to the heating mantle of this reactor. Thereafter, 99 53T99 537 antimony trioxide catalyst is added in an amount of 0.05 parts by weight and the reaction mass is mixed by setting the stirrer speed to 40 rpm, whereby a vacuum of 0.5 t-1 mm Hg is produced in the reactor. After increasing the temperature of the reacting mass to 285 ° C., the speed of the agitator is lowered to 10 rpm. and the process is carried out until the temperature of 289 ° C and the viscosity of the relevant reacting mass are obtained from 0.660 +0.0 (15. PL

Claims (1)

1. Zaist rzezenie patent owe Sposób prowadzenia periodycznej pifikondensacji w aparatach z mieszadlami przez ogrzewanie masy reagujacej do odpowiedniej temperatury, miesza¬ lo 15 nie przy obnizonym cisnieniu i utrzymywanie od¬ powiedniej temperatury az do uzyskania zalozonej lepkosci istotnej, znamienny tym, ze reaktor zawie¬ rajacy mase reagujaca ogrzewa sie Cieklym nosni¬ kiem ciepla o stalym przeplywie i stalej tempera¬ turze nie wyzszej od wymaganej koncowej tempe¬ ratury procesu, korzystnie równej optymalnej tem¬ peraturze procesu, przy czym, przy obnizonym cis¬ nieniu, miesza sie mase reagujaca, az do osiagniecia optymalnej temperatury procesu, po czym zmniejsza sde intensywnosc mieszania, obnizajac obroty mie¬ szadla, dla ustalenia sde temperatury nie wyizsizej od górniej granicznej temperatury procesu, a nastepnie prowadzi sie proces az do uzyskania zalozonej lep¬ kosci istotnej matey reagujacej. LZG Z-d Nr 2 — 1222/78 110 egz. form. A-4 Cena 45 zl PL1. Patent application A method of carrying out periodic pifikondensation in apparatus with stirrers by heating the reacting mass to the appropriate temperature, mixing it under reduced pressure and maintaining the appropriate temperature until the assumed intrinsic viscosity is obtained, characterized in that the reactor is suspended The reacting mass is heated with a liquid heat carrier with a constant flow and a constant temperature not higher than the required final process temperature, preferably equal to the optimal process temperature, and the reactant mass is mixed at a reduced pressure, until the optimum process temperature is reached, and then reduce the agitation intensity, lowering the rotation of the stirrer, in order to set the temperature judgment not higher than the upper limit of the process temperature, and then the process is carried out until the assumed viscosity of the relevant reacting mat is obtained. LZG Z-d No. 2 - 1222/78 110 copies of the form A-4 Price PLN 45 PL
PL17957475A 1975-04-12 1975-04-12 METHOD OF PERIODIC POLYCONDENSATION IN APPLIANCES WITH STIRRERS PL99537B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL17957475A PL99537B1 (en) 1975-04-12 1975-04-12 METHOD OF PERIODIC POLYCONDENSATION IN APPLIANCES WITH STIRRERS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL17957475A PL99537B1 (en) 1975-04-12 1975-04-12 METHOD OF PERIODIC POLYCONDENSATION IN APPLIANCES WITH STIRRERS

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PL99537B1 true PL99537B1 (en) 1978-07-31

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