RO83332B1 - Process for preparing 2, 2-bis-(4-hydroxy-phenyl)-propane - Google Patents
Process for preparing 2, 2-bis-(4-hydroxy-phenyl)-propaneInfo
- Publication number
- RO83332B1 RO83332B1 RO105374A RO10537481A RO83332B1 RO 83332 B1 RO83332 B1 RO 83332B1 RO 105374 A RO105374 A RO 105374A RO 10537481 A RO10537481 A RO 10537481A RO 83332 B1 RO83332 B1 RO 83332B1
- Authority
- RO
- Romania
- Prior art keywords
- maximum
- phenol
- acetone
- propane
- bis
- Prior art date
Links
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 abstract 1
- 230000000295 complement effect Effects 0.000 abstract 1
- 239000012043 crude product Substances 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 238000005292 vacuum distillation Methods 0.000 abstract 1
- 239000003643 water by type Substances 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Inventia de fata se refera la un procedeu pentru prepararea 2,2-bis-(4-hidroxi-fenil)-propanului, prin reactia, într-o singura trapta, dintre fenol si acetona în prezenta de catalizatori acizi si promotori de compusi organici cu sulf, cu recuperarea reactantilor nereactionati si purificarea produsului brut, conform inventiei principale, cu descrierea nr. 65066 si a inventiei complementare, cu descrierea nr. 65618, prin care, în scopul îmbunatatirii randamentului de reactie într-un raport de recirculare de 50: 1 fata de debitul de alimentare cu materii prime, cantitatea de apa admisa în reactantii recirculati fiind de pîna la 2% g, se îndeparteaza fractiunile usoare prin distilare în vid la o presiune de maximum 250 mm Hg si la o temperatura maxima de 150 degree C, se separa prin distilare din fractiunile usoare, acetona si promotorul de apele folosite la maximum 600 mm Hg cu recircularea acestora la sinteza, apele fenolice fiind defenolate prin extractie cu o hidrocarbura aromatica în raport gravimetric de 1:2...5, la temperaturi de 35...60 degree C, apoi se îndeparteaza prin evaporare majoritatea fenolului din produsul de reactie pîna la maximum 10% g, la temperaturi pîna la 175 degree C si presiune de maximum 100 mm Hg, restul de fenol îndepartîndu-se prin dizolvare într-o hidrocarbura aromatica si/sau clorurata, la temperatura de 10...40 degree C.....The present invention relates to a process for preparing 2,2-bis- (4-hydroxy-phenyl) -propane by reacting in a single trap between phenol and acetone in the presence of acid catalysts and promoters of organic compounds with sulfur, with the recovery of unreacted reactants and purification of the crude product according to the main invention, 65066 and the complementary invention, with specification no. 65618, in which, in order to improve the reaction efficiency in a 50: 1 recirculation ratio relative to the raw material feed rate, the amount of water admitted in the recirculated reactants being up to 2% g, the light fractions are removed by vacuum distillation at a pressure not exceeding 250 mm Hg and at a maximum temperature of 150 ° C, distilling off from the light fractions, acetone and the water promoter used up to a maximum of 600 mm Hg with their recirculation to the synthesis, the phenolic waters being defenated by extraction with an aromatic hydrocarbon in a gravimetric ratio of 1: 2 ... 5 at temperatures of 35 ... 60 ° C, then evaporating most of the phenol in the reaction product up to a maximum of 10% g at temperatures up to at 175 ° C and pressure of maximum 100 mm Hg, the remainder of the phenol being dissolved by dissolving in an aromatic and / or chlorinated hydrocarbon at 10 ... 40 ° C .....
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO105374A RO83332B1 (en) | 1981-09-23 | 1981-09-23 | Process for preparing 2, 2-bis-(4-hydroxy-phenyl)-propane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO105374A RO83332B1 (en) | 1981-09-23 | 1981-09-23 | Process for preparing 2, 2-bis-(4-hydroxy-phenyl)-propane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO83332A3 RO83332A3 (en) | 1984-04-02 |
| RO83332B1 true RO83332B1 (en) | 1984-04-30 |
Family
ID=20110470
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO105374A RO83332B1 (en) | 1981-09-23 | 1981-09-23 | Process for preparing 2, 2-bis-(4-hydroxy-phenyl)-propane |
Country Status (1)
| Country | Link |
|---|---|
| RO (1) | RO83332B1 (en) |
-
1981
- 1981-09-23 RO RO105374A patent/RO83332B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RO83332A3 (en) | 1984-04-02 |
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