RO96844B1 - Process for preparing zsm-5 -type supersiliceous zeolites - Google Patents
Process for preparing zsm-5 -type supersiliceous zeolitesInfo
- Publication number
- RO96844B1 RO96844B1 RO126150A RO12615086A RO96844B1 RO 96844 B1 RO96844 B1 RO 96844B1 RO 126150 A RO126150 A RO 126150A RO 12615086 A RO12615086 A RO 12615086A RO 96844 B1 RO96844 B1 RO 96844B1
- Authority
- RO
- Romania
- Prior art keywords
- sio2
- type
- ethylene glycol
- zeolites
- al2o3
- Prior art date
Links
- 239000010457 zeolite Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 9
- 229910052681 coesite Inorganic materials 0.000 abstract 5
- 229910052906 cristobalite Inorganic materials 0.000 abstract 5
- 239000000377 silicon dioxide Substances 0.000 abstract 5
- 235000012239 silicon dioxide Nutrition 0.000 abstract 5
- 229910052682 stishovite Inorganic materials 0.000 abstract 5
- 229910052905 tridymite Inorganic materials 0.000 abstract 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 4
- 239000004115 Sodium Silicate Substances 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052593 corundum Inorganic materials 0.000 abstract 2
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 abstract 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 2
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 238000001027 hydrothermal synthesis Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
Landscapes
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
Inventia se refera la un procedeu pentru prepararea prin sinteza hidrotermala a zeolitilor supersilicosi de tip ZSM-5 din solutii de silicat de sodiu si sulfat de aluminiu, acidulate cu acid sulfuric în prezenta de etilenglicol, în scopul obtinerii unui produs de cristalinitate si puritate maxima si anume, o solutie de silicat de sodiu tehnic se gelifiaza cu etilenglicol, se aciduleaza cu acid sulfuric, se amesteca cu solutie de sulfat de aluminiu tehnic cu formarea gelului de aluminosilicat având compozitie: SiO2:Al2O3=40...120, Na2O:SiO2=0,08...0,12. HO - :SiO2=0,16...0,24, H2O:Al2O3=1000...3000, H2O:SiO2=18...50, etilenglicol: SiO2=0,5...5.The invention relates to a process for the preparation by hydrothermal synthesis of ZSM-5 type supersilic zeolites of solutions of sodium silicate and aluminum sulphate, acidified with sulfuric acid in the presence of ethylene glycol in order to obtain a product of crystallinity and maximum purity and a technical sodium silicate solution is gelled with ethylene glycol, acidified with sulfuric acid, mixed with a technical aluminum sulphate solution to form an aluminosilicate gel having the following composition: SiO2: Al2O3 = 40 ... 120, Na2O: SiO2 = 0.08 ... 0.12. HO -: SiO2 = 0.16 ... 0.24, H2O: Al2O3 = 1000 ... 3000, H2O: SiO2 = 18 ... 50, ethylene glycol: SiO2 = 0.5 ... 5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO126150A RO96844B1 (en) | 1986-12-26 | 1986-12-26 | Process for preparing zsm-5 -type supersiliceous zeolites |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO126150A RO96844B1 (en) | 1986-12-26 | 1986-12-26 | Process for preparing zsm-5 -type supersiliceous zeolites |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO96844A2 RO96844A2 (en) | 1989-04-28 |
| RO96844B1 true RO96844B1 (en) | 1989-04-30 |
Family
ID=20120240
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO126150A RO96844B1 (en) | 1986-12-26 | 1986-12-26 | Process for preparing zsm-5 -type supersiliceous zeolites |
Country Status (1)
| Country | Link |
|---|---|
| RO (1) | RO96844B1 (en) |
-
1986
- 1986-12-26 RO RO126150A patent/RO96844B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RO96844A2 (en) | 1989-04-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS57123815A (en) | Production of crystalline aluminosilicate zeolite | |
| GB1318157A (en) | Process for preparation of high-silica zeolites | |
| ES8603160A1 (en) | Method of preparing crystalline sodium silicates. | |
| ATE38973T1 (en) | PROCESS FOR THE PRODUCTION OF CRYSTALLINE ALKALINE LAYERED SILICATES. | |
| IT1152998B (en) | PROCEDURE FOR THE PREPARATION OF ALUMINUM-SILICATE POROUS CRYSTALS | |
| EP0190903A3 (en) | A crystalline zeolite composition having a cancrinite-like structure and a process for its preparation | |
| ATE72807T1 (en) | PROCESS FOR THE PRODUCTION OF L-TYPE ZEOLITES BY NUCLEAR TECHNOLOGY. | |
| GB1188584A (en) | Process for the preparation of Synthetic Zeolite Molecular Sieves | |
| FR1264290A (en) | Process for the catalytic preparation of ethylene glycol | |
| RO96844B1 (en) | Process for preparing zsm-5 -type supersiliceous zeolites | |
| RO109057B1 (en) | Crystallin and zeolitic alluminium-silicates preparation process | |
| HU9503172D0 (en) | Aluminosilicates | |
| GB1560223A (en) | Synethesis of favjasite | |
| GB1223592A (en) | Process for the preparation of aluminosilicate ion exchange materials | |
| GB1341984A (en) | Production of synthetic zeolites of faujasite structure | |
| GB841812A (en) | "improvements in and relating to zeolites" | |
| GB1066258A (en) | Improved process for preparing crystalline zeolites | |
| GB1297927A (en) | ||
| RO86665B1 (en) | Process for preparing porous crystalline aluminosilicates of zsm-5 type zeolithe | |
| GB980891A (en) | Production of molecular sieve adsorbents from kaolin minerals | |
| ES8704854A1 (en) | Process for the production of zeolites. | |
| GB1409325A (en) | Production of synthetic zeolites of faujasite structure | |
| EP0131898A3 (en) | Process for preparing aluminium silicates with a zeolitic structure | |
| GB1065993A (en) | Process for the production of zeolites | |
| SU1698188A1 (en) | Method of producing type y zeolite |