PT96407A - Processo para a preparacao de um catalisador do tipo de ziegler-natta - Google Patents

Processo para a preparacao de um catalisador do tipo de ziegler-natta Download PDF

Info

Publication number: PT96407A
Authority: PT; Portugal
Prior art keywords: compound; carrier; vanadium; catalyst; titanium
Prior art date: 1990-01-04

Application number

PT96407A

Other languages

English (en)

Portuguese (pt)

Inventor

Jean-Claude Andre Bailly

Patrick Behue

Original Assignee

Bp Chem Int Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-01-04

Filing date

1991-01-02

Publication date

1991-10-15

1991-01-02 Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd

1991-10-15 Publication of PT96407A publication Critical patent/PT96407A/pt

Links

239000003054 catalyst Substances 0.000 title claims description 66
238000000034 method Methods 0.000 title claims description 27
238000002360 preparation method Methods 0.000 title claims description 26
230000008569 process Effects 0.000 title claims description 22
150000001875 compounds Chemical class 0.000 claims description 58
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 42
229910052720 vanadium Inorganic materials 0.000 claims description 39
239000002245 particle Substances 0.000 claims description 36
150000003609 titanium compounds Chemical class 0.000 claims description 36
229930195733 hydrocarbon Natural products 0.000 claims description 33
150000002430 hydrocarbons Chemical class 0.000 claims description 33
239000004215 Carbon black (E152) Substances 0.000 claims description 31
239000007788 liquid Substances 0.000 claims description 31
239000010936 titanium Substances 0.000 claims description 27
150000002902 organometallic compounds Chemical class 0.000 claims description 25
235000011147 magnesium chloride Nutrition 0.000 claims description 21
239000011777 magnesium Substances 0.000 claims description 20
125000004432 carbon atom Chemical group C* 0.000 claims description 19
150000003682 vanadium compounds Chemical class 0.000 claims description 18
229910001629 magnesium chloride Inorganic materials 0.000 claims description 17
238000009826 distribution Methods 0.000 claims description 16
229920001577 copolymer Polymers 0.000 claims description 14
238000004519 manufacturing process Methods 0.000 claims description 14
-1 polyethylene, ethylene Polymers 0.000 claims description 14
238000006116 polymerization reaction Methods 0.000 claims description 14
229910052751 metal Inorganic materials 0.000 claims description 9
239000002184 metal Substances 0.000 claims description 9
239000000047 product Substances 0.000 claims description 8
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
239000012265 solid product Substances 0.000 claims description 7
238000005406 washing Methods 0.000 claims description 7
239000001257 hydrogen Substances 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 6
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
229910052749 magnesium Inorganic materials 0.000 claims description 6
150000001735 carboxylic acids Chemical class 0.000 claims description 5
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 4
150000001298 alcohols Chemical class 0.000 claims description 4
150000002989 phenols Chemical class 0.000 claims description 4
150000003003 phosphines Chemical group 0.000 claims description 4
150000001993 dienes Chemical class 0.000 claims description 3
150000002148 esters Chemical class 0.000 claims description 3
150000002739 metals Chemical class 0.000 claims description 3
125000002734 organomagnesium group Chemical group 0.000 claims description 3
239000004711 α-olefin Substances 0.000 claims description 3
229920001198 elastomeric copolymer Polymers 0.000 claims description 2
150000002170 ethers Chemical class 0.000 claims description 2
150000003140 primary amides Chemical group 0.000 claims description 2
230000009467 reduction Effects 0.000 claims description 2
150000003335 secondary amines Chemical group 0.000 claims description 2
150000003457 sulfones Chemical class 0.000 claims description 2
150000003462 sulfoxides Chemical class 0.000 claims description 2
150000003512 tertiary amines Chemical group 0.000 claims description 2
150000003568 thioethers Chemical class 0.000 claims description 2
239000003795 chemical substances by application Substances 0.000 claims 2
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 2
229920000089 Cyclic olefin copolymer Polymers 0.000 claims 1
150000001408 amides Chemical group 0.000 claims 1
239000003574 free electron Substances 0.000 claims 1
239000000155 melt Substances 0.000 claims 1
150000008039 phosphoramides Chemical group 0.000 claims 1
150000003141 primary amines Chemical group 0.000 claims 1
GFNGCDBZVSLSFT-UHFFFAOYSA-N titanium vanadium Chemical class [Ti].[V] GFNGCDBZVSLSFT-UHFFFAOYSA-N 0.000 claims 1
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 37
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 28
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 19
229910052719 titanium Inorganic materials 0.000 description 19
239000000725 suspension Substances 0.000 description 17
239000000203 mixture Substances 0.000 description 15
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 13
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 12
239000000460 chlorine Substances 0.000 description 11
238000003756 stirring Methods 0.000 description 11
238000007792 addition Methods 0.000 description 9
238000001556 precipitation Methods 0.000 description 9
239000007787 solid Substances 0.000 description 8
125000005287 vanadyl group Chemical group 0.000 description 8
150000001336 alkenes Chemical class 0.000 description 7
239000000843 powder Substances 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
239000005977 Ethylene Substances 0.000 description 6
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
239000007789 gas Substances 0.000 description 6
239000012071 phase Substances 0.000 description 6
238000006722 reduction reaction Methods 0.000 description 6
239000003638 chemical reducing agent Substances 0.000 description 5
238000007334 copolymerization reaction Methods 0.000 description 5
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
239000000853 adhesive Substances 0.000 description 4
230000001070 adhesive effect Effects 0.000 description 4
150000001335 aliphatic alkanes Chemical class 0.000 description 4
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
230000008901 benefit Effects 0.000 description 4
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
229910052794 bromium Inorganic materials 0.000 description 4
229910052801 chlorine Inorganic materials 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000007791 liquid phase Substances 0.000 description 4
238000005259 measurement Methods 0.000 description 4
229920000642 polymer Polymers 0.000 description 4
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
229920006395 saturated elastomer Polymers 0.000 description 4
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 4
150000003623 transition metal compounds Chemical class 0.000 description 4
PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
125000005843 halogen group Chemical group 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000012299 nitrogen atmosphere Substances 0.000 description 3
150000002894 organic compounds Chemical class 0.000 description 3
239000000243 solution Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
229910001220 stainless steel Inorganic materials 0.000 description 3
239000010935 stainless steel Substances 0.000 description 3
239000006228 supernatant Substances 0.000 description 3
229910052723 transition metal Inorganic materials 0.000 description 3
150000003624 transition metals Chemical class 0.000 description 3
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 3
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
230000000536 complexating effect Effects 0.000 description 2
150000004796 dialkyl magnesium compounds Chemical class 0.000 description 2
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
239000010419 fine particle Substances 0.000 description 2
238000012685 gas phase polymerization Methods 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
229920001903 high density polyethylene Polymers 0.000 description 2
239000004700 high-density polyethylene Substances 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
230000001376 precipitating effect Effects 0.000 description 2
ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 2
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 2
JBVMSEMQJGGOFR-FNORWQNLSA-N (4e)-4-methylhexa-1,4-diene Chemical compound C\C=C(/C)CC=C JBVMSEMQJGGOFR-FNORWQNLSA-N 0.000 description 1
PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
LJQDDVJEZIEHNY-YIMUCPRWSA-N (4r)-4-[(5r,8r,9s,10s,13r,14s,17r)-10,13-dimethyl-2,3,4,5,6,7,8,9,11,12,14,15,16,17-tetradecahydro-1h-cyclopenta[a]phenanthren-17-yl]-n,n-dimethylpentan-1-amine Chemical compound C([C@@H]1CC2)CCC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCCN(C)C)C)[C@@]2(C)CC1 LJQDDVJEZIEHNY-YIMUCPRWSA-N 0.000 description 1
OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
SLQMKNPIYMOEGB-UHFFFAOYSA-N 2-methylhexa-1,5-diene Chemical compound CC(=C)CCC=C SLQMKNPIYMOEGB-UHFFFAOYSA-N 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
229910021552 Vanadium(IV) chloride Inorganic materials 0.000 description 1
239000012190 activator Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001348 alkyl chlorides Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
230000008859 change Effects 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
150000004292 cyclic ethers Chemical class 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
230000008021 deposition Effects 0.000 description 1
238000001514 detection method Methods 0.000 description 1
125000006010 dichloroethoxy group Chemical group 0.000 description 1
CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
239000007970 homogeneous dispersion Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
150000002484 inorganic compounds Chemical class 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
238000000399 optical microscopy Methods 0.000 description 1
210000000056 organ Anatomy 0.000 description 1
150000002899 organoaluminium compounds Chemical class 0.000 description 1
125000002370 organoaluminium group Chemical group 0.000 description 1
150000002901 organomagnesium compounds Chemical class 0.000 description 1
IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920005606 polypropylene copolymer Polymers 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
238000010791 quenching Methods 0.000 description 1
230000000171 quenching effect Effects 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000009987 spinning Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
NBRKLOOSMBRFMH-UHFFFAOYSA-N tert-butyl chloride Chemical compound CC(C)(C)Cl NBRKLOOSMBRFMH-UHFFFAOYSA-N 0.000 description 1
VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
230000007704 transition Effects 0.000 description 1
JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000003643 water by type Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/68—Vanadium, niobium, tantalum or compounds thereof
- C08F4/685—Vanadium or compounds thereof in combination with titanium or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

PT96407A 1990-01-04 1991-01-02 Processo para a preparacao de um catalisador do tipo de ziegler-natta PT96407A (pt)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR9000191A FR2656615B1 (fr)	1990-01-04	1990-01-04	Procede de preparation d'un catalyseur de type ziegler-watta a base de vanadium et de titane, supporte sur un chlorure de magnesium.

Publications (1)

Publication Number	Publication Date
PT96407A true PT96407A (pt)	1991-10-15

Family

ID=9392614

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
PT96407A PT96407A (pt)	1990-01-04	1991-01-02	Processo para a preparacao de um catalisador do tipo de ziegler-natta

Country Status (17)

Country	Link
US (1)	US5106805A (cs)
EP (1)	EP0437080A1 (cs)
JP (1)	JPH0439309A (cs)
KR (1)	KR910018415A (cs)
CN (1)	CN1053243A (cs)
AU (1)	AU6835590A (cs)
BR (1)	BR9100019A (cs)
CA (1)	CA2033028A1 (cs)
CS (1)	CS391A2 (cs)
FI (1)	FI910020A7 (cs)
FR (1)	FR2656615B1 (cs)
HU (1)	HUT59702A (cs)
NO (1)	NO905634L (cs)
NZ (1)	NZ236669A (cs)
PL (1)	PL288605A1 (cs)
PT (1)	PT96407A (cs)
TW (1)	TW201761B (cs)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2656614B1 (fr) *	1990-01-03	1993-05-07	Bp Chemicals Snc	Procede de preparation d'un catalyseur de type ziegler-natta a base de vanadium, supporte sur un chlorure de magnesium.
EP0492788A3 (en) *	1990-11-28	1992-12-02	Bp Chemicals Limited	Process for preparing a ziegler-natta type catalyst
FR2691155B1 (fr) *	1992-05-15	1995-07-21	Bp Chemicals Snc	Procede de polymerisation de l'ethylene en plusieurs etapes.
JP2543468B2 (ja) *	1992-10-23	1996-10-16	三和興産株式会社	食品加工澱粉の製法
US5405817A (en) *	1993-02-12	1995-04-11	Quantum Chemical Corporation	V/TI multi-site olefin polymerization catalyst
US6071846A (en) *	1995-04-24	2000-06-06	Tokuyama Corporation	Olefin polymerization catalyst and a polyolefin production method
CN1252095C (zh) *	2000-12-15	2006-04-19	巴塞尔聚烯烃意大利有限公司	连续制备用于α－烯烃聚合的固体催化剂组分的方法
US6677266B1 (en)	2002-07-09	2004-01-13	Eastman Chemical Company	Process for preparing a vanadium/titanium catalyst and use in olefin polymerization
US6831032B2 (en)	2002-08-19	2004-12-14	Novolen Technology Holdings C.V.	Ziegler-Natta catalyst and methods of making and using same
CA2699832C (en)	2010-03-26	2016-10-04	Nova Chemicals Corporation	Polymerization catalysts comprising titanium and magnesium
EP2714753B1 (en) *	2011-06-01	2016-10-26	Dow Global Technologies LLC	Multi-metallic ziegler-natta procatalysts and catalysts prepared therefrom for olefin polymerizations
EP2818509A1 (en)	2013-06-25	2014-12-31	Basell Polyolefine GmbH	Polyethylene composition for blow molding having high stress cracking resistance
EP2818508A1 (en) *	2013-06-25	2014-12-31	Basell Polyolefine GmbH	Polyethylene composition having high impact and stress cracking resistance
CA2890606C (en)	2015-05-07	2022-07-19	Nova Chemicals Corporation	Process for polymerization using dense and spherical ziegler-natta type catalyst

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1267646A (en) *	1985-06-06	1990-04-10	The Dow Chemical Company	Catalyst and method for producing relatively narrow molecular weight distribution olefin polymers
US4612300A (en) *	1985-06-06	1986-09-16	The Dow Chemical Company	Novel catalyst for producing relatively narrow molecular weight distribution olefin polymers
FR2628110B1 (fr) *	1988-03-03	1994-03-25	Bp Chimie	Catalyseur de polymerisation d'olefines de type ziegler-natta, supporte sur des particules spheriques de chlorure de magnesium, et procede de preparation
FR2651001B1 (fr) *	1989-08-17	1993-03-12	Bp Chemicals Sa	Procede de preparation d'un catalyseur de type ziegler-natta a base de vanadium et de titane

1990
- 1990-01-04 FR FR9000191A patent/FR2656615B1/fr not_active Expired - Fee Related
- 1990-12-17 US US07/628,217 patent/US5106805A/en not_active Expired - Fee Related
- 1990-12-20 EP EP90314081A patent/EP0437080A1/en not_active Ceased
- 1990-12-20 AU AU68355/90A patent/AU6835590A/en not_active Abandoned
- 1990-12-21 CA CA002033028A patent/CA2033028A1/en not_active Abandoned
- 1990-12-28 NO NO90905634A patent/NO905634L/no unknown
- 1990-12-28 JP JP2408659A patent/JPH0439309A/ja active Pending
1991
- 1991-01-02 PT PT96407A patent/PT96407A/pt not_active Application Discontinuation
- 1991-01-02 FI FI910020A patent/FI910020A7/fi not_active Application Discontinuation
- 1991-01-03 HU HU9117A patent/HUT59702A/hu unknown
- 1991-01-03 CS CS913A patent/CS391A2/cs unknown
- 1991-01-04 NZ NZ236669A patent/NZ236669A/en unknown
- 1991-01-04 TW TW080100086A patent/TW201761B/zh active
- 1991-01-04 PL PL28860591A patent/PL288605A1/xx unknown
- 1991-01-04 BR BR919100019A patent/BR9100019A/pt unknown
- 1991-01-04 CN CN91100033A patent/CN1053243A/zh active Pending
- 1991-01-04 KR KR1019910000030A patent/KR910018415A/ko not_active Withdrawn

Also Published As

Publication number	Publication date
NO905634D0 (no)	1990-12-28
AU6835590A (en)	1991-07-11
FR2656615A1 (fr)	1991-07-05
FI910020L (fi)	1991-07-05
KR910018415A (ko)	1991-11-30
US5106805A (en)	1992-04-21
HU910017D0 (en)	1991-08-28
CS391A2 (en)	1991-08-13
PL288605A1 (en)	1991-09-09
BR9100019A (pt)	1991-10-22
EP0437080A1 (en)	1991-07-17
FR2656615B1 (fr)	1993-05-07
HUT59702A (en)	1992-06-29
TW201761B (cs)	1993-03-11
CN1053243A (zh)	1991-07-24
JPH0439309A (ja)	1992-02-10
FI910020A0 (fi)	1991-01-02
NZ236669A (en)	1991-12-23
CA2033028A1 (en)	1991-07-05
FI910020A7 (fi)	1991-07-05
NO905634L (no)	1991-07-05

Legal Events

Date	Code	Title	Description
1991-10-15	BB1A	Laying open of patent application	Effective date: 19910531
1997-06-30	FC3A	Refusal	Effective date: 19970407

Publication	Publication Date	Title
JP2810685B2 (ja)	1998-10-15	チーグラー―ナッタ触媒
KR0160770B1 (ko)	1999-01-15	올레핀 중합용으로 적절한 바나듐/티탄기재 촉매의 제조방법
AU606483B2 (en)	1991-02-07	Ziegler-natta catalyst and a process for its preparation
PT96407A (pt)	1991-10-15	Processo para a preparacao de um catalisador do tipo de ziegler-natta
PT96343B (pt)	1998-06-30	Processo para a preparacao dum catalisador solido para a polimerizacao de uma ou varias olefinas e dos seus polimeros, copolimeros ou pre-polimeros
PT96344B (pt)	1998-06-30	Processo para a preparacao de catalisadores solidos e pre-polimeros para a polimerizacao de olefinas
FI75847B (fi)	1988-04-29	Katalysatorer foer polymerisering och kopolymerisering av etylen och polymeriseringsfoerfaranden i vilka saodana katalysatorer utnyttjas.
EP0415588B1 (en)	1994-01-19	Process for preparing in gas phase elastomeric copolymers of propylene
PL167293B1 (en)	1995-08-31	Method of obtaining a catalyst for use in polymerising olefines
PT97007B (pt)	1998-07-31	Processo para a preparacao de catalisadores solidos a base de zirconio e de pre-polimeros para a polimerizacao heterogenea de uma ou mais olefinas e de polimerizacao de olefinas que os utiliza
AU631910B2 (en)	1992-12-10	Process for manufacturing elastomeric propylene copolymers in gas phase
PT97006B (pt)	1998-07-31	Processo para a preparacao de catalisadores solidos e de pre-polimeros para a polimerizacao de olefinas, e de preparacao de (co) polimeros de etileno
KR890014589A (ko)	1989-10-24	지글러-나타형 촉매
KR0172119B1 (ko)	1999-03-30	올레핀 중합용으로 적절한 바나듐-기재촉매의 제조방법
US5098875A (en)	1992-03-24	Process for preparing a ziegler-natta type catalyst
PT99601A (pt)	1992-10-30	Processo para a preparacao dum catalisador do tipo de ziegler-natta
US5252688A (en)	1993-10-12	Process for preparing a Ziegler-Natta type catalyst
PT99960A (pt)	1993-01-29	Processo para a (co) polimerizacao de etileno com pelo menos uma alfa-olefina e para a preparacao do respectivo catalisador